• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.377-380
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• 2005

A study of ignition characteristics of cracked JP-7 fuel with both oxygen and air has been conducted over a wide range of pressures (1-20 atm), temperatures (1200-2000 K), and equivalence ratios (0.5-1.5). Correlations of ignition delay, of the form, $\tau=Aexp(E/RT)[F]^{a}[O_2]^{b}$ are established using the Chemkin-II package and least square analysis. The effect of $C_3$ hydrocarbons in cracked JP-7 fuel is examined by comparing the ignition delays for two different cracked compositions. A comparison for ignition delay is also made with the experimental results obtained by injecting liquid JP-7 fuel in air using a shock tube apparatus.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.89-92
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• 2011

The modeling of thermodynamic non-idealities and transport anomalies is a crucial prerequisite to realistically simulate the mixing and combustion processes of liquid propellants injected above critical pressures. This study has developed a specific set of subroutines to calculate the thermodynamic and transport properties based on the generalized cubic equation of state (EoS) in a coupled manner with the standard chemical kinetics packages (Chemkin). The existing flamelet analysis code is extended with the real-fluid package and applied to numerical investigation of local flame structures of kerosene and liquid oxygen at high pressure conditions relevant to the actual rocket engines.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.6
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• pp.51-58
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• 2003

A cycle simulation method is developed by coupling a commercial code, Ricardo's WAVE, with the SENKIN code from CHEMKIN packages to predict combustion characteristics of an HCCI engine. By solving detailed chemical kinetics the SENKIN code calculates the combustion products in the combustion chamber during the valve closing period, i.e. from IVC to EVO. Except the combustion chamber during the valve closing period the WAVE code solves thermodynamic status in the whole engine system. The cycle simulation of the complete engine system is made possible by exchanging the numerical solutions between the codes on the coupling positions of the intake port at IVC and of the exhaust port at EVO. This method is validated against the available experimental data from recent literatures. Auto ignition timing and cylinder pressure are well predicted for various engine operating conditions including a very high ECR rate although it shows a trend of sharp increase in cylinder pressure immediate after auto ignition. This trend is overpredicted especially for EGR cases, which may be due to the assumption of single-zone combustion model and the limit of the chemical kinetic model for the prediction of turbulent air-fuel mixing phenomena. A further work would be needed for the implementation of a multi-zone combustion model and the effect of turbulent mixing into the method.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.258-262
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• 2011

The laminar burning velocity in premixed Oxy-CH4 flames was studied in a lab-scale Bunsen burner. $CH^*$ chemiluminescence method and Schliren photography were used. Experimental results were compared with numerical prediction which was calculated with a CHEMKIN 3.7 package with a PREMIX code. Global equivalence ratio of oxy-CH4 mixture was varied from 0.5 to 2.0 in a laminar flow region. The laminar burning velocity was measured as 3.1 m/s for Schlieren photograph and 2.9 m/s for $CH^*$ chemiluminescence technique (angle method).

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.91-94
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• 2014

In this study, the laminar burning velocities of SNG fuel were studied using both experimental measurements and kinetic simulations. They were measured using the angle method of Bunsen flame configuration and the annular diverging channel combustor. And they were also numerically calculated by CHEMKIN Package with GRI 3.0 mechanisms. Spectrometer was used for characteristics of flame chemiluminescence of SNG fuels. From results of this work, first, we found that according to adding $H_2$ contents in the fuels the laminar burning velocities of SNG fuels were increased. And second, we also discovered existence of OH*, CH*, $C_2*$, HCO*, $CH_2*$ radicals and their correlation.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.04a
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• pp.234-237
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• 2008

A direct numerical simulation (DNS) code suitable for the prediction of buoyant jet diffusion flames was developed in this study. The thermodynamic and transport properties were evaluated using CHEMKIN package to enhance the prediction performance of the developed DNS code. A two dimensional simulations were performed for the jet diffusion flames in normal and zero-gravity conditions where the Froude numbers are 5 and infinity, respectively. The simulated buoyant jet diffusion flame in normal gravity showed that the unsteady and dynamic motion although the reynolds number is low (400). It was identified that the flame in normal gravity flickered periodically. The periodic motion of the flame disappeared in zero-gravity condition. The dynamic motion of the buoyant jet diffusion flame could be well understood by comparing the flame structures obtained by the simulations of normal and zero-gravity conditions.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.109-112
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• 2015

This article describes a cellular instability and laminar burning velocity of simulated synthetic natural gas(SNG) including 3% hydrogen. In this study, experimental apparatus is employed using cylindrical bomb combustor, and investigation is carried out with high speed camera and Schlieren system. The cellular instability is caused by the buoyancy, hydrodynamic instability. Unstretched burning velocity can be determined by extrapolated stretch rate of zero point from measured results. These results were also compared with numerical calculation by Chemkin package with GRI 3.0, USC-II, WANG, C3 Fuel mechanism. As an experimental conditions, equivalence ratios was adjusted from 0.8 to 1.3. From results of this work, the one was found that the cellular instability has occurred by effect of thermal expansion rate and flame thickness. As the other results, unstretched laminar burning velocity was best coincided with GRI 3.0 mechanism.

• Journal of the Korean Society of Safety
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• v.24 no.1
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• pp.14-20
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• 2009

Direct numerical simulations(DNS) were performed for the prediction of transient buoyant jet diffusion flames where the Froude numbers(Fr) are 5 and 160, respectively. The thermodynamic and transport properties were evaluated using CHEMKIN package to enhance the prediction performance of the DNS code. The simulated buoyant jet diffusion flame of Fr=5 and 160 showed the transient, dynamic motion well. It was identified that the buoyant jet flames were flickered periodically, and the simulated flickering frequency of the jet diffusion flame of Fr=5 was 12.5Hz, which was in good agreement with the experimental results. The flamelet structures of the buoyant jet diffusion flames could be well understood by comparing the scalar dissipation rates(SDR) and the heat release rates(HRR) of the flames. It was found that the SDR was strongly coupled with the HRR in the buoyant jet diffusion flames.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.215-218
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• 2012

In this study, syngas laminar burning velocities with various hydrogen contents were studied using both experimental measurements and kinetic simulations. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including burning velocities were made using CHEMKIN Package with USC-Mech II. A large range of syngas mixture compositions such as 10:90%, 25:75%, 50:50%, 75:25% and equivalence ratio from lean condition of 0.5 to rich condition of 5.0 have been conducted. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increasing of $H_2$ content although the flame speed of hydrogen is faster about ten times than carbon monoxide. This phenomenon is attributed to the rapid production of the hydrogen related radicals such as H and OH at the early stage of combustion, which is confirmed the linear increasing of radical concentrations on kinetic simulation.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.737-746
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• 2016

This article describes a comparison on laminar burning velocity measured by Bunsen and spherical flame methods of synthetic natural gas (SNG) with various composition of hydrogen. In this study, the laminar burning velocity measurements were employed by Bunsen burner and cylindrical constant combustor at which flame images were captured by Schlieren system. These results were also compared with numerical based on CHEMKIN package with GRI 3.0, USC-II and UC Sandiego mechanism. In case of spherical flames, the suitable flame radius range and theoretical models were verified using the well-known previous results in methane/air flames. As an experimental condition, hydrogen content of SNG was adjusted 0% to 11%. Equivalence ratios of Bunsen flames were adjusted from 0.8 to 1.6. On the other hand, those of spherical flames were adjusted from 0.6 to 1.4, relatively. From results of this study, the both laminar burning velocities measured in Bunsen and spherical flame methods were resulted in similar tendency. As the hydrogen content increased, the laminar burning velocity also increased collectively. Laminar burning velocity of measured SNG-air flames was best coincided with GRI 3.0 mechanism by comparison of reaction mechanisms.