• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.1
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• pp.29-35
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• 2001

Radiation-induced oscillatory instability in CH$_4$/Air diffusion flames is numerically investigated by adopting detailed chemistry. Counterflow diffusion flame is employed as a model flamelet and optically thin gas-phase radiation is assumed. Attention is focused on the extinction regime induced by radiative heat loss, which occurs at low strain rate. Once a steady flame structure is obtained for a prescribed value of initial strain rate, transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed on the steady flame. Depending on the initial strain rate and the amount of perturbed strain rate, transient evolution of the flame exhibits various types of flame-evolution behaviors. Basically, the dynamic behaviors can be classified into two types, namely oscillatory decaying solution and diverging solution leading to extinction.

• Journal of the Korean Society of Safety
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• v.17 no.3
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• pp.43-49
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• 2002

The NOx emission characteristics of double-concentric diffusion flames and normal diffusion flames fueled with CH$_4$ were studied. Experimental and numerical investigations were carried out for double-concentric diffusion flame with varying central air flow rate and normal diffusion flame. The Emission indices of NOx(EINOx) were measured by chemiluminescent method and calculated by numerical model based on detailed chemistry. From the comparison between double-concentric diffusion flames and normal diffusion flames, the results show that EINOx of double-concentric diffusion flames are lower than normal diffusion flame, because of Prompt EINOx was decreased. EINOx of double-concentric diffusion flames increase with central air flow rate increasing.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.949-955
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• 2000

Numerical study with detailed chemistry has been conducted to investigate the NOx formation and structure in $CH_4/Air-CO_2$ counterflow diffusion flames. The importance of radiation effect is identified and the role of $CO_2$ addition is addressed to thermal and chemical reaction effects, which can be precisely specified through the introduction of an imaginary species. Also NO separation technique is utilized to distinguish the contribution of thermal and prompt NO formation mechanisms. The results are as follows : The radiation effect is dominant at low strain rates and it is intensified by $CO_2$ addition. Thermal effect mainly contributes to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. It is noted that flame structure is changed considerably due to the addition of $CO_2$ in such a manner that the path of methane oxidation prefers to take $CH_4 {\rightarrow}CH_3{\rightarrow}C_2H_6{\rightarrow}C_2H_5$ instead of $CH_4 {\rightarrow}CH_3{\rightarrow}CH_2{\rightarrow}CH$. At low strain rate(a=10) the reduction of thermal NO is dominant with respect to reduction rate, but that of prompt NO is dominant with respect to total amount.

• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.31-45
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• 2001

The effect of adding carbon dioxide to methane-air flame was investigated experimentally. Measurements included extinction limits, flame temperature and photographic investigation of flame. A diffusion flame was stabilized between counterflowing streams of methane diluted with carbon dioxide and air diluted with carbon dioxide. Extinction limits and temperature for such flames were measured over a wide parametric range and were compared with those for other flames that fuel or oxidant was diluted with nitrogen or argon. The experimental results indicate that extinction phenomena can be explained by thermal effect and as an amount of carbon dioxide in fuel or oxidant increases, greatly as compared with other flames flame-temperature falls and flame-thickness is reduced.

• International Journal of Safety
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• v.2 no.1
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• pp.12-16
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• 2003

In Part 1, the flame structure of the counterflow nonpremixed flames computed by using Fire Dynamics Simulator was compared with that of OPPDIF for different concentrations of methane in the fuel stream. In this study, comparisons were made for the global strain rate that is an important parameter for diffusion flames for further evaluation of FDS. At each of the three fuel concentrations, $20% CH_4＋ 80% N_2, 50% CH_4 ＋ 50% N_2, 90% CH_4 ＋ 10% N_2$ in the fuel stream, the temperature and axial velocity profiles were investigated for the global strain rate in the range from 20 to $100s^{-1}$. Changes in flame thickness and radius were also compared with OPPDIF. There was good agreement in the temperature and axial velocity profiles between the axisymmetric simulations and the one-dimensional computations except for the regions where the flame temperature reach its peak and the axial velocity rapidly changes. The simulations of the axisymmetric flames with FDS showed that the flame thickness decreases and the flame radius increases with increasing global strain rate.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.113-122
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• 2000

Dynamic structures of unsteady $CH_4$/Air jet diffusion flames with flame-vortex interaction were numerically investigated. A time-dependent, axisymmetric computational model was adopted for this calculation. Two step global reaction mechanism which considers 6 species, was used to calculate the reaction rates. The predicted results including gravitational effect show that the large outer vortices and the small inner vortex street can be well simulated without any additional disturbances in the downstream of nozzle tip. It was found that the temperature and species concentrations had various values for the same mixture fraction in flame-vortex interaction region. This unsteady jet flame configuration accompanying flame-vortex interaction is expected to give good implications for the structure of turbulent flames.

• 한국연소학회:학술대회논문집
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• 2002.11a
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• pp.11-17
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• 2002

The first-order conditional moment closure (CMC) model is applied to $CH_4$/Air turbulent jet diffusion flames(Sandia Flame D, E and F). The flow and mixing fields are calculated by fast chemistry assumption and a beta function pdf for mixture fraction. Reacting scalar fields are calculated by elliptic CMC formulation. The results for Flame D show reasonable agreement with the measured conditional mean temperature and mass fractions of major species, although with discrepancy on the fuel rich side. The discrepancy tends to increase as the level of local extinction increases. Second-order CMC may be needed for better prediction of these near-extinction flames.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.1
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• pp.1-8
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• 2004

An study has been performed with axisymmetric coflow diffusion flames to investigate the influence of air-side fuel side dilution and initial preheated temperature on the soot formation in methan/air flames. Soot quantities are determined by using PLII(Planar Laser Induced Incandescence), such a $C_2$H$_2$ major species(CH$_4$, $O_2$, $N_2$) and temperature are simulated by chemkin code. The numerical analysis was performed with transport properties and detailed reaction mechanisms m axisymmetric coflow diffusion flames. The study of how flame temperature and $N_2$ dilution of air and fuel side influence the soot concentrations is focused. Soot concentrations results on PLII show that preheated temperature contributes to an increase in the soot volume fraction, and soot formation Is more productive to air side dilution than to fuel side dilution. $C_2$H$_2$ concentrations have a similar tendency to soot concentrations.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.129-136
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• 2003

Numerical study with momentum-balanced boundary conditions has been conducted to grasp chemical effects of added $CO_{2}$ and $H_{2}O$ to fuel- and oxidizer-sides on flame structure and NO emission behavior in $CH_{4}$/Air counterflow diffusion flames. The dilution with $H_{2}O$ results in significantly higher flame temperatures and NO emission, but dilution with $CO_{2}$ has much more chemical effects than that with $H_{2}O$. Maximum reaction rate of principal chain branching reaction due to chemical effects decreases with added $CO_{2}$. but increases with added $H_{2}O$. The NO emission behavior is closely related to the production rate of OH, CH and N. The OH radical production rate increases with added $H_{2}O$ but those of CH, N decrease. On the other hand the production rates of OR CH and N decrease with added $CO_{2}$. It is found that NO emission behavior is considerably affected by chemical effects of added $CO_{2}$ and $H_{2}O$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.2 s.233
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• pp.263-270
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• 2005

An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $0.79{\sim}{\infty}$, on NOx emissions and chemiluminescence of excited $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ radicals in laminar partially premixed flames. the signal from the electronically excited state of $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, which are processed to the intensity ratio ($C_2^{\ast}/CH^{\ast},\;C_2^{\ast}/OH^{\ast},\;and\;CH^{\ast}/OH^{\ast}$) to reveal the correlation with local equivalence ratio. And measurements of NOx emission were made to investigate the relationship between visible flame appearance, chemiluminescence, and EINOX. The results demonstrated that (1) the flames at ${\phi}<1.59$ exhibited classical double flame structure, at ${\phi}>4.76$, the flames exhibited diffusion flame structure, and the intermediate flames at $1.59<{\phi}<4.76$ was a merged flame, (2) the $OH^{\ast}$ peak was located inside the $CH^{\ast}\;and\;C_2^{\ast}$ radical for all measured conditions and the emission intensity ratio of $C_2^{\ast}/CH^{\ast}\;and\;C_2^{\ast}/OH^{\ast}$ were identified as good marker for local equivalence ratio over a range of ${\phi}=0.79{\sim}1.2\;and\;CH^{\ast}/OH^{\ast}\;is\;0.79<{\phi}<1.9$. However, it was difficult to predict the equivalence ratio in partially premixed flames using this system for ${\phi}>2.38$, (3) the minimum NOX emission index (EINOx) is obtained for a equivalence ratio of 3.19 in the intermediate flames.