• Title/Summary/Keyword: CD98

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Monitoring Heavy Metals in Meat and Meat Products (식육 및 그 가공품의 중금속 모니터링)

  • Hwang, Tae-Ik;Ahn, Tae-Hyun;Kim, Eun-Jung;Lee, Jung-Ah;Kang, Myoung-Hee;Jang, Young-Mi;Kim, Mee-Hye
    • Korean Journal of Food Science and Technology
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    • v.43 no.5
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    • pp.525-531
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    • 2011
  • This study was conducted to examine the contents of lead (Pb), cadmium (Cd), arsenic (As), and mercury (Hg) in meat and meat products in Korea. The contents of Pb, Cd, As, and Hg in 466 samples of beef, pork, chicken, duck, ham, and sausage were measured using inductively coupled plasma mass spectrometry or a mercury analyzer. Wet ashing and microwave method were compared, and the recovery and reproducibility of the microwave method were better than those of wet ashing for meat and meat products. The recovery of the microwave method was 98.1% for Pb, 104.6% for Cd, and 103.4% for As, respectively. The best result was obtained through digestion using an acid mixture ($HNO_3$/$H_2O_2$, 6:2). Hg content was measured using a mercury analyzer. As a result, the contents of Hg and Cd in samples were lower than those of Pb and As. The average contents of Pb were 0.009 mg/kg in beef, 0.010 mg/kg in pork, 0.006 mg/kg in chicken, 0.007 mg/kg in duck, 0.005 mg/kg in ham, and 0.009 mg/kg in sausage. The average Cd contents were 0.0004 mg/kg in beef, 0.0004 mg/kg in pork, 0.0005 mg/kg in chicken, 0.0012 mg/kg in duck, 0.0015 mg/kg in ham, and 0.0019 mg/kg in sausage. The average As contents were 0.016 mg/kg in beef, 0.004 mg/kg in pork, 0.021 mg/kg in chicken, 0.010 mg/kg in duck, 0.014 mg/kg in ham, and 0.018 mg/kg in sausage. The average Hg contents were 0.713 ${\mu}g/kg$ in beef, 0.902 ${\mu}g/kg$ in pork, 0.710 ${\mu}g/kg$ in chicken, 0.796 ${\mu}g/kg$ in duck, 1.141 ${\mu}g/kg$ in ham, and 1.052 ${\mu}g/kg$ in sausage. Based on the results of the National Health and Nutrition Survey 2005, the levels of dietary exposure to heavy metal contaminants in meat and meat products were compared with the provisional tolerable weekly intake(PTWI) established by the Joint FAO/WHO Expert Committee on Food Additives. The average dietary exposure of the general population from meat and meat products was 0.03-0.2% of PTWI for Pb, Cd, As, and Hg, which indicates a safe level for public health at present.

Enhancement of Paraoxon Biodegradation Rate from Recombinant Escherichia coli Catalyst for Bioremediation (Bioremediation을 위하여 재조합 대장균 촉매를 이용한 Paraoxon의 생분해 속도 향상)

  • Choi, Suk Soon;Seo, Sang Hwan;Kang, Dong Gyun;Cha, Hyung Joon;Yeom, Sung Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.3
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    • pp.110-116
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    • 2006
  • In this study, the biodegradation rate of paraoxon, that is an organophosphate pesticide, was enhanced by recombinant Escherichia coli harboring organophosphorus hydrolase (OPH). The optimum conditions were 8.5 of initial pH and 5.0% of acetone for the enhancement of specific whole cell OPH activity. When the OPH was produced to 498 Unit/L, 98% of 275mg/L paraoxon was degraded within 10 minutes, and thus the biodegradation rate was enhanced to $29.2mg/g{\cdot}min$. The results implied that practical bioremediation technology developed in this study was an effective method to degrade residual organophosphate pesticide in ground water or soils in a short time.

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Synthesis and Ion Exchange Capacity of 2-Vinylpyridine Series Ion Exchange Resins (2-비닐피리딘계 이온교환수지의 합성과 그의 이온교환능)

  • Dong Won Kim;Hae Yong Song
    • Journal of the Korean Chemical Society
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    • v.25 no.3
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    • pp.160-165
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    • 1981
  • Radical copolymerization of the complexed 2-vinylpyridine with vinyl acetate and divinylbenzene initiated by azobisisobutyronitrile was carried out in N, N-dimethylformamide in presence of barium chloride at $98{\circ}C$. In the preparation of 2-vinylpyridine-vinylacetate-divinylbenzene terpolymer, the optimum reaction conditions were studied by means of various temperatures and times. 2-vinylpyridine-vinylalcohol-divinybenzene resin was prepared by transesterificating 2-vinylpyridine-vinylacetate-divinylbenzene terpolymer with a 1% methanolic sodium hydroxide solution. 2-Vinylpyridine-vinylphosphate-divinyldenzene was prepared by phosphorylating 2-vinylpyridine-vinylalcohol-divinylbenzene resin with phosphoric acid and urea. The compositions of each synthetic resin were identified by means of infrared absorption spectroscopy. The ion exchange capacities of each 2-vinylpyridine-vinylalcohol-divinylbenzene and 2-vinylpyridine-vinylphosphate-divinylbenzene terpolymer was 3.69 meq/g and 5.38 meq/g.

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Estimation of Heterosis from Strain Crosses of White Crosses and White Plymouth Rock for Certain Economic Traits (백색코니쉬와 백색플리머드록 계통간 교배단계별 경제형질에 대한 잡종강세 발현율 추정)

  • 정일정;정선부;연성흠
    • Korean Journal of Poultry Science
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    • v.12 no.2
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    • pp.75-82
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    • 1985
  • This study was carried out to estimate combining abilities and heterosis in White Cornish and White Plymouth Rock. The data were obtained over an 8weeks period from 3rd Oct., 1984 to 28th Nov. 1984 at the Livestock Experiment Station. A total of 810 birds, composed of 369 pure strains, 270 two-way crosses, and 180 fourway crosses were average amount of heterosis expressed as a ratio was 1.63% for livability, 5.47% for body weight at 8 weeks, 5.57% for weight gain from day old to 8 weeks and -5.98% for feed requirement. Specific combining ability were statistically significant for all of the traits examined in this study. Although the general combining ability was not significant for any of the traits, strain A appears to be superior to other strains.

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Bile Duct Ligation and Insulin-like Growth Factor-I on the Ischemia-Reperfusion Injury of the Small Bowel (쥐에서 허혈-재관류 소장 손상에 대한 담관결찰 및 Insulin-like Growth Factor-I의 영향)

  • Cha, Je-Sun;Lee, Myung-Duk
    • Advances in pediatric surgery
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    • v.3 no.2
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    • pp.98-107
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    • 1997
  • To determine whether bile juice exclusion can prevent the mucosal damage, and Insulin-like growth factor-I can promote mucosal regeneration in ischemia-reperfusion injury of the bowel, 39 weanling rats with 10 cm of Thiry-Vella loop were studied. Animal groups were; Control, BL(common bile duct ligation), IGF{insulin-like growth factor-I(IGF-I) infusion} and IGF-BL(combined treatment). IGF-I(1.5 mg/kg/day) was continuously delivered through a subcutaneously implanted miniosmotic pump. After 15 minutes of superior mesenteric artery clamping, a tissue specimen(P) was taken after 30 minutes of reperfusion. Intestinal continuity was restored to allow oral feeding. A specimen of main tract(M) and another of the Thiry-Vella loop(T) were collected for histomorphometry after 48 hours of reperfusion and free feeding. Villus size ratio(VSR), crypt depth(CD), crypt-depth/villus-height ratio(CVR) and injury score(IS) were measured in 15 consecutive villi. The postoperative mortalities of bile duct ligation groups(BL and IGF-BL) were higher than those of other groups. In control group, VSR of M was lower(P<0.05) than P or T, but not in the other groups. VSR of M in control was lower than those in other groups. CD of T in control, IGF and IGF-BL group were higher than those of M. CD of M and T showed gradual increments from control, IGF and IGF-BL group, respectively. CVR of M and T in IGF group were higher than those in control. CVR in IGF-BL group, T was higher than M, and M was higher than P. About IS, M of BL($20.1{\pm}2.5$) and IGF-BL($20.9{\pm}3.3$) groups were significantly lower than that of control($32.4{\pm}2.5$). These results suggest that the exclusion of bile juice reduces the severity of the reperfusion injury of the mucosa, by inability to activate pancreatic enzymes and IGF-I stimulates mucosal regeneration in injured bowel, and the effect is potentiated by bile juice exclusion.

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Evaluating Soil Respiration as Indicator of Heavy Metal Pollution in Agricultural Field

  • Choi, Won-Suk;Hong, Young-Kyu;Min, Kyung-Jun;Kim, Kwang-Jin;Kim, Sung-Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.472-481
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    • 2017
  • Agricultural field near at the abandoned metal mine and industrial area has a high possibility to be polluted by heavy metals. However, concern about chemical properties including heavy metal concentration has been increased and biological properties such as soil respiration has been minimal in heavy metal polluted field. Therefore, main objective of this research was to evaluate soil respiration as an indicator of heavy metal pollution in agricultural field. Total of 60 sampling sites including each 30 sites of abandoned metal mine and industrial area were selected and heavy metal concentration, soil respiration, and chemical properties were measured. Results showed that heavy metal concentration in metal mine area was ranged Cu: $6.21~85.23mg\;kg^{-1}$, Pb: $23.84{\sim}1,044.72mg\;kg^{-1}$, As: $1.88{\sim}691.44mg\;kg^{-1}$, Zn: $18.72{\sim}527.55mg\;kg^{-1}$, Cd: $0.58{\sim}4.27mg\;kg^{-1}$, and Cu: $0.29{\sim}30.62mg\;kg^{-1}$, Pb: $4.41{\sim}19.77mg\;kg^{-1}$, As: $2.23{\sim}11.76mg\;kg^{-1}$, Zn $39.98{\sim}109.59mg\;kg^{-1}$, Cd $0.29{\sim}0.57mg\;kg^{-1}$ for industrial area respectively. While no sampling site was exceed the threshold value of each heavy metals in industrial field, metal mine area was highly polluted with Pb, As, Zn, and Cd. Soil respiration in the metal mine and industrial area was ranged $12.05{\sim}299.80mg\;O_2\;kg^{-1}$ and $27.68{\sim}330.94mg\;O_2\;kg^{-1}$, respectively. Correlation analysis between heavy metal concentration in soil and soil respiration showed that negative correlation was observed in metal mine area while no correlation was observed in industrial area. This result might indicate that as heavy metal concentration was increased, microbial activity in soil was decreased resulting decrease of soil respiration rate. Overall, soil respiration can be used as indicator of heavy metal pollution in soil and more biological properties need to be evaluated to better understand heavy metal pollution in soil.

Availability of Carboxylated Magnetic Beads for Extracting Heavy Metals from Aqueous Solution

  • So, Hyung-Suk;Yoo, Yeong-Seok;Schaeffer Andreas
    • Journal of Magnetics
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    • v.11 no.2
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    • pp.98-102
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    • 2006
  • It was examined in this study that magnetic beads, which are assumed to be environmentally functional, could be effective in processing heavy metals that are water pollutants. For the purpose, magnetic beads containing carboxyl groups, which has strong binding force with heavy metals, are mixed with each Cd, Pb, Ni, Cu and Cr(III) solution, then stirred in pH 6. As a results of the process, it was proven that heavy metals bind quickly with magnetic beads through the reaction. In order to analyze heavy metal concentration, magnetic beads bind with heavy metal were collected by external magnetic force and dissolved in acid. The graphite furnace AAS was used to get heavy metal concentration melted in the acid solution. The results showed that heavy metal extractions by magnetic beads were influenced by the type and the concentration of a heavy metal, and over 90% of a heavy metal can be extracted in ppm level save for Cr(III). It was also examined in the study whether heavy metal extraction is influenced when other ions exist in each heavy metal solution. According to experiment, adding other heavy metals to a solution did have little influence on extracting an intended heavy metal. But in case salt or heavy metal chelate was added, Ni extraction changed sensitively although extracting other heavy metals were influenced only when the concentration of an added substance is high. In conclusion, it was shown that magnetic beads could be used to treat wastewater with relatively high heavy metal concentration.

Biosorption of $Pb^{2+}$ and $Cr^{3+}$ by using Sargassum hornei (Sargassum horneri를 이용한 $Pb^{2+}$$Cr^{3+}$ 생체흡착)

  • 서근학;안갑환;조문철
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.387-391
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    • 1999
  • $Pb^{2+}$ and $Cr^{3+}$ uptake capacity by Sargassum horneri was 185.5 mg $Pb^{2+}$/g biomass and 102.6 mg $Cr^{3+}$/g biomass, respectively. An adsorption equilibria were reached within about 0.5 hr for $Pb^{2+}$ and 1 hr for $Cr^{3+}$. The adsorption parameters for $Pb^{2+}$ and $Cr^{3+}$ were determined according to Langmuir and Freundlich model. With an increase in pH values of 2 to 5, $Pb^{2+}$ uptake was increased, however $Cr^{3+}$ uptake jwas constant. The selectivity of mixture solution showed the uptake order of $Pb^{2+}$>$Cu^{2+}$>$Cr^{3+}$>$Cd^{2+}$. $Pb^{2+}$ and $Cr^{3+}$ adsorbed by S. horneri could be recovered from 0.1M HCl, 0.1M ${HNO}_3$ and 0.1M EDTA by desorption process, and the efficiency of $Pb^{2+}$ desorption was above 98%, whereas the efficiency of $Cr^{3+}$ desorption was below 34%.

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Electroluminescence Properties of Simple Anthracene Derivatives Containing Phenyl or Naphthyl Group at 9,10-position for the Blue OLED

  • Kim, Si Hyun;Lee, Song Eun;Kim, Yong Kwan;Lee, Seung Hee
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.562-567
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    • 2017
  • The organic light-emitting diodes are fabricated with six anthracene derivatives containing simple substituents such as phenyl or naphthyl group. The device structure is as in the following: Indium tin oxide (ITO) (180 nm)/4,4-4,4',4"-tris[N-(1-naphthyl)-N-phenylamino]triphenylamine (2-TNATA) (30 nm)/4,4'-bis[N-(1-naphthyl)-N-phenyl-1-amino] biphenyl (NPB) (20 nm)/Emitting compound (30 nm)/2,2',2"-(1,3,5-Benzinetriyl)-tris (1-phenyl-1-H-benz-imidazole) TPBi (40 nm)/lithium quinolate (Liq) (2 nm)/Al (100 nm). In the emitting layer the anthracene derivatives are used without any dopant. All the six devices show blue emissions. Among the tested diodes, the one with 9-(2-naphthyl)-10-(p-tolyl) anthracene (2-NTA) exhibited luminous efficiency, power and external quantum efficiencies of 3.26 cd/A, 0.98 lm/A, 2.8 % at $20mA/cm^2$.

The Study on Dielectric layer Design and Manufactor for Luminance Improvement of Red Organic Light Emitting Device (적색 유기발광소자의 휘도향상을 위한 Dielectric layer 설계 및 제작에 관한 연구)

  • Ki, Hyun-Chul;Kim, Seon-Hoon;Kim, Doo-Gun;Kim, Sang-Gi;Jeong, Haeng-Yun;Choi, Young-Sung;Hong, Kyung-Jin
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.5
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    • pp.918-921
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    • 2010
  • We have proposed an dielectric layer to improve the luminance of red organic light emitting device. Here, we have calculated refractive index of dielectric layer material that was revised refractive index of organic material, ITO and glass. Refractive index of dielectric layer material was 1.711. The structure of dielectric layer was designed in organic material/ITO/dielectric layer/glass. Dielectric material changed thickness that deposited by ion-assisted deposition system. Transmittances of ITO were 95.66-98.85 [%]. Red OLED was fabricated with the structure of TPD($400[{\AA}]$)/DCMII($20[{\AA}]$), Rubrene($20[{\AA}]$)/Alq3($500[{\AA}]$)/LiF($15[{\AA}]$)/Al($1,000[{\AA}]$). Turn-on voltage and Luminance of Red OLED were 10 [V] and 5,857 cd/m2.