• Journal of the Korean Chemical Society
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• v.43 no.1
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• pp.85-91
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• 1999

The second order rate constants for the hydrolysis of substituted phenyl N,N-diethyl-P-benzylphosphonamidates (2,4-$(NO_2)_2$, 4-$NO_2$, 4-CN, 4-Cl, 4-H)in 20% dioxane-water (v/v) have been determined by UV/Vis spectrophotometric method at various temperatures. The activation parameters (Ea, ${\Delta}H^{\neq}$,${\Delta}S^{\neq}$) were calculated from the rate constants and the reaction constant ($\rho$) was also estimated by Hammett equation. The activation entropies of the title reactions show considerably negative values, this result is not consistent with a dissociative mechanism (EA) in which a positive or a slightly negative value of the entropy of activation should be expected. Further, kinetic evidence for an associative mechanism (AE) was obtained from the linear free energy relationship. By the results of kinetic study for the alkaline hydrolysis of substituted phenyl N,N-diethyl-P-benzylphosphonamidates, it may be concluded that these reactions proceed through an associative mechanism.

• Journal of the Korean Applied Science and Technology
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• v.11 no.1
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• pp.79-85
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• 1994

All the activities and physical properties including surface tension' foaming power, foam stability, emulsifying power, dispersion effect of 3-(N, N-dimethyl N-alkylammonio)-2-hydroxyY-1-propane sulfonate (HSB)류와 3-CN-alkylamidopropyl-N,N-dimethylamm-onjo)-2-hydroxy-1-propane sulfonate (APSB) aquous solution were measured and critical micelle concentration was evaluated. Their cmc of hydroxy sulfobetaine derivatives evaluated by the surface tension method was $1.0{\times}10^{-3}{\sim}1.0{\times}10^{-4}$ mol/l, and surface tension of the aquous solution was decreased to $27{\sim}38dyne/cm$. The experimental results for foaming power, foam stability, emulsifying power in liquid paraffin showed a good surface active properties, especially, dispersion effect in ferric oxide exhibited some efficient surface active properties, and then it would be expected to application as detergent and dispersion agent.

• Water for future
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• v.27 no.4
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• pp.85-94
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• 1994

A Sensitivity analysis on the model parameters involved in the Clark watershed routing method is made to demonstrate the effect of each parameter on the magnitude of 50-year design flood for small urban streams. As for the rainfall parameter the time distribution pattern of design storm was selected. For short duration storms Huff, Yen & Chow and Japanese Central type distributions were selected and the Mononobe distribution of 24-hour design storm was also selected and tested for Clark method application. The effect of SCS runoff curve number for effective rainfall and the methods of subbasin division for time-area curve were also tested. The routing parameter, i.e. the storage constant(K), was found to be the dominating parameter once design storm is selected. A multiple regression formula for K correlated with the drainage area and main channel slope of the basin is proposed for the use in urban stream practice for the determination of design flood by Clark method.

• Journal of Korean Society on Water Environment
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• v.32 no.6
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• pp.562-569
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• 2016

Recently, Low Impact Development (LID) is being used in Korea to control urban runoff and nonpoint source pollution. In this study, we evaluated the reduction of surface runoff from a study area, as the effect of connecting three bioretention as LID-BMP. Surface runoff and storage volume of bioretention is estimated by the Curve Number (CN) method. In this study, the storage volume of bioretention is divided by the volume of surface runoff and precipitation which directly enters the bioretention. The ratio of captured surface runoff volume to storage volume is highly influenced by the ratio of drainage area to surface area of bioretention. The high bioretention surface area-to-drainage area ratio captures more surface runoff. The ratio of 1.2 captures 51~54% of the total surface runoff, ranging from 5-30cm of bioretention depth; a ratio of 6.2 captures 81~85%. Three connected bioretentions could therefore captures much more runoff volume, ranging from $35.8{\sim}167.3m^3$, as compared to three disconnected bioretentions at their maximum amount of precipitation with non-effluent from the connecting three bioretentions. Hence, connecting LID-BMPs could improve the removal efficiencies of surface runoff volume and nonpoint source pollution.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.211-211
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• 1999

Titanium nitride (TiN) thin films have useful properties including high hardness, good electrical conductivity, high melting point, and chemical inertness. The applications have included wear-resistant hard coatings on machine tools and bearings, decorative coating making use of the golden color, thermal control coatings for widows, and erosion resistant coatings for spacecraft plasma probes. For all these applications as feature sizes shrink and aspect ratios grow, the issue of good step coverage becomes increasingly important. It is therefore essential to manufacture conformal coatings of TiN. The growth of TiN thin films by chemical vapor deposition (CVD) is of great interest for achieving conformal deposition. The most widely used precursor for TiN is TiCl4 and NH3. However, chlorine impurity in the as-grown films and relatively high deposition temperature (>$600^{\circ}C$) are considered major drawbacks from actual device fabrication. To overcome these problems, recently, MOCVD processes including plasma assisted have been suggested. In this study, therefore, we have doposited Ti(C, N) thin films on Si(100) and D2 steel substrates in the temperature range of 150-30$0^{\circ}C$ using tetrakis diethylamido titanium (TDEAT) and titanium isopropoxide (TIP) by pulsed DC plamsa enhanced metal-organic chemical vapor deposition (PEMOCVD) method. Polycrystalline Ti(C, N) thin films were successfully grown on either D2 steel or Si(100) surfaces at temperature as low as 15$0^{\circ}C$. Compositions of the as-grown films were determined with XPS and RBS. From XPS analysis, thin films of Ti(C, N) with low oxygen concentration were obtained. RBS data were also confirmed the changes of stoichiometry and microhardness of our films. Radical formation and ionization behaviors in plasma are analyzed by optical emission spectroscopy (OES) at various pulsed bias and gases conditions. H2 and He+H2 gases are used as carrier gases to compare plasma parameter and the effect of N2 and NH3 gases as reactive gas is also evaluated in reduction of C content of the films. In this study, we fond that He and H2 mixture gas is very effective in enhancing ionization of radicals, especially N resulting is high hardness. The higher hardness of film is obtained to be ca. 1700 HK 0.01 but it depends on gas species and bias voltage. The proper process is evident for H and N2 gas atmosphere and bias voltage of 600V. However, NH3 gas highly reduces formation of CN radical, thereby decreasing C content of Ti(C, N) thin films in a great deal. Compared to PVD TiN films, the Ti(C, N) film grown by PEMOCVD has very good conformability; the step coverage exceeds 85% with an aspect ratio of more than 3.

• Economic and Environmental Geology
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• v.20 no.2
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• pp.85-95
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• 1987

The host rocks of titaniferous magnetite deposits in Gonamsan are alkaline gabbros, which are typical of undersaturated alkaline rocks in terms of the lack of normative quartz. According to field occurrences and petrographic features, these alkaline gabbros are divided into 3 rock types: coarse-grained and pegmatitic rock, medium-grained rock with equigranular texture, and layered cumulate rock. All these rocks mainly contain clinopyroxene(salite), plagioclase(An 43-66), pargasite, and ilmenite. The accessory minerals are apatite, sphene, quartz, and sometimes titaniferous magnetite. Pargasite, sphene, and quartz are considered to be secondary minerals formed by the reaction among clinopyroxene, plagioclase and Fe-Ti oxide at deuteric stage. Fe-Ti oxides generally occur as ilmenite in the alkaline rocks, and titaniferous magnetite in the ore deposits. Layered cumulate rocks are characterized by a recurrence of discontinuous thin mesolayer of clinopyroxene-pargasite within leucolayer mainly composed of plagioclase. Clinopyroxene is cumulus mineral whereas plagioclase, ilmenite and apatite occur as intercumulus minerals. According to the variation diagrams of oxide and trace element contents against the differentiation index, incompatible elements, such as Na, Ba and Sr, show positive correlations whereas compatible elements, such as Mg and Cr, show negative correlations. However some compatible elements, such as Co, Ni and V show irregular variations, reflecting relative cumulate status of cumulus and intercumulus minerals. On the de la Roche multicationic diagram, these alkaline gabbros are distributed along the differentiation curve of undersaturated alkaline series from alkaline basaltic composition through basanitic composition to tephritic composition. Layered cumulate rocks, which are distributed between basanitic composition and tephritic composition, reflect their cumulate character, slightly scattering away from the curve. The medium-grained rock shows higher contents in Ba, Sr and light rare earch elements than the coarse-grained and pegmatitic rock. The former shows two times higher contents of total rare earth elements than the latter, $while(La/Lu)_{cn}$ ratios maintain fairly constant values of 5.08~5.06 in these two rocks. This means that coarse-grained and pegmatitic rock, as compared with the medium-grained rock, was formed by the earlier differentiated magma but rare-earth element distribution pattern remained almost parallel during differentiation. From the data the above mentioned, these alkaline gabbros are considered to be comagmatic and to be formed by intrusions of differentiated magmas in its reservoir.

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.315-315
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• 2018

L-THIA ACN-WQ 2016 모형 개선 연구에서는 침투량 산정, 다중 기상지점 등 유역 규모 확대를 목적으로 엔진 개선과 모형의 최적 매개변수 선정을 위해 최적화 알고리즘을 활용한 자동보정 모듈을 개발하였다. 개선된 침투량 초기손실 산정 계수를 적용한 침투량 산정 방법을 Green-Ampt 모형의 침투량 산정 결과와 비교한 결과 편차는 매우 작았으며, Green-Ampt 모형을 통해 산정된 침투량 범위 내에 분포되어 개선된 침투량 산정 방법의 결과가 유효한 값을 의미하는 것으로 나타났다. 이렇게 도출된 초기손실 산정 계수를 관계식으로 개발하여 L-THIA ACN-WQ 2018 모형 내에서 CN에 따른 초기손실량이 산정되도록 하였고, 이를 기반으로 침투량 및 기저유출량이 산정된다. 유역 규모 확대를 위해 다중 기상지점이 적용되도록 엔진 코드를 개선하였으며, 평창A와 고부A 유역을 대상으로 단일 기상지점과 다중 기상지점 적용에 따른 유출 해석을 유량지속곡선을 통해 비교 한 결과 다중 기상지점 적용에 따라서 평창A와 고부A 유역 모두 유황구간이 크게 달라지는 것으로 나타났다. 특히 고부A 유역은 우황 변동 특성이 크게 나타났는데, 지역적 강우 특성이 뚜렷한 유역에서는 유출해석에 매우 중요한 영향인자로 작용되는 것으로 알 수 있었다. 마지막으로 L-THIA ACN-WQ 2018모형을 이용함에 있어 유역 특성에 알맞은 최적 매개변수 산정을 위해 유량 및 TN, TP 자동보정 툴을 개발하였다. 자동보정툴은 2개의 보정방안으로 개발하였다. 첫 번째는 유역 전체에 대해 하나의 최적매개변수를 도출하는 것이며, 두번째는 유역 내 다중 보정 지점을 통해 소유역별 최적매개변수를 도출하는 것이다. 이를 통해 사용자는 모형의 활용 목적 및 가용 가능한 보정 자료 등을 고려하여 모형의 최적 매개변수를 도출할 수 있다. 이렇게 개선된 L-THIA ACN-WQ 2018 모형을 총량단위유역 한강 평창A와 금강 고부A에 적용한 결과 유량은 NSE 0.76, 0.85로 매우 높게 나타났으며, TN, TP의 NSE는 0.64 ~ 0.86 로 매우 높은 적용성 결과가 도출되었다. Ryu(2016)의 연구 결과와 비교해보면 평창A는 NSE와 $R^2$ 수치로는 큰 차이를 보이지 않았지만, 유량 모의에서 일별 예측값 변화 폭에 큰 변화가 있는 것으로 나타났다. 기존 L-THIA ACN-WQ 2016모형 결과에서는 일별 유량의 변동성이 매우 크지만, L-THIA ACN-WQ 2018 모형에서는 일별 유량 변동폭이 크게 감소하여, 유량 모의에 큰 개선 효과가 있는 것으로 나타났다

• Journal of the Mineralogical Society of Korea
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• v.15 no.2
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• pp.85-94
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• 2002

XRF, XRD, EPMA have been used to investigate microstructures and mineralogical changes caused by the faulting and fluids associated with faulting in the Quaternary fault gouge zones at the Sangchon, Ipsil and Wangsan faults located at the southeastern part of the Korean Peninsula. The chemical compositions of faulted rocks and protoliths analyzed by XRF show that the fault gouges are relatively enriched in TiO$_2$, P$_2$O$_{5}$, MgO, and Fe$_2$O$_3$) compared with protoliths, indicating that the fluids associated with faulting were highly activated. XRD results show that the fault gouges predominantly consist of quartz, feldspar, calcite and clay minerals. Clay minerals formed in the gouge zones are mainly composed of smectite characterized by a dioctahedral sheet. Based on EPMA analyses various kinds of sulfide, carbonate, phosphate minerals were identified in the gouge zones and protoliths. Xenotime of grey fault gouge of the Sangchon fault and sulfide minerals of contact andesitic rock of Ipsil fault and contact grey andesitic rock of Wangsan fault were probably formed by inflow of hydrothermal solution associated with faulting prior to the Quaternary. Carbonate minerals of contact andesitic rock and gouge zone of the Ipsil fault were formed by inflow of fluid associated with faulting prior to the Quaternary. They are heavily fractured and have reaction rim on their edge, indicating that faultings and inflow of fluids were highly activated after carbonate minerals were formed. Calcites of Wangsan fault seemed to be formed in syntectonic or posttectonic Quaternary faulting.g.