• 제목/요약/키워드: C-S-H phase

검색결과 1,379건 처리시간 0.035초

퀜칭과정에서 상변태를 고려한 탄소성 열응력의 유한요소 해석(II) -오오스테나이트에서 마르텐사이트로의 변태- (An Analysis Finite Element for Elasto-Plastic Stresses Considerating Phase Transformation at the Quenching Process(II) -From Austenite to Martensite-)

  • 김옥삼;송관흠;구본권
    • 열처리공학회지
    • /
    • 제8권1호
    • /
    • pp.12-23
    • /
    • 1995
  • In this a set of constitutive equation relevant to the analysis of thermo-elasto-plastic materials with phase transformation during quenching process was presented on the basis of continuum thermo-dynamic. In calculating the transient thermal stresses, temperature between coolant and specimen(SM45C) surface was determined from the heat transfer coefficient. A calculation was made for specimen with 40mm in diameter quenched in coolant from $820^{\circ}C$ and the results are as follow. Stresses at starting point of transformation always show the maximum tensile value. Reverse of stresses takes place after completion of transformation of inner part at specimen.

  • PDF

EFFECT OF SOYBEAN EXTRUSION ON NITROGEN METABOLISM, NUTRIENT FLOW AND MICROBIAL PROTEIN SYNTHESIS IN THE RUMEN OF LAMBS

  • Ko, J.Y.;Ha, J.K.;Lee, N.H.;Yoon, C.S.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제5권3호
    • /
    • pp.571-582
    • /
    • 1992
  • Soybeans were dry extruded at three different temperatures (125, 135 and $145^{\circ}C$) for 30 s. Four lambs fitted with cannulae in the rumen and abomasums were used in a balanced $4{\times}4$ Latin square design. Lambs were fed at 2 h intervals for 12 times a day with automatic feeder to maintain steady state conditions in digestive tract. A dual-phase marker system was used to estivate ruminal flow rate of both liquid and solid digesta. Objectives of this study were to determine the effect of extrusion temperature of raw soybean on the ruminal liquid and solid dilution rate, nitrogen digestion and flow at the abomasum and availability of amino acid in lambs. There were no significant effects of extrusion on liquid and solid dilution rate, and liquid volume. Ruminal liquid flow rate was not influenced by extrusion and ranged from 389 to 435 ml/hr. Extrusion had no influence on ruminal OM digestion and flow rate to the abomasums. Dietary N flow to the abomasums increased (p < 0.05) as extruding temperature increased. Extruding temperature had a significant effect (p < 0.05) on flow of N escaping ruminal degradation and ranged from 34.91 to 57.38%. Microbial N synthesized/kg OMTDR ranged from 27 to 37 g and highest with $145^{\circ}C$ ESB diet. Extrusion decreased the amount of degradable amino acid in the rumen and increased the supply of amino acid to the lower gut, especially with 135 and $145^{\circ}C$ ESB diets.

Autolytic Enzyme을 이용한 Rhizopus oryzae의 원형질체 생성과 그 특성에 관한 연구 (Characteristics of Protoplast Induction by Autolytic Enzyme of Rhizopus oryzae)

  • 이영하;최영길
    • 한국균학회지
    • /
    • 제14권4호
    • /
    • pp.273-280
    • /
    • 1986
  • Rhizorus oryzae의 생장 및 autolysis에 따른 여러가지 autolytic enzymes의 활성도 변화와 이 autolytic enzyme system을 이용한 원형질체 생성에 관하여 조사하였다. Autolytic·phase의 culture filtrate 내에 함유된 autolytic enzyme은 Rh. oryzae 균사체로부터의 원형질체 생성에 효율적인 세포벽 분해효소로 작용하였으며 Autolytic enzyme중 원형질체 생성은 proteolytic 및 chitosanase activity와 가장 긴밀하게 관련되어 있었다. 이와같은 autolytic enzyme을 이용한 원형질체 생성은 10시간 배양한 균사체에 0.5M mannitol을 사용하였을 때 최고의 수율을 보였으며 원형질 생성의 최적온도 및 pH는 각각 $25{\sim}30^{\circ}C$$6.0{\sim}6.5$로 나타났다 한편 18시간 배양된 균사체를 osmotic stabilizer와 aut-olytic enzyme을 1 : 1이 되도록 처리하고 5시간 동안 $30^{\circ}C$에서 incubation하여 얻은 원형질체를 주사전자현미경으로 조사한 결과 효소에 의하여 가수분해되는 세포벽 주변으로부터 원형질체가 형성되는 것을 확인하였다.

  • PDF

수열 합성에 의해 제조된 다공성 Wollastonite Ceramics의 특성 (Characteristics of Porous Wollastonite Ceramics Fabricated by Hydrothermal Synthesis)

  • 김병훈;나용한
    • 한국세라믹학회지
    • /
    • 제32권8호
    • /
    • pp.893-900
    • /
    • 1995
  • The porous wollastonite ceramics were fabricated after firing calcium silicates, obtained using natural resources and by-products of power plants by hydrothermal synthesis, without organic fibers or asbestos for reinforcement agent. A specimen from diatomite as a SiO2 staring raw material had the highest strength owing to normal grain growth and good densification from homogeneous sperhcial C-S-H hydrates. A specimen from SiO2 sol as a SiO2 starting raw material showed tobermolite, but fly ash and mixed system did xonotlite after hydrothermal synthesis. The specimen from fly ash showed the lowest firing shirikage and strength changes in the firing range from 50$0^{\circ}C$ to 120$0^{\circ}C$. The other phases in all specimens changed to wollastonite phase after firing at 100$0^{\circ}C$. Also the average pore size was distributed from 0.2${\mu}{\textrm}{m}$ to 2${\mu}{\textrm}{m}$.

  • PDF

Thermotropic Polyurethanes의 合成과 機能性에 관한 硏究 (A Study on the Synthesis and Functional Properties of the Thermotropic Polyurethanes)

  • Lee, Jong Back;Song, Jin Cherl;Choi, Dae Woong
    • 한국염색가공학회지
    • /
    • 제8권2호
    • /
    • pp.1-7
    • /
    • 1996
  • Thermotropic liquid-crystalline polyurethanes were synthesized by the polyaddition reaction of such para-substiuted diisocyanate monomer as 1,4-phenylene diisocyanate(1,4-PDI) and 2,5-tolylene diisocyanate(2,5-TDI), with 4,4'-bis($\omega$-hydroxyalkoxy)biphenyls(BPm: $HOC_{m}OC_{6}H_{4}C_{6}H_{4}OC_{m}H_{2m}OH$; m is the carbon number of the hydroxyalkoxy group). These polyurethanes have mesogenic biphenyl units in the main chain. Properties of polymers were studied by differential scanning calorimetry, wide-angle X-ray scattering, thermogravimetic analysis, polarizing microscopy, and infraed spectroscopy. DSC thermograms for these polymers exhibited two endothermic peaks corresponding to phase transitions of melting and isotropization. Mesomorphic behavior of the polyurethanes were also observed under the polarizing microscope. For example, polyurethane 2,5-YDI/BP5 with [$\theta$]=0.44 prepared from 2,5-TDI and BP5 exhibited a liquid crystalline phase from 194 to 205$^{\circ}C$. Infrared spectrum study indicated that the hydrogen bonding between urethane linkages affected the mesomorphism. The thermostabilities of polyurethanes 2,5-TDI/BP5 and 1,4-PDI/BP5 were measured at a heating rate of 1$0^{\circ}C$/min in air. The temperatures of 5% weight loss for 2,5-TDI/BP5 and 1,4-PDI/BP5 were 297 and 334$^{\circ}C$, respectively.

  • PDF

정상인 경수에 대한 확산텐서영상과 PC기법을 이용한 뇌척수액 속도 측정에 관한 연구 (Diffusion Tensor Imaging and Cerebrospinal Fluid Flow Study of Cine Phase Contrast in Normal Cervical Spinal Cords)

  • 손봉경;곽소영;한용희;유장선;김옥화;고현윤;문치웅
    • Investigative Magnetic Resonance Imaging
    • /
    • 제17권2호
    • /
    • pp.123-132
    • /
    • 2013
  • 목적 : 정상인 경수에 대한 내부 부위별, 경수 레벨별 확산텐서영상과 뇌척수액 속도에 대한 정상인 기준을 마련하고자 하였다. 대상 및 방법 : 정상인을 대상으로 3T MRI를 이용하여 영상을 획득하였다. 확산텐서영상은 척수 레벨별로 각각 미리 정의해둔 백질의 후삭, 좌, 우 측삭과 회백질에 관심영역을 정하여 FA, MD에 대한 평균값을 구하였다. PC 기법을 이용한 뇌척수액 속도 측정은 C2-3, C4-5, C5-6 척수레벨을 각각 스캔한 후, 척수 레벨별 최대 수축기 및 이완기 속도를 측정하였다. 결과 : FA 값과 MD 값에서 회백질과 백질의 내부 구조 사이에서는 통계적으로 유의한 차이 (p < 0.05)를 보였다. 경수 레벨별에서는 회백질의 FA 값에서 통계적으로 유의한 차이(p < 0.05)를 보였으며, 나머지 부분에서는 통계적으로 유의한 차이를 보이지 않았다 (p > 0.05). 뇌척수액 속도 측정 결과, 평균 최대 수축기 속도 $5.18{\pm}2.00cm/sec$, 평균 최대 이완기 속도 $-7.32{\pm}3.18cm/sec$ 이었으며, 경수 레벨별로는 통계적으로 유의한 차이를 보이지 않았다 (p > 0.05). 결론 : 정상인에 대한 경수 확산텐서영상의 정량적 수치 및 경수 레벨에 영향을 받지 않는 뇌척수액 속도에 대한 평균치를 알 수가 있었다.

Chemical Leaching of Non-Equilibrium Al(Fe-Co) Powder Produced by Rod Milling

  • Kim, Hyun-Goo
    • 한국분말재료학회지
    • /
    • 제10권5호
    • /
    • pp.305-309
    • /
    • 2003
  • We report on the formation and chemical leaching of non-equilibrium $Al_{0.6}(Fe_{75}Co_{25})$ alloy produced by rod milling. X-ray diffractometry, transmission electron microscopy, differential scanning calorimetry, scanning electron microscopy, and vibrating sample magnetometry were used to characterize the as-milled and leached specimens. After 400 h, only the $Al_{0.4}Fe_{0.6}$ peak of the body-centered cubic type was present in the XRD pattern. The entire rod milling process could be divided into three different stages of milling: agglomeration, disintegration, and homogenization. The saturation magnetization, $M_s$ decreased with increased milling time, the $M_s$ of the powders before milling was about 113.8 emu/g, the $M_s$ after milling for 400 h was about 11.55 emu/g. Leaching of the Al in KOH of the Al at room temperature from the as-milled powders did not induce any significant change in the diffraction pattern. After the leached specimen had been annealed at $600^{\circ}C$ for 1 hour, the nanoscale crystalline phases were transformed into the bcc Fe, cubic Co, and $CoFe_2O_4$ phases. On cooling the specimen from 85$0^{\circ}C$, the degree of magnetization increased slightly, then increased sharply at approximately 364.8$^{\circ}C$, indicating that the bcc $Al_{0.4}Fe_{0.6}$ phase had been transformed to the Fe and Co phases.

3차원 CFD해석을 이용한 환형 역류형 연소기설계 (DESIGN OF ANNULAR REVERSIBLE COMBUSTOR WITH 3 DIMENSIONAL CFD ANALYSIS)

  • 나상권;심재경;박희호;이성준;전승배
    • 한국전산유체공학회:학술대회논문집
    • /
    • 한국전산유체공학회 2010년 춘계학술대회논문집
    • /
    • pp.247-251
    • /
    • 2010
  • It is very difficult to understand and estimate the heat transfer and flow characteristics in the combustor, which is one of main components in the Auxiliary Power Unit (APU), because its flow filed has very complex structure. In this paper, specified is characteristics of injection and flow through different air goles in the liner, which consist of large circular holes film cooling holes, and tangential air swirl holes. The durability of the liner depends on whether the surface of the liner is exposed to the hot gas over 1000 $^{\circ}C$ of a temperature or net. It is proved that the locations of hot spots estimated from the calculation using CFD are matched well with that from the test. In this study, CFD simulations were performed to examine the heat transfer and temperature distributions in and about a liner wall with film cooling on the wall. This computational study is based on the ensemble average continuity, compressible Navier-Stokes, energy, and PDF combustion equations closed by the standard $k-{\varepsilon}$ turbulence model with standard wall functions for the gas phase and the Fourier equations for conduction in the solid phase.

  • PDF

자기공명영상을 위한 개방형 새장 고주파코일 (An Open Bridcage RF coil for Magnetic Rresonance Imaging)

  • 이수열;이정한;이완;문치웅;조민형
    • 전자공학회논문지S
    • /
    • 제35S권5호
    • /
    • pp.42-47
    • /
    • 1998
  • Bridcage RF coil is one of the most widely used RF coils in MRI. In order to use birdcage RF coils in open MRI systems, an open tructured birdcage RF coil has been investigated. By opening the ring structure of an original birdcage RF coil and driving the coil at two opening ends, the original birdcage RF coil can be modified to an open structured coil. In order to improve magnetic field uniformity of the open birdcage RF coil, driving voltage phases at the two opening ends can be controlled to be in-phase or out-of-phase each other. Operating frequency of the open birdcage RF coil has been theoretically derived, and the theoretical derivation has been verified by experiments.

  • PDF

Kluyveromyces marxianus 가 생산하는 Intracellular 및 Extracellular Inulase 의 정제 및 특성비교 (Purification and Characterization of Intracellular and Extracellular Inulase from Kluyveromyces marxianus)

  • 김수일;문항식
    • Applied Biological Chemistry
    • /
    • 제30권2호
    • /
    • pp.169-178
    • /
    • 1987
  • Kluyveromyces marxianus로 부터 inulase를 생산하고 정제하며 intra 및 extracellular inulase의 성질을 조사하였다. 본 균주는 stationary phase인 24시간째 intra 및 extracelullar enzyme의 생산이 최고에 달했으며 유기 질소원으로 YNB를 사용하고 배양 중 pH를 조절해 줌으로써 효소 생산을 향상시킬 수 있었다. 조효소는 DEAE-cellulose에 의해 intra 및 extracellular inulase 모두 2개의 fraction으로 분리되었고 각 fraction의 전기영동 양상은 비슷하여 주 band를 비롯 모두 3개의 glycoprotein band가 관찰되었으며 이중 주 band만 inulase 및 invertase activity를 보유하고 있었다. 정제 효소의 inulase 및 invertase의 최적 pH는 각각 5.0과 4.5였고 intra가 extracellular enzyme 에 비해 다소 넓은 범위의 pH에서 높은 활성을 나타내었다. 모든 fraction의 최적 온도는 inulase가 $40^{\circ}C$, invertase가 $50^{\circ}C$였으며 intracellular enzyme이 더 넓은 범위의 온도에서 안정하였고 열에 대한 안정성도 intracellular inulase가 extracellular inulase보다 높게 나타났다. Km value는 intra가 $16{\sim}19mM$, extracellular inulase가 $9{\sim}11mM$로써 extracellular inulase가 inulin에 대한 친화력이 더 높았으나 모두 exo-type의 inulase로 판명되었다.

  • PDF