• Title/Summary/Keyword: C1 reduction

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The Influence of Alloying Elements Addition on the Electrical and Mechanical Properties of Cu-Ni-Si-P Alloy (Cu-Ni-Si-P 합금의 기계적 및 전기적 성질에 미치는 첨가원소의 영향)

  • Kim, Seung-Ho;Yum, Young-Jin;Park, Dong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.1
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    • pp.1-9
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    • 2014
  • For connector material applications, the influence alloying elements of Mn, Cr, Fe, and Ti and cold rolling reduction on the mechanical property, electrical conductivity and bendiability of Cu-Ni-Si-P alloy was investigated. The hot rolled plates were solution treated at $980^{\circ}C$ for 1.5 h, quenched into water, cold rolled by 10% and 30% reduction in thickness, and then aged at $440{\sim}500^{\circ}C$ for 3, 4, 5 times. respectively. Cu-Ni-Si-P-x alloys cold rolled by 10 reduction before heat treatment have a good bendability compare to cold rolled by 30 reduction. Cu-3.4Ni-0.8Si-0.03P-0.1Ti shows the peak strength value of 759 MPa, an electrical conductivity of 39%IACS, an elongation of 10% and a hardness of 256 Hv aged at $440^{\circ}C$ for 6 hrs. Thus it is suitable for lead frame and connector.

Fabrication of Fe-TiC Composite Powder by High-Energy Milling and Subsequent Reaction Synthesis (고에너지 밀링 및 합성반응에 의한 Fe-TiC 복합분말 제조)

  • Ahn, Ki-Bong;Lee, Byung-Hun;Lee, Young-Hee;Khoa, Hyunh Xuan;Kim, Ji-Soon
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.53-59
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    • 2013
  • Fe-TiC composite powder was fabricated via two steps. The first step was a high-energy milling of FeO and carbon powders followed by heat treatment for reduction to obtain a (Fe+C) powder mixture. The optimal condition for high-energy milling was 500 rpm for 1h, which had been determined by a series of preliminary experiment. Reduction heat-treatment was carried out at $900^{\circ}C$ for 1h in flowing argon gas atmosphere. Reduced powder mixture was investigated by X-ray Diffraction (XRD), Field Emission-Scanning Electron Microscopy (FE-SEM) and Laser Particle Size Analyser (LPSA). The second step was a high-energy milling of (Fe+C) powder mixture and additional $TiH_2$ powder, and subsequent in-situ synthesis of TiC particulate in Fe matrix through a reaction of carbon and Ti. High-energy milling was carried out at 500 rpm for 1 h. Heat treatment for reaction synthesis was carried out at $1000{\sim}1200^{\circ}C$ for 1 h in flowing argon gas atmosphere. X-ray diffraction (XRD) results of the fabricated Fe-TiC composite powder showed that only TiC and Fe phases exist. Results from FE-SEM observation and Energy-Dispersive X-ray Spectros-copy (EDS) revealed that TiC phase exists uniformly dispersed in the Fe matrix in a form of particulate with a size of submicron.

The Reactivity for the SO2 Reduction with CO and H2 over Sn-Zr Based Catalysts (Sn-Zr계 촉매 상에서 CO와 H2를 이용한 SO2 환원 반응특성)

  • Han, Gi Bo;Park, No-Kuk;Ryu, Si Ok;Lee, Tae Jin
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.356-362
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    • 2006
  • The $SO_2$ reduction using CO and $H_2$ over Sn-Zr based catalysts was performed in this study. Sn-Zr based catalysts with Sn/Zr molar ratio (0/1, 1/4, 1/1, 2/1, 3/1, 1/0) were prepared by the precipitation and co-precipitation method. The effect of the temperature on the reaction characteristics of the $SO_2$ reduction with a reducing agent such as $H_2$ and CO was investigated under the conditions of space velocity of $10,000ml/g_{-cat.}h$, $([CO(or\;H_2)]/[SO_2])$ of 2.0. As a result, the activity of Sn-Zr based catalysts were higher than $SnO_2$ and $ZrO_2$. The reactivity for the $SO_2$ reduction with CO was higher than that with $H_2$, and sulfur yield in the $SO_2$ reduction by $H_2$ was higher than that by CO. The reactivity for the $SO_2$ reduction with $H_2$ was increased with the reaction temperature regardless of Sn-Zr based catalyst with a Sn/Zr molar ratio. $SnO_2-ZrO_2$ (Sn/Zr=1/4) had highest activity at $550^{\circ}C$, in the $SO_2$ reduction with $H_2$ and $SO_2$ conversion of 94.4% and sulfur yield of 66.4% were obtained at $550^{\circ}C$. On the other hand, in the $SO_2$ reduction by CO, the reactivity was decreased with the increase over $325^{\circ}C$. At the optimal temperature of $325^{\circ}C$, $SO_2$ conversion and sulfur yield were about 100% and 99.5%, respectively, in the $SO_2$ reduction over $SnO_2-ZrO_2$ (Sn/Zr=3/1). Also, the $SO_2$ reduction using syngas with $CO/H_2$ ratio over $SnO_2-ZrO_2$ (Sn/Zr=2/1) was performed in order to investigate the application possibility of the simulated coal gas as the reductant in DSRP. As a result, the reactivity of the $SO_2$ reduction using syngas with $CO/H_2$ ratio was increased with increasing the CO content of syngas. Therefore, it could be known that DSRP using the simulated coal gas over Sn-Zr based catalyst is possible to be realized in IGCC system

Electrochemical Reduction of High Pressure Carbon Dioxide on Metal Electrodes and Gas Diffusion Electrodes

  • Hara, Kohjiro;Sakata, Tadayoshi
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.683-689
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    • 1995
  • Electrochemical reduction of carbon dioxide under high pressure on Fe electrodes and a gas diffusion electrode containing Pt catalyst (Pt-GDE) had been investigated. Formic acid was formed on Fe electrode with a faradaic efficiency of 60% at a current density of $120mA\;cm^{-2}$ under 30 atm of $CO_2$. Hydrocarbons such as $CH_4$, $C_2H_6$, $C_3H_6$, $1-C_4H_8$, and $n-C_5H_{12}$ are also formed. The distribution of hydrocarbons followed well the Schultz-Flory distribution. $CH_4$ was formed efficiently as the main reduction product on Pt-GDE.

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Synthesis and Characteristics of W-Ni-Fe Nanocomposite Powder by Hydrogen Reduction of Oxides (산화물 수소환원에 의한 W-Ni-Fe 나노복합분말의 합성과 특성)

  • 이창우;윤의식;이재성
    • Journal of Powder Materials
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    • v.8 no.1
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    • pp.49-54
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    • 2001
  • The synthesis and characteristics of W-Ni-Fe nanocomposite powder by hydrogen reduction of ball milled W-Ni-Fe oxide mixture were investigated. The ball milled oxide mixture was prepared by high energy attrition milling of W blue powder, NiO and $Fe_2O_3$ for 1 h. The structure of the oxide mixture was characteristic of nano porous agglomerate composite powder consisting of nanoscale particles and pores which act as effective removal path of water vapor during hydrogen reduction process. The reduction experiment showed that the reduction reaction starts from NiO, followed by $Fe_2O_3$ and finally W oxide. It was also found that during the reduction process rapid alloying of Ni-Fe yielded the formation of $\gamma$-Ni-Fe. After reduction at 80$0^{\circ}C$ for 1 h, the nano-composite powder of W-4.57Ni-2.34Fe comprising W and $\gamma$-Ni-Fe phases was produced, of which grain size was35nm for W and 87 nm for $\gamma$-Ni-Fe, respectively. Sinterability of the W heavy alloy nanopowder showing full density and sound microstructure under the condition of 147$0^{\circ}C$/20 min is thought to be suitable for raw material for powder injection molding of tungsten heavy alloy.

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Effects of Washing and Storage Temperature on Quality and Safety of Washed Shell Eggs (세척 수 및 보관온도가 세척 식용란 품질과 안전에 미치는 영향)

  • Choi, Bum-Geun;Min, Ji-Hyeon;Yoon, Ki-Sun
    • Journal of the East Asian Society of Dietary Life
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    • v.27 no.1
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    • pp.78-87
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    • 2017
  • The objective of this study was to investigate the effects of various washing waters on the quality and safety characteristics of eggs during storage. Eggs were washed with tap water, 100 ppm of sodium hypochlorite, or 30 ppm of slightly acidic electrolyzed water and stored at $10^{\circ}C$ and $20^{\circ}C$. Effects of various washing waters on reduction of Salmonella Enteritidis and aerobic plate counts and survival of S. Enteritidis on egg shells were also analyzed at $10^{\circ}C$ and $20^{\circ}C$ for 25 days. As an index of quality, haugh unit, weight reduction, and pHs of egg white and egg yolk were measured. Reduction percentages of haugh unit and weight were higher at $20^{\circ}C$ than at $10^{\circ}C$. Egg qualities were less affected by tap water, slightly acidic electrolyzed water, and sodium hypochlorite, regardless of storage temperature. The greatest reductions in aerobic plate counts and S. Enteritidis were observed with slightly acidic electrolyzed water. The level of S. Enteritidis on egg shells gradually decreased during 20 days of storage at both $10^{\circ}C$ and $20^{\circ}C$, whereas S. Enteritidis survived longer at $20^{\circ}C$ than at $10^{\circ}C$. S. Enteritidis was not detected in eggs at $10^{\circ}C$, 2.13 log CFU/g of S. Enteritidis was detected in eggs washed with sodium hypochlorite after 20 days of storage at $20^{\circ}C$, indicating that S. Enteritidis penetrated into the egg shell during storage at $20^{\circ}C$. In conclusion, slightly acidic electrolyzed water increased microbial reduction and least affected quality of washed eggs. Thus, slightly acidic electrolyzed water can be recommended for washing of graded eggs, at retail markets.

Gradient Reduction of $C_1$ in /pk/ Sequences

  • Son, Min-Jung
    • Speech Sciences
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    • v.15 no.4
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    • pp.43-60
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    • 2008
  • Instrumental studies (e.g., aerodynamic, EPG, and EMMA) have shown that the first of two stops in sequence can be articulatorily reduced in time and space sometimes; either gradient or categorical. The current EMMA study aims to examine possible factors_linguistic (e.g., speech rate, word boundary, and prosodic boundary) and paralinguistic (e.g., natural context and repetition)_to induce gradient reduction of $C_1$ in /pk/ cluster sequences. EMMA data are collected from five Seoul-Korean speakers. The results show that gradient reduction of lip aperture seldom occurs, being quite restricted both in speaker frequency and in token frequency. The results also suggest that the place assimilation is not a lexical process, implying that speakers have not fully developed this process to be phonologized in the abstract level.

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Analysis of Noise Special Medical Examination and Work Environment Monitoring results (소음에 대한 특수건강진단 및 작업환경측정 결과 분석)

  • Kim, Kab Bae;Park, Hae Dong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.698-698
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    • 2014
  • According to the analysis of special medical examination and work environment monitoring data, the rate of C1 and D1 on noise hazard exceeded 90% among those of total hazardous factors. The rate of company exceeding noise exposure limit was also more than 90%. The analysis result shows that main ages diagnosed with C1 and D1 was age of 50s. The majority scale company having workers diagnosed with C1 and D1 was the companies employing 5~49 workers. Types of industries which have a large number of companies exceeding noise exposure limit were automobile and trailer manufacturing, metal processing industry and primary metal manufacturing. A large number of work processes exceeding noise exposure limit were forming and processing work, cutting and bending work and grinding. To reduce the number of company exceeding noise exposure limit, the reduction counterplan should be focused on the type of industry and the work process which exceeded noise exposure limit frequently. However, the reduction counterplan is preemptively necessary to the type of industry and the work process which exceeded noise exposure limit consecutively if the purpose of reduction counterplan is not to merely reduce the number of company exceeding noise exposure limit but to abate workers' suffering from noise.

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The Microstructure and Mechanical Property of 0.19C-1.17Cr Steel with Cold Drawing (0.19C - 1.17Cr 강의 냉간인발조직과 기계적 성질)

  • Shin J. H.;Jang B. L.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.11a
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    • pp.85-90
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    • 2001
  • The microstructure and mechanical property of 0.19C-1.17Cr steel were investigated with cold drawing. This commercial steel has the microstructure that is consist of ferrite and pearlite. The tensile and yield strength are increased as the reduction ratio of cold drawing is increased. It was clear that mechanical properties could be improved by combination of the heat treatments and reduction ratio. Yield strength. tensile strength, and impact value were formulated as a constitutive function of cold drawing ratio, respectively.

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Hydration Property of Electric Arc Furnace Reduction Slag (전기로(電氣爐) 환원(還元) 슬래그의 수화반응(水和反應) 특성(特性) 연구(硏究))

  • An, Yong-Jun;Han, In-Kyu;Choi, Jae-Seok;Bae, Kwang-Hyun;Kim, Hyung-Seok
    • Resources Recycling
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    • v.19 no.6
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    • pp.93-101
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    • 2010
  • In this study, we have studied hydration properties and compressive strength of the electric arc furnace reduction slag as a cement admixture. The reduction slag is mainly consisted of 17.1% of f-CaO and rapid curing clinker minerals, 37.1% of $C_{11}A_7CaF_2$, and 21.0% of $C_3A$. When the substitution rate of the slag on OPC was 30%, the initial setting time and final setting time has been shortened from 305 min. and 425 min. to 10min. and 30min. When the substitution rate of the slag on OPC was 7%, the compressive strength of mixed cement mortars has been increased than that of OPC during all period. When the substitution rate of the slag on OPC was over 20%, the compressive strength of mortars has been reduced than that of OPC at initial and final compressive strength. As a result of hydration properties of reduction slag, $C_{11}A_7CaF_2$ transfer to $C_3AH_6$ but as the substitution rate of slag on OPC increases, increased f-CaO and the metastable hydrates $C_4AH_{13}$ increased. Therefore, we should control the substitution rate of the slag on OPC was under 7% in order to use EAF reduction slag as a cement admixture.