• Journal of Korean Society for Atmospheric Environment
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• v.10 no.1
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• pp.41-48
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• 1994

A monitoring system for atmospheric CFC-12 and CFC-11 has been established at Mt. Kwan-Ak, Seoul National University (SNU) since July, 1991. The concentrations showed quite a large variation ranging from 495 to 37600 pptv (pptv=part per trillion, 10$^{-12}$ , v/v) for CFC-12 and from 233 to 12100 pptv for CFC-11 due to many local sources. However, monthly medians show rather limited ranges ; 553~765 pptv for CFC-12 and 301~431 pptv for CFC-11. Furthermore minimum concentrations could be defined relatively well during the whole period of observation. The regional background concentrations in 1993 near SNU wer estimated as 533 pptv for CFC-12 and 293 pptv for CFC-11. These values are very comparable to global averages in Northern Hemisphere, 523 pptv for CFC-12 and 287 pptv for CFC-11, reflecting the fast atmospheric mixing processes within the hemisphere. Examinations with meteorological parameters such as wind speed and direction suggest the possible measurement-window at SNU, appropriate for regional monitoring. Studies for improving the monitoring capability of the SNU station such as automation of the analysis system along with correlation with other meteorological parameters, are in progress at the present time.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.5
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• pp.569-580
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• 1998

In this study, condensation heat transfer coefficients(HTCs) of a plain tube, low fin tube, and Turbo-C enhanced tube for CFC-11, HCFC-123, CFC-12, HFC-l34a are measured and compared against each other. All data are taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling temperature 3~8$^{\circ}C$. Test results show that HTCs of a low vapor pressure refrigerant, HFC-123, for a plain, low fin, and Turbo-C tubes are 10.5~20.5%, 8.2~12.2%, 16.5~19.2% lower than those of CFC-11, respectively. On the other hand, HTCs of a medium vapor refrigerant, HFC-l34a, for a plain, low fin, and Turbo-C tubes are 20.6~31.8%, 0.0~8.0%, 13.2~20.9% higher than those of CFC-12, respectively. For all refrigerants tested, HTCs of Turbo-C tube are the highest among the three tubes showing almost 8 times increase in HTCs as compared to those of a plain tube. Nusselt's prediction equation for a plain tube yielded 12% deviation for all plain tube data while Realty and Katz's prediction equation for a low fin tube yielded 20% deviation for all low tube data.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.6
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• pp.830-840
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• 1997

In this study, condensation heat transfer coefficients(HTCs) of CFC-11, HCFC-123 and HCFC-141b are measured, which are used/or considered as working fluids in centrifugal chillers. The main objectives of this study are to measure and compare the HTCs of various refrigerants on plain and low fin tubes and also to find out the optimum fin density of the low fin tubes. To accomplish these goals, HTCs of three refrigerants are measured for the plain tube as well as 4 types of low fin tubes. All measurements are carried out at the vapor temperature of 39.deg. C with the wall temperature difference of 3 .deg. C ~ 8.deg. C. For all the refrigerants tested, a low fin tube of 28 fins per inch yielded the best performance among all the tubes tested. For the plain tube, the HTCs of CFC-11 and HCFC-141b were very similar and those of HCFC-123 were 10% lower than those of CFC-11.Thus, it can be concluded that HCFC-123 and HCFC-141b are acceptable as alternative refrigerants for CFC-11 from the view point of condensation heat transfer.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.6 no.4
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• pp.365-379
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• 1994

Pool boiling experiments were carried out to study the effect of electric field on nucleate boiling heat transfer. CFC-11 and its alternative HCFC-123 were used as working fluids. Boiling on both single tube and a bundle of five tubes was investigated. Heat flux varied from 5 to $25kW/m^2$ while the applied voltage changed from 0 to 1kV. The results showed that at low heat flux where boiling was not present or very weak, electric field-induced forced convection helped increase the heat transfer coefficients of CFC-11 and HCFC-123 significantly(4-15 times increase). However, at higher heat flux, nucleate boiling of CFC-11 which is a highly dielectric fluid, was not affected significantly by the application of electric field. In contrast to CFC-11, even at high heat flux, nucleate boiling of CFC-11 which has a relatively larger electric conductivity than CFC-11, was vigorously increased up to 2-4 times. The additional power required to apply the electric field was 1-2% of the total power consumption by the heater. The increase in overall heat transfer coefficient of evaporators with HCFC -123 was about 40%, suggesting a considerable reduction in evaporator size with EHD technique.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.9
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• pp.2316-2327
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• 1995

Experimental results from nucleate pool boiling heat transfer with various finned tubes in CFC11, HCF123 and HCFC141b are reported. One plain tube and four low fin tubes of various fin densities were tested in an attempt to find out the optimum fin density in the heat flux range of 10-60 kW/m$^{[-992]}$ at near atmospheric pressure. The results indicated that CFC11 showed the highest heat transfer coefficients. Its alternatives, HCFC123 and HCFC141b, showed 3-5% lower heat transfer coefficients than those of CFC11 at the same heat flux. As the fin density increases, so does the heat transfer surface area. Measured heat transfer coefficients, however, do not necessarily always increase as the fin density increases. This unique phenomenon seems to be caused by the coalescence of the bubblers that prevent the cool liquid from entering into the fin valleys. For all the refrigerants tested, the optimum fin density yielding the highest performance was 28 fins per inch confirming the previous results by other researchers.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.28 no.5
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• pp.389-395
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• 1999

냉동공조설비, 발전설비, 화학플랜트설비 등에 사용되는 응축기는 주로 증기가 관의 외부에서 응축을 하고 냉각수가 관 내부로 흐르는 쉘-튜브(shell and tube)형 태를 취하고 있다. 초기투자비용 및 운전비용을 줄이기 위해서는 응축기의 열교환 성능을 향상시키는 일이 필수적이며 이를 위해 코팅 표면(coated surfaces), 거친 표면(rough surfaces), 코일 튜브(coiled tubes), 선회 흐름장치(swirl flow), 전열면적을 넓힌 낮은 핀관과 3차원 형상을 갖는 열전달 촉진관의 사용이 제시되고 있다.

• Polymer Science and Technology
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• v.2 no.2
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• pp.99-104
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• 1991

• Bulletin of the Korean Chemical Society
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• v.22 no.11
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• pp.1273-1276
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• 2001

• Journal of Soil and Groundwater Environment
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• v.8 no.2
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• pp.1-8
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• 2003

Two types of ground-water sampling techniques for CFCs (chlorofluorocarbons) analysis, the cold-welded copper tube method and flame-sealed borosilicate glass ampule method, were compared and evaluated. CFCs concentrations by the copper tube method showed a poor reproducibility among triplicates whereas those by the glass ampule method showed a good agreement and relative standard deviations of triplicates were less than 5%. The poor reproducibility of the copper tube method appears to be attributed to the incomplete sealing in connection between faucets of wellhead and the sampling apparatus. The copper tube method also showed higher CFCs concentrations than the glass ampule method, which is more pronounced for CFC-11 than for CFC-12. The plastic tubings and rubber gasket of faucets in case of the copper tube method possibly contaminated the samples with CFC-11 and CFC-12. The potential of CFCs contamination for the glass ampule method was eliminated by using stainless steel and Nylon only and by connecting the sampling equipment directly to the main discharge pipe of wellhead. The validity of the glass ampule method were also verified by detecting very low level of CFCs for the ground-water sample which is old enough to have negligible CFCs.

• Journal of the Korean Institute of Gas
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• v.9 no.1 s.26
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• pp.16-20
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• 2005

CFC-11 and HCFC-l4lb have been used as blowing agents for rigid polyurethane foam insulation of LNG storage tank. But CFC-11 and HCFC- l4lb deplete ozone layer in the stratosphere. So in leading countries, the use of CFC-11 has been prohibited since 1995 and the use of HCFC-l4lb will be prohibited from 2005. Much efforts and studies have been done about alternative blowing agents and insulations blown by alternative blowing agents. This paper deals with polyurethane foams (PUFs) blown by HFC-365mfc, shows their physical and mechanical characteristics and thermal performance. These data are compared with the results of PUFs blown by HCFC-l4lb. From these test results, PUFs blown by HFC-365mfc show good mechanical and thermal characteristics. It is possible to use PUFs blown by HFC-365mfc as main insulation of membrane type LNG storage tank.