• Title/Summary/Keyword: CEC

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Composting of Sewage Sludge and Llum Sludge (하수슬러지와 Alum 슬러지를 이용한 퇴비화)

  • Chang, Ki Woon;Lim, Jae Shin;Lee, In Bog;Kim, Young Han
    • Journal of the Korea Organic Resources Recycling Association
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    • v.3 no.1
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    • pp.61-71
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    • 1995
  • This study is concerned with the assessment of the possibility of alum sludge composting, as well as changes of some chemical properties during composting. Alum sludge was mixed in different proportions, which are 0%, 25%, 35% and 45%, respectively, with a sewage sludge and sawdust mixture. The final mixtures to be composted are placed on static piles constructed with a perforated aeration pipe on the ground, and composted for more than 50 days. During the composting of some alum sludge treatments, there was not notable difference in changes of pH, C/N ratio, and content of several minerals among the alum sludge treatments, while changes of pile temperatures and CEC were significant and these remarkable differences in related to the pile temperatures and CEC seem suitable for the evaluation of alum sludge maturity. Also, the results suggested that the proper mixing ratio of alum sludge for composting was 25% level.

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HDMI Resolution Control of Smart Platform with WiFi Channel Analysis (WiFi 채널분석에 따른 스마트 플랫폼의 HDMI 해상도 조정)

  • Hong, Sung-Chan;Kang, Min-Goo
    • Journal of Satellite, Information and Communications
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    • v.11 no.2
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    • pp.23-28
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    • 2016
  • In this paper, we proposed the novel algorithm which controls the resolution of the HDMI(High Definition Multimedia Interface) by the channel estimation from WiFi-AP(Access Point) in the ISM(Industry-Science-Medical) band. The 2.4 and 5 GHz channel models are widely used since they have identical RF property as RSSI(Received Signal Strength Indication). Especially, the performance degradation of signal-transmission and streaming of WiFi will be occurred by the co-channel interference between AP(Access Point) and increased number of smart devices. Therefore, the optimization scheme of video format timing was designed by HDMI-CEC(Consumer Electronics Control) which considers the transmission speed of radio channel. The HDMI resolution, video quality of home-gateway and digital TV and the decision of PIP position can be maintained by the protocols between smart devices and DLNA(Digital Living Network Alliance) via proposed technique.

Effects of N. P. K and Organic Matters for 15-years Successive Application on Paddy Soil Properties. Plant Growth and Yield of Rice Plant (3요소 및 유기물의 연용이 답토양의 변화와 수도생육 및 수량에 미치는 영향)

  • 오윤진
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.4
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    • pp.431-438
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    • 1983
  • Experiments were conducted to know the effects of 15 years successive application of fertilizers and organic matters on the soil properties, plant growth and yield of rice. Application of fertilizers and organic matters for 15 years in same plots were increased soil pH, OM, and CEC, but decreased $SiO_2$ and Ca content in paddy soil. Organic matter application for 15 years was increased OM about 0.5% compare to non-applied plot. Particulary lime application was increased soil pH, $SiO_2$, Ca and CEC in paddy soil. NPK+compost and NPK+straw application were increased number of panicles and number of spikelets per unit area, but decreased ripening ratio compare to NPK applied plot. Average grain yield for 15 years in the non-fertilized, -N, -P, -K, NPK+compost, NPK+straw and NPK+lime applied plot was 47, 51, 88, 95, 113, 117, and 106% of yield conpare to NPK applied plot, respectively.

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Comparison of Derived Intervention Levels Against Contamination of Foodstuffs Using the Different Procedures Suggested by the Recognized Organizations (상이한 국제기관의 방법론에 따른 음식물 중 방사능의 유도개입준위의 비교)

  • Hwang, Won-Tae;Kim, Eun-Han;Han, Moon-Hee
    • Journal of Radiation Protection and Research
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    • v.26 no.4
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    • pp.433-440
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    • 2001
  • Using the different procedures suggested by the recognized organizations including IAEA, FDA, WHO and CED, derived Intervention levels (DILs) against contamination of foodstuffs were evaluated for considerations in radiological emergency planning in Korea. Three radionuclides important in terms of the consequence due to accidents at a nuclear power plant, i.e., $^{137}Cs,\;^{90}Sr$ and $^{131}I$, were considered. Intervention level for dose based on new recommendation of the ICRP (ICRP-60) was applied. The DILs tot the same foodstuff differ by up to afactor of 10. In most cases, the DILs based on FDA and WHO approaches were more conservative than those based on IAEA and CEC approaches. A critical age group for milk was infant of 3 month for all radionuclides. In most foods except milk, a critical age group was adult, 15yr and 5yr for $^{137}Cs,\;^{90}Sr$ and $^{131}I$, respectively.

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Quantification of Soil Properties using VNIR Spectroscopy (가시.근적외 분광 스펙트럼을 이용한 토양 특성 정량화)

  • Choe, Eun-Young;Hong, S.Young;Kim, Yi-Hyun;Song, Kwan-Cheol;Zhang, Yong-Seon
    • Proceedings of the KSRS Conference
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    • 2009.03a
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    • pp.121-125
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    • 2009
  • 농업과 환경분야에서 토양 상태를 신속하고 주기적으로 모니터링하는 것에 대한 관심이 높아지고 있다. 토양의 특성을 측정하는 기존의 화학분석 방식은 분석의 정밀도, 시료의 수, 분석항목 등에 따라 시간, 인력, 비용적 소모가 커진다. 최근에는 식품, 농업, 환경 분야에서 신속하고 비파괴적 분석 방법으로 가시 근적외선 분광학을 도입하고 있다. 가시 근적외선 영역(VNIR, 400-2400 nm)에는 다양한 물질의 고유한 흡수분광형태가 존재한다는 이론적 토대로부터 물질의 정성 정량적 분석이 가능하다고 알려져 있다. 본 연구에서는 VNIR 분광 스펙트럼으로부터 Al, organic carbon (OC), clay, silt, sand, CEC (Cation exchange capacity), CEC/clay 등의 토양 특성을 정량하고자 하였다. 농경지에서 채취한 94개 토양시료를 기존의 화학분석 방법으로 분석하고 실내에서 VNIR 스펙트럼을 측정하였다. 스펙트럼은 원시형태와, 1차, 2차 도함수로 변환된 형태 모두 partial least square regression (PLSR) 모델에 적용하였다. PLSR에 의한 토양특성 추정식은 RMSE, $R^2$, SDE, RPD 값을 이용하여 검증하였다. Al, OC, silt, sand 함량에 대해서는 통계적으로 유의한 수준의 추정값을 산출하였고, clay와 CEC/clay에 대해 추정한 값은 실측값과 약한 상관성을 나타내었다. 이러한 분광학적인 추정 기법은 영상을 이용한 정성 정량분석에 활용될 수 있을 것으로 사료된다.

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Adsorption and Leaching Characteristics of Nonionic Pesticides in Soils of Jeju Island, Korea (제주도 토양 중 비이온계 농약의 흡착 및 용탈 특성)

  • Chun, Si-Bum;Hyun, Ik-Hyun;Lee, Min-Gyu;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.27 no.7
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    • pp.561-575
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    • 2018
  • Agricultural soils around springwaters heavily affected by pesticide run-off and around wells considering the regional characteristics were collected at 24 stations in Jeju Island, and the physicochemical properties and adsorption and leaching characteristics of four nonionic pesticides (diazinon, fenitrothion, alachlor, and metalaxyl) were investigated. The values of the major soil factors affecting the adsorption and leaching of pesticides, namely, soil pH($H_2O$), organic matter content, and cation exchange capacity (CEC), were in the range of 4.64 ~ 8.30, 0.9 ~ 13.1% and 12.7 ~ 31.7 meq/100 g, respectively. The Freundlich constant, $K_F$ value, which gives a measure of the adsorption capacity, decreased in the order of fenitrothion > diazinon > alachlor > metalaxyl, which was identical to their lower water solubility. Among the collected soils, the $K_F$ value was very highly correlated with organic matter content ($r^2=0.800{\sim}0.876$) and CEC ($r^2=0.715{\sim}0.825$) and showed a high correlation with clay content ($r^2=0.473{\sim}0.575$) and soil pH($H_2O$) ($r^2=0.401{\sim}0.452$). The leaching of pesticides in the soil column showed a reverse relationhip with their adsorption in soils, i.e., the pesticides leached more quickly for the soils with lower values of organic matter content and CEC among the soils and for the pesticides with higher water solubility.

Real-Time XRD Analysis of Polystyrene/Clay Nanocomposites by In-Situ Polymerization (In-situ 중합법에 의한 폴리스티렌/점토 나노복합재료의 실시간 X선 분석)

  • Kim, Jang-Yup;Hwang, Seok-Ho;Hong, Yoo-Seok;Huh, Wan-Soo;Lee, Sang-Won
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.87-90
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    • 2005
  • In this study, we have examined the exfoliation behavior of layered clay during in-situ polymeriztion with styrene by using real-time XRD analysis. The 4C1 beam line at the Pohang Accelerator Laboratory (PAL) was used for this study. Different exfoliation behaviors have been shown to depend on the cation exchange capacity (CEC) of clay and the chemical structure of organic modifiers. For 10A-MMT and 15A-MMT having high CEC, no peak shifts were observed on real-time XRD analysis during polymerization. However, 2$\theta$ for 25A-MMT and VDAC-MMT, each having low CEC’s as well as aromatic benzene moieties and vinyl groups, respectively, decreased as polymerization time increased.

Characteristics of Soil Chemical Properties in Abandoned Coal Mine Forest Rehabilitation Areas in Hwasun, South Jeolla Province (전라남도 화순군 폐탄광 산림복구지 토양의 화학적 특성)

  • Jung, Mun-Ho;Shim, Yon-Sik;Kim, Tae-Heok
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1010-1015
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    • 2011
  • The objectives of this study were to investigate soil chemical characteristics for forest rehabilitation and suggest management in abandoned coal mine areas in Hwasun-gun, South Jeolla Province. Total study sites were 8 sites, and soil analysis particular were soil pH, TOC, total-N, C/N ratio, Avail. $P_2O_5$, and CEC. Average soil pH was 5.8 (4.7~6.4). Average contents of TOC, total-N and C/N ratio were 1.1% (0.2~2.0%), 0.08% (0.02~0.13%) and 15.0 (7.9~31.4), respectively. Average Avail. $P_2O_5$ was $8.3mg\;kg^{-1}$ (2.7~15.0) and Average CEC was $13.7cmol_c\;kg^{-1}$ ($9.9{\sim}18.5cmol_c\;kg^{-1}$). Soil pH was decreased according to elapsed time from forest rehabilitation, while TOC, total N and CEC were increased. Av. $P_2O_5$ did not show any relationship with elapsed time. Soil pH was stable comparing with general forest soil in South Jeolla Province (5.1), while contents of TOC and total N were lower than general forest soil in South Jeolla Province (4.9% and 0.18%, respectively). Therefore, sustainable managements such as fertilization for TOC and total N are necessary for good rooting and growth of vegetation.

Effects of Bentonite Illitization on Cesium Sorption (벤토나이트의 일라이트화에 의한 세슘 수착 특성 변화 연구)

  • Hwang, Jeonghwan;Choung, Sungwook;Han, Weon Shik;Yoon, Wonwoo
    • Journal of Soil and Groundwater Environment
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    • v.26 no.5
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    • pp.29-38
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    • 2021
  • This study investigated the mineralogical properties of bentonite and illite and evaluated the Cs sorption at various concentrations (Cw≈1-105 ㎍/L). Bentonite samples, collected from South Korea and USA, majorly consisted of Ca- and Na-montmorillonite, showed large cation exchange capacity (CEC, 91.4 and 47.3 meq/100 g) and specific surface area (SSA, 46.1 and 39.7 m2/g). In contrast, illite sample (USA) had relatively low values for 14.4 meq/100g of CEC and 29.3 m2/g of SSA, respectively. Bentonite and illite had different non-linear sorption for Cs along with Cw. At low Cw<10 ㎍/L, illite showed higher sorption capacity than bentonite despite low CEC because of the existence of specific sorption sites at the weathered mineral edge. However, as Cw increased, bentonite represented high sorption capacity because the cation exchange between Cs and interlayer cations was effective at high Cw conditions. These results implicated that the Cs concentration is important to evaluate the sorption performance of bentonite and illite. Finally, the Cuadros' kinetic model for illitization using various K concentrations (2×10-5 and 1.7×10-3 mol/L) and temperature (100-200℃) showed that up to 50% of the montmorillonite in bentonite could be converted to illite, suggesting that the illitization should be considered to evaluate the sorption performance of the bentonite in deep geological disposal repository.

Changes in Chemical Properties of Paddy Field Soils as Influenced by Regional Topography in Jeonbuk Province (지형특성에 따른 전북지역 논토양 화학성 변화)

  • Ahn, Byung-Koo;Lee, Jin-Ho;Kim, Kab-Cheol;Kim, Hyung-Gook;Jeong, Seong-Soo;Jeon, Hye-Won;Zhang, Yong-Sun
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.3
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    • pp.393-398
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    • 2012
  • We investigated the changes in chemical properties of paddy field soils at 300 different sampling sites containing 4 topography in Jeonbuk province, Korea. The soil samples were collected 43.0% from local valley and fans, 39.3% from fluvio-marine deposits, 15.0% from alluvial plains, and 2.7% from diluvium sites. The optimal values of soil properties in the total soil samples were as follows: 65.3% of total samples in soil pH value, 48.3% of total samples in cation exchange capacity (CEC) value, and 22.3% of total samples in available phosphorus content, whereas the deficient values of soil properties were 63.3% of total samples in soil organic matter (SOM) content, 75.7% of total samples in available silicate content, and 61.3%, 51.0%, and 59.3% of total samples in exchangeable $K^+$, $Ca^{2+}$, and $Mg^{2+}$ concentrations, respectively. There were different soil types in the paddy fields: that is, 34.4% immature paddy and 33.6% sandy paddy in the local valley and fans, 57.8% sandy paddy in the alluvial plains, 47.4% normal paddy in the fluvio-marine deposits, and 75.7% immature paddy in the diluvium. Soil textures were also different: 53.5% loam in the local valley and fans, 37.8% sandy loam in the alluvial plains, and 55.1% silty loam in the fluvio-marine deposits. Soil pH and SOM contents were not different among the different topographical sampling sites. However, the mean value of available phosphorus content, 224 mg $kg^{-1}$, was exceeded optimal values in the diluvium. The contents of exchangeable cations were optimal in all the sites, except exchangeable $Ca^{2+}$ contents in the local valley and fans. The contents of available silicate ranged between 112 and 127 mg $kg^{-1}$ in all the sites, which were lower than optimal value. In addition, soil pH values were proportionally correlated to the order of available silicate, exchangeable $Ca^{2+}$, $Mg^{2+}$, $Na^+$, CEC, and exchangeable $K^+$. The contents of SOM were proportionally correlated to the order of CEC, available $P_2O_5$, exchangeable $Ca^{2+}$, and available silicate. The contents of heavy metals, Cd, Cr, Cu, Ni, Pb, and Zn, were only 10% of the threshold levels of the metals, and As content was about 20 to 30% of the threshold level.