• Bulletin of the Korean Chemical Society
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• v.28 no.9
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• pp.1613-1614
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• 2007

• Digital Contents
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• no.10 s.41
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• pp.85-88
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• 1996

개교 50주년 기념 사업의 일환/전국 대학 최초의 CD-ROM 동문 명부 제작에 성공/다채로운 영상과 정지화상을 쉽게 살펴볼 수 있어/수익금은 모교 발전 기금으로 조성 예정

• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.791-793
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• 1997

• Journal of the Mineralogical Society of Korea
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• v.30 no.4
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• pp.195-204
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• 2017

For evaluation of adsorption characteristics of heavy metals, precipitates were collected from stream bottom in the Dalseong mine. The removal of some heavy metals such as As, Cu, and Cd from aqueous solution is studied using a precipitates taken from acid mine drainage. The yellowish brown (Munsell color 8.75YR 5/10) and dark brown (Munsell color 2.5YR 3/8) precipitates that collected from the study area consist mainly of schwertmannite and goethite, respectively. The percentage removal or adsorption capacity of metals depends on the initial concentration and characteristics of adsorbent. Removal efficiency of the adsorbents shows the order for metal ions of As > Cu > Cd. The adsorption efficiency by absorbent of precipitates in low concentration metal aqueous solution were observed 67.00-85.00% for As, 26.24-29.08% for Cd, and 7.67-12.82% for Cu. As the initial concentration of metal ions was increased from 1 to 10 mg/L, adsorption amount of adsorbent increased from 0.29 to 1.29 mg/g of Cu of schwertmannite, and from 0.24 to 1.97 mg/g of goethite.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.1
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• pp.53-57
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• 2011

The MuSI is known as a multiple stress resistant gene with several lines. A previous study using RT-PCR showed that the expression of MuSI gene in tobacco plant induced its tolerance to Cd stress. This study was conducted to examine the enhanced Cd tolerance of the MuSI transgenic tobacco plant through germination test and to understand the role of the involved antioxidant enzymes for the exhibited tolerance. Germination rate of MuSI transgenic tobacco was more than 10% higher than that of wild-type tobacco, and seedlings of MuSI transgenic tobacco grew up to 1.6 times larger and greener than seedlings of wild-type tobacco at 200 and 300 ${\mu}M$ Cd. From the third to the fifth day, CAT activities at 100 and 200 ${\mu}M$ Cd and APX activities at 100, 200 and 300 ${\mu}M$ Cd of MuSI transgenic tobacco were up to two times higher than those of wild-type tobacco. MuSI gene is shown to enhance the activities of antioxidant enzymes resulting in higher tolerance to oxidative stress compared with the control plant.

• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3255-3260
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• 2011

Two novel binuclear metal-organic coordination complexes $[Cd_2(L)_2(bpy)_2(H_2O)_2]{\cdot}6H_2O$ (1), $[Cd_2(L)_2(phen)_2-(H_2O)_2]{\cdot}2H_2O$ (2) (where L = 2-methylquinoline-3,4-dicarboxylate dianion, bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions and characterized by single crystal Xray diffraction, spectral method (IR), elemental analysis and thermal gravimetric analysis (TGA). Both 1 and 2 consist of two Cd(II) atoms bridged by two monoatomic bridging carboxylate groups from two L ligands, and the second carboxylate group of each L is monodentately coordinated to Cd(II), creating a sevenmembered chelating ring. The coordination at each metal nucleus is completed by a water molecule and a chelating bidentate molecule. The 3D structures of the complexes are stabilized by ${\pi}-{\pi}$ stacking interactions and hydrogen-bonds.

• Korean Journal of Crystallography
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• v.12 no.4
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• pp.207-211
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• 2001

The crystal structure of the title complex, Cd(SCN)₂{CH/sub 6/H/sub 10/(NH₂)₂}₂(1) has been analyzed by X-ray single crystallography. The complex 1 crystallizes in the monoclinic system P2₁/ space group with a=11.842(2), b=7.926(2), c=11.291(2) Å, β=106.73(3)°V=1014.8(4)Ų, Z=2, R₁=0.0518 and ωR₂=0.1315 for 1775 independent reflections. The central Cd(II) atom of this com-plex has a slightly distorted octahedral coordination geometry, with the 1,2-Diaminocyclohexane ligands functioning as an N,N'-bidentate and the thiocyanate ligands bonding through the sulfur atom in a trans arrangement.

• YAKHAK HOEJI
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• v.45 no.4
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• pp.357-365
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• 2001

The purpose of this study is to investigate the influence of cyclodextrins (CDs) and different acids on the solubility of fluconazole, and o formulate its more concentrated parenteral aqueous solution. Solubility studies of fluconazole with 7-CD, 2-hydroxypropyl-$\beta$-CD (HPCD), sulfobutyl ether $\beta$-CD (SBCD) and dimethyl-$\beta$-CD(DMCD) were performed. The aqueous solubility of fluconazole was measured in different concentrations of different acids with or without addition of CDs. Solubility of fluconazole increased in the rank order of $\beta$-CD$^1$H-NMR studies confirmed the formation of an inclusion complex of fluconazole with HPCD. It was also shown by the NMR studies that the complex formed was a 1:1 complex. Among the different acids used, maleic acid and phosphoric acid increased solubility of fluconazole. The lower the pH of solution is, the more fluconazole dissolved, regardless of acids. Addition of HPCD (50 mM) to acid solutions increased the solubility about two times. New fluconazole injections at a dose of 10 mg/ml could be prepared in aqueous solutions containing 10% HPCD or 15% SBCD. These parenteral solutions did not form any precipitates at 4$^{\circ}C$ and was very stable at elevated temperatures. These results demonstrate that it is possible to develop a parenteral aqueous solution of fluconazole with a smaller injection volume using HPCD or SBCD.

• Journal of Plant Biology
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• v.22 no.1_2
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• pp.15-20
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• 1979

The present study was carried out to investigate the effects of cadmium(Cd), mercury(Hg) and lead(Pb) on the respiration of the germinating seeds. Two kinds of seeds namely, mungbean (Paseolus radiatus L.) and buckwheat (Fagopyrum esculentum M ench) were used for the plant materials. The concentrations of Cd, Hg, and Pb applied for the treatment were 0.1, 1, 10, 100 and 1,000ppm. The germination test was carried out in the dark at 27$^{\circ}C$. Regardless of the kinds of heavy metals, the respiration of the germinating seeds was greatly increased for 24hrs absorbing the heavy metals, and subsequently the respiration was increased average 0.69mg/g.hr.CO2 for mungbean and 0.7mg/g.hr.CO2 for buckwheat. In the lower concentrations of cadmium and lead than 10ppm the germinating rates, seedling concentraitons. The germinating rates, the seedling growth and the respiration were not increased in ay concentrations of mercury, but were decreased with increase of the mercury concenration. The inhibition of seeds respiration by mercury was 3 times higher than by cadmium, and 5 times higher than that by lead. The toxicity of three heavy metals on the respiration was showed from the highest to the lowest in the order of Hg, Cd, and Pb.

• Proceedings of the KIEE Conference
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• 2002.06a
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• pp.88-93
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• 2002

$Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ and $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}:Co^{2+}$ + single crystals were grown by CTR method. The grown single crystals have defect chalcopyrite structure with lattice constant a= 5.5966A. c= 10.8042${{\AA}}$ for the pure. a= 5.6543${{\AA}}$. c= 10.8205${{\AA}}$ for the Co-doped single crystal. respectively. The optical energy band gap was given as indirect band gap. The optical energy band gap was decreased according to add of Co-impurity. Temperature dependence of optical energy band gap was fitted well to the Varshni equation. From this relation. we can deduced the entropy. enthalpy and heat capacity. Also. we can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.