• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.10
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• pp.890-896
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• 2009

Li(Ni, Co, Mn)$O_2$ has been known as one of the most promising cathode materials for lithium secondary batteries. However, it has some problems to overcome for commercialization such as inferior rate capability and unstable thermal stability. In order to address these problems, surface modification of cathode materials by coating has been investigated. In the coating techniques, selection of coating material is a key factor of obtaining enhanced properties of cathode materials. In this work, we introduced solid electrolyte (Li-La-Ti-O) as a coating material on the surface of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ cathode. Specially, we focused on a rate performance of Li-La-Ti-O coated $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ cathode. Both bare and Li-La-Ti-O 2 wt.% coated sample showed similar discharge capacity at 0.5C rate. However, as the increase of charge-discharge rate to 3C, the coated samples displayed better discharge capacity and cyclic performance than those of bare sample.

• Bulletin of the Korean Chemical Society
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• v.31 no.8
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• pp.2304-2308
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• 2010

A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.5
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• pp.58-65
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• 2004

A cylindrical constant volume combustion chamber was used to investigate the combustion characteristics of stratified methane-air mixture under several initial charge conditions in the author's previous reports. The results showed that the improvement of thermal efficiency and reduction of heat loss was realized simultaneously by using 2-stage injection method. This paper deals with the reason why the stratified combustion has showed better combustion rate through the measurement and analysis of chemiluminescence of C $H^{*}$ and $C_{2}$$^{*}$ radicals. An optic fiber bundle is used to measure the local emission of C $H^{*}$ and $C_{2}$$^{*}$ radicals to map the relationship between the excess air ratio and local radical intensity ratio in the combustion vessel at 5 mm apart form the geometric center. The results show that there exist a relationship between the intensity ratio and the air-fuel ratio. It is revealed that the improvement of combustion rate in a lean-stratified mixture is realized through the 2-stage injection method. method.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.50 no.12
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• pp.819-828
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• 2022

Sensitivity of aircraft sizing depending on battery performance was studied for a generic quad tilt rotor type electric vertical takeoff and landing vehicle. The mission requirements proposed by Uber Elevate and NASA were used for initial sizing, and the calculated gross weight is ranged between 5,000lb and 11,000lb for battery specific energy range of 200-400Wh/kg in pack level and continuous discharge rate range of 4-5C. For the assumed gross weight of 7,000lb, the required battery performance was calculated with two different criteria: available power and energy, and the effects of battery specific energy and discharge rate are analyzed. The maximum discharge rate is also recommended considering failure cases such as one battery pack inoperative and one prop rotor inoperative.

• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.303-308
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• 2010

Pseudo-first-order rate constants ($k_{obsd}$) have been measured spectrophotometrically for nucleophilic substitution reactions of 4-nitrophenyl benzoate (5a), 4-nitrophenyl 4-methoxybenzoate (5b), and 4-nitrophenyl 4-hydroxybenzoate (5c) with alkali metal ethoxides, $EtO^-M^+$ ($M^+=Li^+$, $Na^+$ and $K^+$) in anhydrous ethanol (EtOH) at $25.0{\pm}0.1^{\circ}C$. The plots of $k_{obsd}$ vs. [$EtO^-M^+$] exhibit upward curvatures in all cases, indicating that $M^+$ ions catalyze the reactions and ionpaired $EtO^-M^+$ species are more reactive than dissociated $EtO^-$. Second-order rate constants for reactions with dissociated $EtO^-$ and ion-paired $EtO^-M^+$ (i.e., $k_{EtO^-}$ and $k_{EtO^-M^+}$, respectively) have been calculated from ion-pair treatment for the reactions of 5a and 5b. However, such ion-pair treatment has failed to determine $k_{EtO^-}$ and $k_{EtO^-M^+}$ values for the reactions of 5c. It has been concluded that reactions of 5a and 5b are catalyzed by one metal ion, which increases electrophilicity of the reaction center through coordination on the carbonyl oxygen. In contrast, reactions of 5c have been suggested to involve two metal ions, i.e., the one coordinated on the carbonyl oxygen increases the electrophilicity of the reaction center while the other one associated on the phenoxy oxygen decreases the charge repulsion between the anionic reagents (i.e., $EtO^-$ and deprotonated 5c). It has been found that the rate equation derived from the mechanism involving two metal ions fits nicely to the kinetic results obtained for the reactions of 5c.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.4
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• pp.51-59
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• 2002

In this study, cycle simulation was performed to investigate the effect of EGR on combustion characteristics and emissions including NO and soot using a two-zone model in a DI diesel engine. The NO formation was well predicted for different EGR rate and temperature using a two-zone model. The oxygen in the inlet charge was replaced by CO$_2$ and H$_2$O with EGR. The reduction in the inlet charge oxygen resulted in very large reduction in NO level at the same inlet charge temperature. The effect of EGR was to reduce the burned gas temperature. When EGR was increased from 0% to 15%, the peak flame temperature was decreased by 50$\^{C}$ and it caused about 57% NO reduction. EGR caused increase of the overall inlet charge temperature which offset some of benefit of lower flame temperature resulting from O$_2$ displacement. Cooling the EGR was confirmed to provide additional benefits by lowering NO emission. It also reduced soot emission.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.28A no.12
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• pp.59-64
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• 1991

Thin (25-103$\AA$) SiO$_2$ films are grown using the rapid thermal oxidation processing at temperatures of 105$0^{\circ}C$-115$0^{\circ}C$ for 5-30 sec, in order to investigate the characteristics of ultra thin oxide. For measuring the thickness of oxide TEM, ellipsometry, and C-V method which is taken in the condition of small surface band bending are used and compared. When neglecting the small deviation affected by both interface state and moisture charge effect, those three methods described above give similar results. In order to examine the effect of rapid thermal annealing, part of samples are annealed in N$_2$ ambient. MOS capacitors are fabricated and the characteristics of I-V and C-V are measured. Measurements show that the activation energy of initial thickness of oxide grown during the ramp-up time is of 1.125eV and the activation energy of the oxidation rate is of 0.98eV. As oxidation temperature is increased, dielectric breakdown field E$_{BD}$ is decreased due to the increase of fixed charge density N$_f$ However, E$_{BD}$ is shown to be decreased as increasing the thickness of oxide. The increase of N$_f$ in the early stage of thermal annealing results in the decrease of E$_{BD}$.

• Textile Coloration and Finishing
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• v.9 no.5
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• pp.42-51
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• 1997

The purpose of this article is to investigate the effect of $O_{2}$ low temperature plasma treatment oft chitosan treatment of polyester fabrics. Moisture regain, static charge, crease resistance and reduction ratio of the treated fabric were measured. The results of this study were as follows: The add-on ratio and. the moisture regain of polyester fabrics treated with chitosan after treated by plasma(CP PET) were higher than those of polyester fabrics treated with only chitosan(C PET). The static charge of polyester fabrics decreased greatly with increasing the concentration of chitosan. A durability for laundering of CP PET was higher than those of C PET. The crease resistance of polyester fabrics decreased with ihcreasing the concentration of chitosan continuously. CP PET had higher decreasing rate and better durability than C PET. It showed that chitosan-treated polyester fabrics had over 90% reduction ratio after 10 times of laundering, and CP PET had better reduction ratio than C PET.

• The Korean Journal of Ceramics
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• v.6 no.1
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• pp.53-57
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• 2000

It was observed that the growth rates are different each other in the opposite direction along c-axis due to the crystal polarity. In according to the calculation based on diffusional equations with consideration of the electrical polarization and the surface charge, the difference of growth rates could be explained. Some experiments were compared with this kinetic explanation.

• Journal of the Microelectronics and Packaging Society
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• v.6 no.2
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• pp.69-74
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• 1999

Graphite and carbonaceous materials intercalate and deintercalate Li-ion reversibly into their layered structures. These materials show an excellent capacity for using a negative electrode in Li-ion batteries, because the electrochemical potential of Li-ion intercalated carbon is almost identical with that of lithium metal. Carbon used in this study was obtained by the pyrolysis of petroleum pitch, and heat-treated at the several temperatures between $700^{\circ}C$ and $1300^{\circ}C$. XRD analysis revealed that crystallization of carbon increased with increasing the heat treatment temperature. Charge/discharge properties were studied by a constant-current step at the rate of 0.1C, and the interfacial reaction between the electrolyte and the surface of carbon electrode was studied by cyclic voltammetry. Cell capacities were investigated in terms of the heat treatment temperature and the cycle number. Reversible capacity increased with the heat treatment temperature up to $1000^{\circ}C$, thereafter decreased continuously. Also, charge capacity decreased with the cycle number, while the reversibility improved with it.