• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.1844-1848
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• 2007

본 연구에서는 섬진강유역에 위치한 주요 수위관측소 지점의 유출률을 산정하기 위해서 지리정보시스템(Geographic Information System : GIS)을 적용하였다. 유출률 산정에 이용된 GIS 소프트웨어로는 ArcInfo와 ArcView 등을 이용하였으며, 대상유역의 수치유역도, 강우관측망도, 수위관측망도, 수계망도, 주암댐 유역도, 섬진강댐 유역도, 순유역도 등을 일차적으로 생성하였다. 또한 수치표고모델(Digital Elevation Model : DEM), 토양도, 토지피복도, 유출곡선지수도(Curve Number : CN) 등의 기본도를 생성하였다. 일반적으로 미계측 유역에서의 유출률 산정은 강우모형과 유역모형, 하도모형 등에 의한 수문학적 방법으로 산정되나, 계측 유역은 수위관측소 지점의 수위-유량관계곡선식에 의해 수위 수문곡선을 유량 수문곡선으로 변환하여 산정하게 된다. 본 연구에서는 수위-유량관계곡선식에 의하여 유출수문곡선을 산정하였으며, 또한 산정된 유출률의 적정성을 파악하기 위해 GIS를 이용하여 산정한 CN의 값과 비교하였다. 본 연구는 섬진강유역을 대상으로 하는 유출률 산정에 관한 연구로 강우량자료의 일관성 분석 등도 수행하였다. 유출률 산정에 이용된 강우자료는 기상청 자료이며 평균 강우량은 강우의 시간적 분포와 강우량의 양적분포 등을 분석한 후 산술평균법에 의해 산정하였다.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.221-226
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• 1990

The solvolysis of substitued phenacyl tosylates was studied in binary solvent mixtures of methanol-acetonitrile and methanol-acetone at 55$^{\circ}C$. Except for m-nitrophenacyl tosylate, the rate constants were increased with both of electron-donating substituents and electron-withdrawing ones and its rate constants were the largest in the binary solvent mixtures of 90% MeOH-10% MeCN. The results show that the reactions were changed with dissociative $S_N2$ mechanism judging from the magnitude of 1/m values going from the electron-withdrawing group to the electron-donating one of the substrate. And above results were consisted with the account for the PES model and QM approach.

• Korean Journal of Remote Sensing
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• v.16 no.1
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• pp.87-98
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• 2000

Image merging techniques have been developed to integrate the advantage of different data type. The objective of this study is to present the optimal method for merging high spatial resolution panchromatic image, such as the latest commercial satellite data, and low spatial resolution mulitspectral images. For this study, a set of 2m resolution panchromatic and 8m resolution mulitspectral data were simulated by using airborne mulitspectral data. Five merging methods of MWD, IHS, PCA, HPF, and CN were applied to produce four bands of high spatial resolution mulitspectral data. Merging results were evaluated by visual interpretation, image statistics, semivariogram, and spectral characteristics. From the aspects of both spatial resolution and spectral information, the wavelet-based MWD merging method have shown very similar results compared with the original data used for the merging.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.397.2-397.2
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• 2014

유기 발광 다이오드 (OLED)의 상용화를 위해 해결해야할 기술적 문제 중하나는 장수명이다. OLED에 적용된 유기물 층은 수분과 산소에 취약하여 소자 수명을 단축하는 요소로 작용하는데, 이를 해결하기 위해 유기물을 보호하며, 유기물 내로 침투되는 수분과 산소를 제어하기 위한 보호 층의 증착이 필수적이다. 필수적이다. 본 연구에서는, 사이클 화학 기상 증착법(C-CVD)을 이용하여 SiN/SiCN/SiN 구조의 무기 박막을 증착하여 유기물 보호층으로서의 적용 가능성을 제시하고자 한다. 이 때 각층의 두께는 각 각 10 nm이다. 증착된 다층 무기 박막은 비정질 상으로 수분 침투 보호막으로서 적당하다. 다층 무기 박막의 수분에 대한 저항성은 칼슘을 이용한 투과도 변화를 이용하여 측정하였다. 칼슘을 이용한 투과도 측정을 위해 고분자 PEN 필름위에 칼슘을 60nm 두께로 증착 시키고, 이어서 무기물인 SiN/SiCN/SiN의 다층 박막을 확산 방지층으로 증착 하였다. 제작된 소자는 온도 $85^{\circ}C$, 상대습도 85%의 가혹 조건에서 시간에 따른 표면 변화 및 투과도의 변화를 측정하였다. SiN/SiCN/SiN 구조를 갖는 무기 박막 층의 투습도는 3000시간까지는 $3.2{\times}10-5g/m/day$를 유지하였다. 이는 OLED 소자의 상용화를 위한 요구 조건에 근접한 값이다. 그러나 투습도는 측정 시간이 6000시간이 지난 후에 급격 증가하는데 이것은 30nm 두께의 SiN/SiCN/SiN의 확산 방지층에 임계 수명이 존재 한다는 것을 의미 한다고 할 수 있다. C-CVD 기술에 의해 제조된 다층 무기 박막 보호 층의 경계면에서 각 층간의 intermixing 현상이 관측되었으며, 이는 무기물 층의 결함과 핀 홀을 통해 내부로 확산 되는 수분의 침투 경로를 효과적으로 제어할 수 있는 방법이다. 본 연구 결과는 유연 기판 상에 제작된 OLED 소자에 적용 가능한 기술로서 소자 수명의 연장 뿐만 아니라 경량화에도 기여할 수 있는 기술이다.

• Korean Journal of Crystallography
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• v.13 no.2
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• pp.82-85
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• 2002

From the reaction of cis,cis,trans- [MoBr/sub 2/(CO)/sub 2/(PPh/sub 3/)/sub 2/］with 2,6-dimethylphenyl isocyanide, a molybdenum oxohaloisocyanide compound cis,fac-[Mo(O)Br/sub 2/,(CN-C/sub 6/H/sub 3/,-2,6-Me/sub 2/)sub 3/] (1) was iso-lated. Compound 1 was characterized by spectroscopy (/sup 1/H-NMR, /sup 13/C｛/sup 1/H｝-NMR, IR) and X-ray diffraction. Crystallographic data for 1: triclinic space group P(equation omitted), a=9.172(2) (equation omitted), b ＝ 11.550(3) (equation omitted), c ＝ 15.106(3) (equation omitted), α ＝ 100.44(2)°, β＝ 107.12(2)°, γ＝ 107.83(1)°, Z ＝ 2, R(wR/sub 2/) ＝ 0.0529(0.1344).

• Journal of the Korean Chemical Society
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• v.28 no.6
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• pp.366-373
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• 1984

Methanolysis rates of benzylbenzenesulfonates, substituted both on the substrate (Y) and on the leaving group (Z), were determined in MeOH-MeCN mixtures. The results showed that the reaction proceeds via the dissociative $S_N2$ mechanism, in which bond breaking proceeds in greater degree compared to bond formation at the transition state(TS). Multiple Hammett correlation analysis showed that the cross term, ${\rho}_{YZ}$, is very small and hence the cross interaction of two substituents, Y and Z, at the TS is not important, supporting the dissociative $S_N2 $ type mechanism. While transition state variations predicted by the quantum mechanical model is shown to agree in general with the experimental results, those predicted by the potential energy surface model failed to account for the leaving group effect properly.

• Journal of Korea Water Resources Association
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• v.36 no.2
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• pp.183-193
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• 2003

A relation between the temporal variation of rainfall and direct runoff was characterized using temporal indexes of rainfall(1st, 2nd, 3rd, and 4th moment). Curve Number has a relation with 1st and 2nd moment for AMCIII condition when the rainfall duration is relative (10th quantile). Also peak runoff ratio(QP/Q) has a relation with 1st and End moment for AMCIII condition as well as 3rd and 4th moment for AMC I condition. Considering all durations of rainfall, alternatively, Curve Number has a relation with 1st and 2nd moment for AMCIIIcondition besides every moments for AMC I condition. But peak runoff ratio(QP/Q) has few relations excepting 3rd and 4th moment for AMC I condition. As a results, temporal indexes of rainfall are useful to determine curve numbers regarding the temporal variation of rainfall.

• International Journal of Highway Engineering
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• v.9 no.3
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• pp.75-82
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• 2007

Washed wastewater generated from the intermittent cleaning process of the three tunnel sites located in the Seoul area showed high concentrations of SS, $COD_{Cr}$, T-N, $NH_3-N$, $NO_3-N$, Zn, Cu, Cr(+6), Mn, Mg, Phenol, $CN^-$ and E-Coli based on the water quality analysis. These characteristics of the deteriorative wastewater depend on the sampling method, cleaning frequency, released amount of washing water, inner material of tunnel wall, traffic volume, and type of drainage systems. Gravitational separation experiment of SS with collected tunnel wastewater showed considerable removal of pollutants such as 80% of $COD_{Cr}$, 30% of T-N and 90% of T-P simultaneously. GAC isotherm test was conducted to remove dissolved portion of the pollutants, and resulted in high removal efficiencies above 80% of $COD_{Cr}$, T-N, Zn, Cu, Mn, Phenol, CN in the experimental condition of GAC dosage of $50g/1/{\ell}$.

• Economic and Environmental Geology
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• v.41 no.4
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• pp.427-442
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• 2008

Estimation of groundwater recharge is one of the most critical issues in sustainable management of groundwater resources. This study estimated groundwater recharge in the Junggwae-Boeun area in Ulsan City, by using the water balance and hydrogeological characteristics of geology and soil. Evapotranspiration was computed by using the Thornthwaite method, and direct runoff was determined by using the SCS-CN technique. Groundwater recharge was obtained as 266 mm/a (20.6% of the average annual precipitation, 1296 mm/a), with 779 mm/a (60.1%) of evapotranspiration and 119 mm/a (9.2%) of direct runoff. Precipitation and groundwater recharge was highly correlated, comparing with the relationships between precipitation and evapotranspiration, and between precipitation and direct runoff. This fact indicates that groundwater recharge responds more sensitively to precipitation than evapotranspiration and direct runoff do.

• Journal of the Korean Society of Hazard Mitigation
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• v.7 no.4
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• pp.67-74
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• 2007

Rational method has been widely used to calculate peak runoff drainage design or small watershed because of simplicity and convenience. Runoff coefficient(C) is the most important parameter in the rational method which varies according to rainfall intensity, return period, rainfall duration time and soil characteristics. In practice, constant which is value of C in rational formula has been used from the table, originally based on ASCE. These table value does not consider the upper conditions of the depending factors, hence peak runoff calculation could be in correct. Therefore to calculate C in this paper we have devised an improved formula, considering relationship with rainfall duration, return period and CN of NRCS method. This formula is considered to be more reliable and helpful to the hydrologists and engineers to predict correct peak runoff.