• Title/Summary/Keyword: CFC

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Analysis on the contamination and source of VOCs in groundwaters of Gwangju area (광주광역시의 지하수 중 휘발성유기화합물(VOCs)의 오염과 오염원 분석)

  • Yun, Uk;Cho, Byong-Wook;Eum, Chul-Hun;Sung, Ik-Hwan
    • The Journal of Engineering Geology
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    • v.13 no.4
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    • pp.389-404
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    • 2003
  • VOCs were detected in the 21 groundwaters out of 37 groundwaters sampled from around the Hanam Industrial Complex and the Gwangju stream. Ten components of chlorinated aliphatic hydrocarbons of VOCs were detected in the 18 groundwater samples. Among them, total trihalomethanes (TTHM) concentration is in the range of $0.1~36.2{\;}\mu\textrm{g}/L$, CECs concentration is $2.3~190{\;}\mu\textrm{g}/L$, and chlorinated solvents concentration containing PCE, TCE, etc. is $0.1~124.2{\;}\mu\textrm{g}/L$ respectively. Ten components of the aromatic hydrocarbons of VOCs were detected in the 5 groundwater samples, but their concentration are less than $1{\;}\mu\textrm{g}/L$. Detection frequency and concentration of the chlorinated aliphatic hydrocarbons components from the groundwaters in the Hanam Industrial Complex are higher than those of nearby downtown Gwangju stream. VOCs components except for TCE are lower than the MCL of USGS drinking water standard. TCE concentration of the 2 groundwater samples is over MCL, whose concentrations are 5 and 25 times higher than MCL, respectively. TCE is detected from the H8 and H10 groundwater samples and CFCs is detected H8 and H11 groundwater samples in the Hanam Industrial Complex. TTHM in study area is estimated from leakage of the main waters or sewage waters. Because most of the studied groundwater is under an aerobic condition, aromatic hydrocarbons are well degraded. But chlorinated aliphatic hydrocarbons are degraded very slowly.

Life Cycle Assessment on Process of Wet Tissue Production (물티슈 제조공정의 전과정 평가)

  • Ahn, Joong Woo
    • Clean Technology
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    • v.24 no.4
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    • pp.269-274
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    • 2018
  • In this study, Life Cycle Assessment (LCA) of wet tissue manufacturing process was performed. The wet tissue manufacturing process consists of preparation of wetting agent (chemical liquid), impregnation of nonwoven fabric into wetting agent and primary and secondary packaging. Data and information were collected on the input and output of the actual process from a certain company and the database of the Korea Ministry of Environment and some foreign countries (when Korean unavailable) were employed to connect the upper and the lower process flow. Based on the above and the potential environmental impacts of the wet tissue manufacturing process were calculated. As a result of the characterization, Ozone Layer Depletion (OD) is 3.46.E-06 kg $CFC_{11}$, Acidification (AD) is 5.11.E-01 kg $SO_2$, Abiotic Resource Depletion (ARD) is $3.52.E+00\;1yr^{-1}$, Global Warming (GW) is 1.04.E+02 kg $CO_2$, Eutrophication (EUT) is 2.31.E-02 kg ${PO_4}^{3-}$, Photochemical Oxide Creation (POC) was 2.22.E-02 kg $C_2H_4$, Human Toxicity (HT) was 1.55.E+00 kg 1,4 DCB and Terrestrial Ecotoxicity (ET) was 5.82.E-04 kg 1,4 DCB. In order to reduce the environmental impact of the manufacturing process, it is necessary to improve the overall process as other general cases and change the raw materials including packaging materials with less environmental impact. Conclusively, the energy consumed in the manufacturing process has emerged as a major issue, and this needs to be reconsidered other options such as alternative energy. Therefore, it is recommended that a process system should be redesigned to improve energy efficiency and to change to an energy source with lower environmental impact. Due to the nature of LCA, the final results of this study can be varied to some extent depending on the type of LCI DB employed and may not represent of all wet tissue manufacturing processes in the current industry.

Measurement of R-134a Leakage from Vehicle Equipped Mobile Air Conditioning(MAC) System (실차를 이용한 자동차 에어컨 냉매 누출량 평가)

  • Kim, Ji Young;Seo, Chungyoul;Lee, Sangeun;Kim, Jeongsoo
    • Journal of Climate Change Research
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    • v.3 no.2
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    • pp.153-159
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    • 2012
  • CFC-12 used in mobile air conditioning(MAC) system has been replaced by R-134a, a type of HFC refrigerant, from 1991 to 1994. R-134a has since been widely used as a refrigerant of a mobile air conditioner. However, it is one of the six main green house gases listed in Kyoto Protocol, which makes it imperative to regulate its emission and develop alternative refrigerants. In this study, the concentration of leaked R-134a was measured using VT(Variable Temperature) shed and Running loss test shed to analyze the level of air conditioner refrigerant leaked in a vehicle. According to the analysis of the concentration of R-134a leaked from a vehicle parked, annual leakage amount of R-134a was in the range of 6.46~13.28 g/yr. The figure was similar with the leakage from the mobile air conditioning system currently used. In a study using the same vehicle model, a vehicle equipped with dual evaporation system had a higher leakage rate of refrigerant than a vehicle with a single evaporation system. It appears that the added fittings and joints of the dual evaporator system led to higher leakage rate. Besides, the analysis of the change in R-134a concentration under various car speed found that more refrigerant leaked under high speed(100km/hr) and but the volume of the wind did not affect to the variation of refrigerant leakage.

Estimates of Basin-Specific Oxygen Utilization Rates (OURs) in the East Sea (Sea of Japan) (동해 각 분지의 수층내 산소 소모율 추정)

  • Kim, Il-Nam;Min, Dong-Ha;Lee, Tong-Sup
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.15 no.2
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    • pp.86-96
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    • 2010
  • The oxygen utilization rate (OUR) is one of the crucial parameters for ocean carbon cycling and climate models. However, parameterization of OUR in the East Sea (Sea of Japan) is yet to be established. We estimated the basin-specific OURs in the East Sea and fitted them with exponential functions with depth by using pCFC- 12 age and apparent oxygen utilization (AOU) measured in summer 1999. The estimated OURs are higher in the upper water column and decrease with depth, in general. The vertical distributions of the estimated OURs in the Western and Eastern Japan Basins (WJB & EJB) are very similar. The OURs in the Ulleung Basin (UB) varied greatly depending on whether the surface layer (0~200 m) data are included in the OUR estimate or not. Apparently, weaker oxygen consumption occurs in the deep layer of Yamato Basin (YB). The ranges of the OURs between 200 m and 2000 m at WJB, EJB, UB, and YB are 8.15~0.83, 8.11~0.68, 5.29~0.73, and 7.31~0.06 ${\mu}mol$ $kg^{-1}$ $yr^{-1}$, respectively. Consideration of the wintertime surface water oxygen disequilibrium condition in estimating the OUR will be necessary in the future study.

A Study on the Performance of the Condensation and the Boiling Heat Transfer of Low Fin Tubes Used in Cooling of the Cutting Oil (절삭유 냉각용 낮은 핀관의 응축 및 비등 열전달 성능에 관한 연구)

  • 이종선
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.8 no.4
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    • pp.68-78
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    • 1999
  • Heat transfer performance is studied for boiling and condensation of R-11 on integral-fin tubes. Nine tubes with trapezoidal integral-fins having fin densities from 748 to 1654fpm and 10,30 grooves and finned tubes with caves of 0.55 and 0.64 mm height respectively are tested. in case of condensation CFC-11 condensates at saturation stat of 32$^{\circ}C$ on the outside surface cooled by inside cooling water flows. And in case of boiling the refrigerant evaporates at a saturation state of 1 bar on the outside tube surface and heat is supplied by hot water which circulates inside of the tube,. The tube having fin transfer coefficient concerns fin tubes with caves show higher valve than low fin tube having find density of 1299fpm and 30grooves. The overall heat transfer coefficient of fin tube with caves is about 5155 W/mK at 2.8m/s of water velocity, The value is abuot 2.7 times higher than plain tube and 1.3 times higher than low fin tube having fin density of 1299fpm and 30 grooves.

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A Study on the Performance of the Condensation and the Boiling Heat Transfer of Low Fin Tubes Used in Cooling of the Cutting Oil (절삭유 냉각용 낮은 핀관의 응축 및 비등 열전달 성능에 관한 연구)

  • Jo, Dong Hyeon;Lee, Jong Seon
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.8 no.4
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    • pp.65-65
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    • 1999
  • Heat transfer performance is studied for boiling and condensation of R-11 on integral-fin tubes. Nine tubes with trapezoidal integral-fins having fin densities from 748 to 1654fpm and 10,30 grooves and finned tubes with caves of 0.55 and 0.64 mm height respectively are tested. in case of condensation CFC-11 condensates at saturation stat of 32℃ on the outside surface cooled by inside cooling water flows. And in case of boiling the refrigerant evaporates at a saturation state of 1 bar on the outside tube surface and heat is supplied by hot water which circulates inside of the tube,. The tube having fin transfer coefficient concerns fin tubes with caves show higher valve than low fin tube having find density of 1299fpm and 30grooves. The overall heat transfer coefficient of fin tube with caves is about 5155 W/mK at 2.8m/s of water velocity, The value is abuot 2.7 times higher than plain tube and 1.3 times higher than low fin tube having fin density of 1299fpm and 30 grooves.

The Numerical Analysis on Insulation Performance with Respect to the Envelope Geometries and Array of Evacuated Powder Panel in Rigid Foam/Evacuated Powder Composite Panels (혼합초단열재에서 진공분말패널의 외피형상 및 패널배열에 따른 단열성능해석)

  • Hong, J.K.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.497-509
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    • 1996
  • Evacuated powder insulations have long been known to have better thermal performance than existing commercially available insulators, such as fiber glass and CFC-blown foam. To make a composite powder panel, a series of individually evacuated panels was encapsulated in a rigid closed cell foam matrix. The panels were encapsulated in a thin glass sheet barrier to preserve the vacuum. The thermal conductivity of the individual panel was found to be $0.0062W/m^{\circ}K$ by experiment and the polyurethane foam above had a thermal conductivity of $0.024W/m^{\circ}K$. In this study, numerical analysis using finite element method was carried out to investigate insulation performance of rigid foam/evacuated powder composite panel with respect to panel geometries such as panel pitch, panel aspect ratio and panel area ratio. Numerical analysis has indicated that more optimal vacuum panel geometries, much lower overall thermal conductivities can be achieved.

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2MHz, 2kW RF Generator (2MHz, 2kW RF 전원장치)

  • Lee J.H.;Choi D.K.;Choi S.D.;Choi H.Y.;Won C,Y.;Kim S.S
    • Proceedings of the KIPE Conference
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    • 2003.07a
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    • pp.260-263
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    • 2003
  • When ICP(Inductive Coupled Plasma type etching and wafer manufacturing is being processed in semiconductor process, a noxious gas in PFC and CFC system is generated. Gas cleaning dry scrubber is to remove this noxious gas. This paper describes a power source device, 2MHz switching frequency class 2kW RF Generator, used as a main power source of the gas cleaning dry scrubber. The power stage of DC/DC converter is consist of full bridge type converter with 100kHz switching frequency Power amplifier is push pull type inverter with 2MHz switching frequency, and transmission line transformer. The adequacy of the circuit type and the reliability of generating plasma in various load conditions are verified through 50$\Omega$ dummy load and chamber experiments result.

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Studies on the Selective Oxidation of Niobium Containing Mixed Metal Oxide Catalysts (니오비움 함유 복합 금속산화물 촉매의 선택산화반응에 관한 연구)

  • Kim, Young-Chul;Kim, Hyeong-Ju;Moon, Dong-Ju
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.129-134
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    • 1998
  • Conversion of propane to acrylonitrile via ammoxidation was studied using physically mixed catalysts composed of $Nb_2O_5(10{\sim}30wt%)$ and $V_{0.4}Mo_1Te_{0.1}$. Catalytic activities of ammoxidation were improved by adding strong acidic niobium oxide to $V_{0.4}Mo_1Te_{0.1}$, the selectivities to acrylonitrile+propylene being remained constant. The maximum activity was obtained at the mixing ratio 25wt% niobium oxide in $Nb_2O_5-V_{0.4}Mo_1Te_{0.1}$. Niobium oxide was found to be a selective catalyst for the oxidative dehydrogenation of propane.

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An Experimental Study on the Performance of Heat Pump Assisted Batch Dryer Using HFC134a (HFC134a를 사용한 열펌프 건조기의 성능에 관한 실험적 연구)

  • Kim, Y.J.;Yim, C.S.
    • Solar Energy
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    • v.17 no.2
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    • pp.3-11
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    • 1997
  • In conventional heat and vent dryer, both sensible and latent heat could not be recovered from the exhaust air, but this problem could be solved by introducing a heat pump to a conventional dryer, having a connection with cooling, dehumidifying and heating of heat pump. In this work, HFC134a as a substitute refrigerant of CFC12 adopted in heat pump and a batch type is also introduced. The variables affected on the system performance are holding temperature of a drying chamber, bypass air ratio, degree of superheat and refrigerant flowrate, etc. The moisture contents were decreased curvilinearly in the range of $86{\sim}75%$ on the wet basis. Under the constant drying temperature, the face velocity plays an important role to the drying performance. The COPs are increased in accordance with the air velocity, on the other hand the SMERs are gradually decreased.

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