• Title/Summary/Keyword: CH Chemiluminescence

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The Dependency of CH* Chemiluminescence of a Laminar Premixed Flame on Fuel Types (연료에 따른 층류 예혼합화염의 CH* Chemiluminescence 신호특성 변화)

  • Lee, Won-Nam;Kang, Suk-Min
    • Journal of the Korean Society of Combustion
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    • v.13 no.2
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    • pp.14-22
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    • 2008
  • The CH* chemiluminescence of premixed flames and their dependency on fuel types has been experimentally investigated on laminar methane and propane premixed flames. The measured chemiluminescence intensities are observed linearly proportional to the fuel flow rate, which could be interpreted as the CH* chemiluminescence signal is linearly proportional to the heat release rate under fuel lean conditions. The effect of equivalence ratio could be expressed by an exponential function as ${I_{CH*}}^{\propto}\;a_1\;{\exp}(b_1{\Phi})$, where $a_1\;=\;0.00054$ and $b_1\;=\;4.60$ for methane and $a_1\;=\;0.0056$ and $b_1\;=\;5.02$ for propane. Oscillating flames showed the temporal fluctuation of chemiluminescence intensity: however, the time averaged values are virtually identical to those of quiescent flames under the same fuel flow rate and equivalence ratio conditions. This observation suggests that there is no significant flame stretch effect on chemiluminescence intensity, in average values.

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A Study on chemiluminescence characteristics of a turbulent flame for different measurement location (난류 확산화염의 계측 위치에 따른 화염자발광 특성에 대한 연구)

  • Kwon, Minjun;Lee, Changyeop;Kim, Sewon
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.219-222
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    • 2014
  • The flame chemiluminescence is a good tracer of flame statement. In this study, the characteristics of flame chemiluminescence($OH^*$, $CH^*$, ${C_2}^*$) according different measuring locations using photomultiplier(PMT), spectrometer and CCD camera. Measurements are made for $OH^*$, $CH^*$, ${C_2}^*$ radicals in gas & light oil diffusion flames. At turbulent nonpremixed combustion mode, the equivalence ratio is varied. The experimental results showed that measuring location affects the result of flame chemiluminescence.

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$CO_2^*$ Background Effect on $OH^*$ and $CH^*$ Chemiluminescence Intensities in a Gas Turbine Combustor (가스터빈 연소기에서 $CO_2^*$ 배경 강도가 $OH^*$$CH^*$ 화학 발광 강도에 미치는 영향)

  • Kim, Dae-Sik;Lee, Jong-Guen
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.37-42
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    • 2010
  • The measurement of heat release rate is of great importance in the study of thermo-acoustic instability occurring in lean premixed combustion and the chemiluminescence emission has been used as an indicator of heat release in combustion instability studies primarily for its relative simplicity. This paper presents results of experimental study of flame chemiluminescence from an atmospheric, swirl-stabilized, turbulent lean premixed flame with a main emphasis on the effect of $CO_2^*$ background level in the $CH^*$ and $OH^*$ band. The test results show that the effect of $CO_2^*$ level in the $CH^*$ band is greater than that in the $OH^*$ band. Also, the background to peak ratio for both $CH^*$ and $OH^*$ bands can be expressed as a function of equivalence ratio, almost regardless of a change in the inlet velocity.

OH-and CH-Radical Chemiluminescence Characteristics in the Spray Combustion of Ultransonically Atomized Kerosene (초음파에 의해 무화된 케로신 분무연소에서의 OH 라디칼 및 CH 라디칼 자발광 특성)

  • Kim, Min Cheol;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.72-79
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    • 2018
  • An experimental study was performed to investigate the chemiluminescence characteristics in the spray combustion of ultransonically atomized kerosene. The radical intensity of the spray flame was measured using an ICCD camera and the amount of fuel consumed was obtained by a precise flow-rate measurement technique during combustion. Fuel consumption increased linearly with the increase in carrier-gas flow rate, and typical group combustion, which is a characteristic of spray combustion, was observed. It was found from the analysis of chemiluminescence that the maximum emission intensities of OH and CH radicals decrease, and they move downstream resulting in the increase in a vivid reaction zone as the spray flow rate increases.

Detailed Local Chemiluminescence Measurement (OH*, CH* and C2*) and Nitrogen Oxides Emissions in Laminar Partially Premixed CH4/Air Flames (메탄/공기 층류 부분예혼합화염의 상세 라디칼(OH*, CH* 그리고 C2*) 정보와 배기매출물에 관한 실험적 연구)

  • Jeong Yong Ki;Oh Jeong Seog;Jeon Chung Hwan;Chang Young June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.263-270
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    • 2005
  • An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $0.79{\sim}{\infty}$, on NOx emissions and chemiluminescence of excited $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ radicals in laminar partially premixed flames. the signal from the electronically excited state of $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, which are processed to the intensity ratio ($C_2^{\ast}/CH^{\ast},\;C_2^{\ast}/OH^{\ast},\;and\;CH^{\ast}/OH^{\ast}$) to reveal the correlation with local equivalence ratio. And measurements of NOx emission were made to investigate the relationship between visible flame appearance, chemiluminescence, and EINOX. The results demonstrated that (1) the flames at ${\phi}<1.59$ exhibited classical double flame structure, at ${\phi}>4.76$, the flames exhibited diffusion flame structure, and the intermediate flames at $1.59<{\phi}<4.76$ was a merged flame, (2) the $OH^{\ast}$ peak was located inside the $CH^{\ast}\;and\;C_2^{\ast}$ radical for all measured conditions and the emission intensity ratio of $C_2^{\ast}/CH^{\ast}\;and\;C_2^{\ast}/OH^{\ast}$ were identified as good marker for local equivalence ratio over a range of ${\phi}=0.79{\sim}1.2\;and\;CH^{\ast}/OH^{\ast}\;is\;0.79<{\phi}<1.9$. However, it was difficult to predict the equivalence ratio in partially premixed flames using this system for ${\phi}>2.38$, (3) the minimum NOX emission index (EINOx) is obtained for a equivalence ratio of 3.19 in the intermediate flames.

Characteristics of Chemiluminescence Intensities of Kerosene/Air Swirl Flames (케로신/공기 와류 화염의 화학발광 세기 특성에 관한 실험적 연구)

  • Lee, Hyeonjae;Seo, Seonghyeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.485-496
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    • 2015
  • The present study presents experimental results on the characteristics of emission spectra of kerosene/air swirl flames. The aviation fuel Jet A-1, which is used for the liquid rocket engines of the Korea Space Launch Vehicle, is used with three different swirlers to investigate the swirl strength effects. The emission spectra from the flames are measured with a spectrometer as the swirl strength and combustion air temperature are varied. Chemiluminescence intensities of $OH^*$, $CH^*$ and $C_2{^*}$ are identified from the spectra. The chemiluminescence intensities from the kerosene flames show sensitivity to the swirl strength and are affected by changes in the combustion air temperature. Among the three radicals of interest, $C_2{^*}$ show the most significant changes in chemiluminescence intensity with the swirl strength and equivalence ratio. The intensity ratios $I_{OH^*}/I_{CH^*}$ and $I_{C_2{^*}}/I_{CH^*}$ are adequate for indicating changes in the equivalence ratio with the air and fuel mass flow rates, respectively.

A Study of Characteristics of Combustion Radical and Exhausted Emissions in a Radiant Burner with Porous Ceramic Mat (다공성 세라믹 매트를 이용한 복사버너에서의 연소라디칼 특성과 배기배출물에 관한 연구)

  • Kim, Young-Su;Cho, Seung-Wan;Kim, Gyu-Bo;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.6 s.261
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    • pp.539-546
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    • 2007
  • An experimental study was performed to investigate the characteristics of chemiluminescence in a radiant burner, varying the excess air ratio from 0.91 to 1.67 at firing rate 80.5 to 134.2 kW/m2 on $OH^*,\;CH^*,\;{C_2}^*$ in LNG-Air premixed flames. The signals from electronically excited states of $OH^*,\;CH^*,\;{C_2}^*$ were detected using a Intensified Couple Charged Detector (ICCD) camera. The measurements of exhausted emission were made to investigate the correlation between chemiluminescence and emissions. The chemiluminescence intensity was increased with increase of firing rate like characteristics of $NO_x$ emission. $NO_x$ also increased with increase of firing rate and excess air ratio. It is found that offset of firing rate is more dominant excess air ratio $NO_x$ emission. The maximum chemiluminescence intensity occurs near the stoichiometric excess air ratio or lean conditions in case of high firing rate and the maximum intensity occurs rather than rich conditions in case of relatively low firing rate. Amount of $NO_x$ emission is maximum at near stoichiometric excess air ratio, which is chemiluminescence intensity is maximum.

Analysis of Stratified Co-Flow Flames from Chemiluminescence Images (화염 발광 가시화를 이용한 성층화된 동축류 화염 특성 분석)

  • Ahn, Taekook;Nam, Younwoo;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.185-187
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    • 2012
  • The characteristics of stratified co-flow flames have been investigated from the flame chemiluminescence images. The fuel lean premixed flame could be stabilized with a fuel rich premixed flames that is generated with the supply of fuel through the inner nozzle. The penetration of outer region lean premixture into the fuel stream produced a lifted rich premixed flame at the center. Chemiluminescence images of OH, CH, and $C_2$ radicals indicated that the way of stratification of fuel/air mixture under various operating conditions.

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Detailed Spectroscopic Measurements of Chemiluminescence from Turbulent Premixed Flames in a Dump Combustor

  • Santavicca, D.A.;Lee, Jong-Guen
    • Journal of the Korean Society of Combustion
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    • v.9 no.3
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    • pp.19-26
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    • 2004
  • This paper presents results of experimental study of flame chemiluminescence from turbulent premixed flames in a dump combustor. A detailed spectroscopic measurement of chemiluminescence over the wavelength of 405-495 nm is made for various flow conditions. No effect of turbulence on the relationship between chemiluminescence and heat release is found, suggesting the overall chemiluminescence intensity collected be used as a measure of overall heat release for non-oscillating stable flame. The background-$CO_2^*$ subtracted $CH^*$ chemiluminescence is found to be more sensitive to the equivalence ratio and premixedness of fuel-air mixture than $CO_2^*$ chemiluminescence.

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