• 제목/요약/키워드: C-F properties

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A temperature stable bandpass filter using dieletric-filled stepped impedance resonators (접합된 Stepped impedance resonator를 이용한 온도보상형 유전체 대역통과 필터)

  • Lim, Sang-Kyu;Kim, Jun-Chul;Kim, Duck-Hwan;Ha, Jong-Su;Oh, Chang-Heon;Sim, Hwa-Sup;An, Chul
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.2
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    • pp.78-85
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    • 1998
  • The design method of a temperature stable bandpass filter using dielectric coaxial resonators of with two dielectric ceramics with opposite signs of temperature coefficient of dielectric constant (${\tau}_{\epsilon}$) to compensate for each other in this method. $MgTiO_3$(${\tau}_{\epsilon}$=+99 ppm/${\circ}C$) as a positive ${\tau}_{\epsilon}$ material and Ba($Zn_{1/3}Nb_{2/3}$)$O_3$(${\tau}_{\epsilon}$=-77ppm/${\circ}C$) as a negative material were selected. The length of a SIR for the temperature stability was calculated according to the design method and the susceptance slope parameter of the SIR was obtained. A temperature stable bandpass filter using dielectric SIR's was designed, simulated and fabricated. The center frequency of this filter was 915 MHz and the pass bandwidth was 20 MHz. Temperature properties of this bandpass filter by simulations were compared with the measured results of the bandpass filter fabricated.

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Manufacture of paste opaque porcelains using glycols as a solvent and evaluation of their physical properties (글리콜을 용매로 제조한 연고형 불투명 도재의 물성)

  • Kim, Sa-Hak
    • Journal of Technologic Dentistry
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    • v.25 no.1
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    • pp.41-62
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    • 2003
  • In this research, we manufactured the paste opaque porcelains using Propylene Glycol (PG) and Buthylene Glycol (BG) as a solvent, and compared the composition of solvents, the coefficient of thermal expansion, the particle size distribution, the viscosity and bonding strength to metal, and the tone with those of the commercial products(Duceram Plus, Duceram GmbH; VMK 95, Vita Co.; Noritake EX-3, Noritake Co.)used in the clinical field. The results of the research were as follows: 1. The result of solvent analysis indicated that the solvents included in the paste opaque porcelains of the control group were mainly composed of Glycols. 2. From the Coefficient of thermal expansion measurement, we drew out the following results; testing group: $14.0\times10^{-6}/^{\circ}C$, Duceram Plus: $13.9\times10^{-6}/^{\circ}C$, VMK 95: $14.3\times10^{-6}/^{\circ}C$, and Noritake EX-3: $13.3\times10^{-6}/^{\circ}C$. 3. Seen from the result of particle size distribution measurement, the experimental group was similar to the control group in 1$\mu m$ below, but the experimental group marked the highest distribution of 61% in the case of between 1$\mu m$ and 5$\mu m$. Between 5$\mu m$ and 10$\mu m$, they showed relatively similar distribution, and Noritake EX-3 was turned out the highest distribution of 29% in 10$\mu m$ above. 4. From the result of viscosity measurement, Duceram plus showed the highest viscosity throughout all the measurements followed by Noritake Ex-3, experimental group and VMK 95 in decreasing order. 5. The result of bonding strength measurement was EX 35.53 $\beta\acute{A}$, DU 40.88 $\beta\acute{A}$, VM 39.43 $\beta\acute{A}$, and NO 35.39 $\beta\acute{A}$, and no significant difference was found between the experimental group and the control groups(P>0.05). 6. The measurement of the tone indicated that the $L^*$ value of the experimental group was 86.89 0.63 in average, which is higher than the control group in its brightness. In the case of the $a^*$ value, Duceram Plus, VMK 95 and EX-3 showed positive value, whereas the testing group was turned out negative value. In $b^*$ value, Duceram Plus proved the highest. From the results of this research, the paste opaque porcelains using Propylene Glycol (PG) and Buthylene Glycol (BG) as a solvent did not make differences from the commercial products that are actually used in the clinical fields. Therefore, it is possible to utilize Propylene Glycol (PG) and Buthylene Glycol (BG) for the paste opaque porcelains of P.F.M crown. It is also recommended that further researches concerning the compositions and forms of powder, the types of organic solvent components and the ratio of mixture proceeded in order to improve the level of productivity in the future.

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Isolation of Serratia marcescens CK-3 against phytopathogenic fungi and its enzymatic properties (식물(植物) 병원류(病源惟) 사상균(絲狀菌)에 길항력(拮抗力)을 갖는 Serratia marcescens CK-3의 분리(分離) 및 효소적(酵素的) 성질(性質))

  • Kim, Yeong-Yil;Rhee, Young-Hwan;Kim, Kwang-Sik;Park, Hwa-Sung;Chun, Woo-Bock;Lee, Jae-Wha;Kim, Jong-Hyun
    • Applied Biological Chemistry
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    • v.34 no.1
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    • pp.54-60
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    • 1991
  • Serratia marcescens CK-3, decomposing chitin which is a mar component of cell wall in phyitopathogenic fungi, was isolated from the continuous cropping rhizosphere of pepper and cucumber and its enzymatic property was examined. S. marcescens CK-3 was found tn have an tagonistic effects against, Fusarium axysporum and Rhizoctonia solani and to have complex enzyme system such as chitinase, laminarinase, and proteinase. The preferable composition of the medium for production of chitinase was fond and was as follows : colloidal chitin 1.5%, tryptone 0.5%, glucose 1.0%, peptone 0.2%, $MgSO_4{\cdot}7H_2O\;0.1%,\;K_2HPO_4\;0.1%,\;and\;NaCl\;0.1%$(w/v), pH 6.8. The maximum enzyme production was observed after culture of 72 hours at $30^{\circ}C$ using a medium containing the above chemical composition. The optimal pH and temperature for in vitro activity of chitinase from S. marcescens CK-3 were pH 7.5 and $50^{\circ}C$, respectively. The enzyme activity in-creased by metal ions such as$Ag^+$ and $Mn^{++}$.

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Soil Physical and Chemical Properties of Forest-Fired Area in Koseong, Kangwon (강원도 고성 산화지역의 토양 이화학성 변화)

  • Nam, Yi;Min, Ell-Sik;Jang, In-Soo
    • Korean Journal of Environment and Ecology
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    • v.14 no.1
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    • pp.38-45
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    • 2000
  • This research has been done to investigate influence of soil physical and chemical properties on forest environmental change by fired pine forest in Koseong, Kangwondo. The sample sites were divided by not-fired sites(NF), not-cutting site after fired(FNC), cutting and planting sites after fired(FCP) and cutting and not-planting sites after fired(FC). Soil texture of whole sites was sandy clay loam. Sand content of NF top soil were lower than those of sub soil and clay content were higher, while FNC, FCP and FC sand content of top soil were higher than those of sub soil. Total porosity didn't differ between the sites. Coarse porosity and permeability had the increasing order as NF> FNC> FCP> FC, but fine porosity and bulk density had the opposite trends. Because forest fire removed the vegetation and then soil erosion was accelerated, forest environmental changes by forest fire greatly degraded soil porosity and permeability which were indices for forest water retention, so that soil physical properties were deteriorated. Both top and sub soil pHs of NF and FNC were higher than those of FCP and FC. Organic matter content and total nitrogen content of top and sub soils were high in order as NF> FNC> FCP> FC. Cation exchange capacities and exchangeable cation(K+, Na+, $Ca^2$+, $Mg^2$+) content in top soils were higher than those in sub soils, and in order as NF> FNC> FCP> FC, to be compared by the sites. Those mean that forest fire result from the erosion of top soil layers.

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Effects of Lime, Magnesium Sulfate, and Compound Fertilizers on Soil Chemical Properties of Acidified Forest Soils (산성화(酸性化)된 산림토양(山林土壤)에 석회(石灰), 황산고토(黃酸苦土) 및 복합비료(複合肥料) 시비(施肥)가 토양(土壤)의 화학적(化學的) 성질(性質)에 미치는 영향(影響))

  • Yoo, Jeong-Hwan;Byun, Jae-Kyoung;Kim, Choonsig;Lee, Choong Hwa;Kim, Young-Kul;Lee, Won-Kyu
    • Journal of Korean Society of Forest Science
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    • v.87 no.3
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    • pp.341-346
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    • 1998
  • The effects of CaO, $CaO+MgSO_4$, and $CaO+MgSO_4$+compound fertilizers(NPK) on soil chemical properties of acidified forest soils were studied in Quercus spp. and Pinus rigida stands in Mt. Namsan and Mt. Surak in urban areas, and Kwangnung in a mountain area. The soil samples were collected in November 1995 after every year fertilization from November 1991 through April 1995. The fertilizations affected soil chemical properties. Soil pH increased after fertilizations compared with control. However, the effect was different between the stand types and the areas. Organic matter and total nitrogen content were not changed, while exchangable cations such as calcium and magnesium increased after fertilizations. However, these ration concentrations after fertilizer treatments were lower in P. rigida than in Quercus spp. stands. These rations also showed increased leaching characteristics more in the urban area than in the mountain area.

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Effects of Surface Microstructure on Microwave Dielectric Properties of ZrO2-NiO added Ba(Zn1/3Ta2/3)O3 Ceramics (ZrO2와 NiO가 첨가된 Ba(Zn1/3Ta2/3)O3에서 표면 미세조직이 고주파 유전특성에 미치는 영향)

  • Kang, Sung-Woo;Kim, Tae-Heui;Moon, Joo-Ho;Kim, Sung-Youl;Park, Jun-Young;Choi, Sun-Hee;Kim, Joo-Sun
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.701-706
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    • 2008
  • High frequency dielectric ceramics have potential for applications in mobile and satellite communications systems at frequencies higher than 10GHz. The Ba$(Zn_{1/3}Ta_{2/3})O_3$ ceramics are known to have a high quality factor, a small temperature coefficient of the resonance frequency and a high dielectric constant. On the other hands, sintering at high temperature for extended time is required to obtain the ordered structure for high quality factor. In this study, the microwave dielectric properties of $ZrO_2$ and NiO-added Ba$(Zn_{1/3}Ta_{2/3})O_3$ ceramics prepared by solid-state reaction have been investigated. Adding $ZrO_2$ and NiO could effectively promote the densification even the case of decreasing the sintering time. At the surface of samples, secondary phase of Ba-Ta compounds was formed possibly due to the evaporation of ZnO, however, the interior of the samples remained as pure Ba$(Zn_{1/3}Ta_{2/3})O_3$. The samples sintered at $1600^{\circ}C$ for 2h exhibited 1:2 ordering of Zn and Ta cations. Excellent microwave dielectric properties of $Q{\cdot}f$(>96,000 GHz) and ${\varepsilon}_r$=30 has been obtained.

Temporal and Spatial Variations of Particulate Organic Matter in the Southeastern Coastal Bays of Korea (한반도 남동 연안내만 입자유기물질의 시$\cdot$공간 변동 특성)

  • LEE Pil-Yong;KANG Chang-Keun;CHOI Woo-Jeung;LEE Won-Chan;YANG Han-Soeb
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.1
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    • pp.57-69
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    • 2001
  • The chemical, elemental and biochemical components of the suspended particulate matter (SPM) were investigated in order to quantify particulate organic matter (POM) and assess diet quality for suspension feeders in the southern coastal bay systems of Korea where the marine farming of the suspension feeders are most active, The intense field observation program was carried out seasonally in the three coastal bay systems of Chinhae, Gosung and Kangjin bays, The SPM was characterized as collective properties of organic carbon (POC), nitrogen (PON), phosphorus (PP) and more refined collective properties of protein (PPr), carbohydrate (PCHO) and chlorophyll a (Chl a) compound. Although the three coastal bays are regarded as phytoplankton based ecosystem, the SPM is not composed entirely with phytoplankton cells. Due to the shallow water depth, resuspension of bottom sediment contributes significantly to some of the regions. Therefore, concentration of SPM in the surface water did not co-vary with Chl a or PPr, PCHO. In general, temporal variation of POC, PON and Chl a contents in seawater were closely associated with phytoplankton biomass in the three coastal bays, However, PPr and PCHO contents in seawater were higher in Chinhae bay than in Gosung and Kangjin bays and Chl a PPr-N ratio was higher in Chinhae bay than in Kosung and Kangjin bays, since Chinhae bay is more eutrophicated than other bays. Average C : N ratios from regressions of POC and PON of SPM were 6.6, 6.6 and 5.0 in Chinhae, Gosung and Kangjin bays, respectively. SPM in Chinhae and Gosung bays appears to be made of largely phytoplankton cells and SPM in Kangjin bay appears to be contributed from the bacterial biomass due to the shallow water depth. N : P ratios from regressions of PON and PP of SPM were 10.8 and 14.7 in spring, and 18.2 and 24.6 in Chinhae and Gosung bays, respectively. With respect to the hypothetical Redfield molecule, phytoplankton appears to be limited by the lack of N and f in spring and summer, respectively, in the two bays, In Kangjin bay, N : P ratios from regressions of PON and PP of SPM were varied from 6.3 to 12.8 throughout the year. The low N : P ratio with resepct to the hypothetical Redfield molecule, phytoplankton growth appears to be limited by the lack of N-nutrients.

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Isolation of Marine Bacteria Killing Red Tide Microalgae I. Isolation and Algicidal Properties of Micrococcus sp. LG-1 Possessing Killing Activity for Harmful Dinoflagellate, Cochlodinium polykrikoides (적조생물 살조세균 탐색 I. 유해 적조생물 Cochlodinium Polykrikoides 살조세균 Micrococcus sp. LG-1의 분리와 살조특성)

  • PARK Young-Tae;PARK Ji-Bin;CHUNG Seong-Youn;Song Byung-Chul;LIM Wol-Ae;KIM Chang-Hoon;LEE Won-Jae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.5
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    • pp.767-773
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    • 1998
  • In this study, we have investigated the distributions and killing effects of marine bacteria that tend to kill the red tide microalgae, C. polykikoides in the area of Masan bay from June to October, 1996. To summarize, C. polykikoides killing bacteria were detected at $10^2$ to $10^3$ cells/ml of seawater samples during the survey period, and the bloom was observed in September by containing $4.8\times10^3$cells/ml. It appears however that the number of these bacteria is decreased ($2.0\times10^2$cells/ml) in October, A total of 110 strains were isolated from seawater samples and seawater filtrate (pore size, 0.8 $\mu$m)-containing mixed culture of C. polykikoides in which the mixed culture was grown in f/2 medium. As results we have successfully isolated Micrococcus sp. LG-1 which decreased to less than 10cells/ml within 6days and 5days sfter inoculation of Micrococcus sp. LG-1 into the la9 and logarithmic growth phases of C. polykrikoides respectively. Therefore, it appears that inoculation of Micrococcus sp. LG-1 against the logarithmic C. polykrikoides is more effective than the lag growth phase, (n addition, the killing effects were increased in accordance with bacterial cell densities inoculated in a dose dependent manner. Especially, the filtrate of kitling bacterium culture (nore size, 0.2 $\mu$m) revealed a dramatic effect in which C. polykrikoides were decreased to less than 10 cells/mf of culture within 1 hr, 1,5 hrs, 1,5 hrs, 3.5 hrs. and 5,5 hrs after inoculations of the culture filtrate with concentration of $30\%,\;20\%,\;10\%,\;5\%$ and $2.5\%$, respectively. Moreover Micrococcus sp. LG-1 showed a selective specificity against C. polykrikoides and any other killing effects of Micrococcus sp. LG-1 were not observed against Alexandrium tamarense, Prorocentrum micans, Scrippsiella trochoidea. ana Gymnodinium sanguineum.

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Thermal Properties of Granite from the Central Part of Korea (한국 중부 지역의 화강암 열물성)

  • Kim, Jongchan;Lee, Youngmin;Koo, Min-Ho
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.441-453
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    • 2014
  • Thermal and physical properties were measured on 206 Jurassic granite samples obtained from three boreholes in the central part of Korea. Thermal conductivity(${\lambda}$), thermal diffusivity(${\alpha}$), and specific heat(Cp) were measured in a laboratory; the average values are ${\lambda}$=2.813 W/mK, ${\alpha}=1.296mm^2/sec$, and Cp=0.816 J/gK, respectively. In addition, porosity(${\phi}$), and dry and saturated density(${\rho}$) were measured in the laboratory; the average values are ${\phi}$=0.01, ${\rho}(dry)=2.662g/cm^3$ and ${\rho}(saturated)=2.67g/cm^3$, respectively. Thermal diffusivity of 10 granite samples were measured with increasing temperature from $25^{\circ}C$ to $200^{\circ}C$. In this study, we found that thermal diffusivity at $200^{\circ}C$ is about 30% lower than thermal diffusivity at $25^{\circ}C$. In correlation analysis, thermal conductivity increases with increasing thermal diffusivity. However, thermal conductivity does not show good correlation with porosity and density. Consequently, we know that thermal conductivity of granite would be more influenced by mineral composition than by porosity. We also derived ${\rho}=-2.393{\times}{\phi}+2.705$ from density and porosity data. XRD and XRF analysis were performed to investigate effects of mineral and chemical composition on thermal conductivity. From those results, we found that thermal conductivity increases with increasing quartz and $SiO_2$, and decreases with increasing albite and $Al_2O_3$. Regression analysis using those mineral and chemical composition were carried out ; we found $K=0.0294V_{Quartz}+1.93$ for quartz, $K=0.237W_{SiO_2}-14.09$ for $SiO_2$, and $K=0.053W_{SiO_2}-0.476W_{Al_2O_3}+6.52$ for $SiO_2$ and $Al_2O_3$. Specific gravities were measured on 10 granite samples in the laboratory. The measured specific gravity depends on chemical compositions of granite. Therefore, specific gravity can be estimated by the felsic-mafic index(F) that is calculated from chemical composition. The estimated specific gravity ranges from 2.643 to 2.658. The average relative error between measured and estimated specific gravities is 0.677%.

Perfluoropolymer Membranes of Tetrafluoroethylene and 2,2,4Trifluofo- 5Trifluorometoxy- 1,3Dioxole.

  • Arcella, V.;Colaianna, P.;Brinati, G.;Gordano, A.;Clarizia, G.;Tocci, E.;Drioli, E.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.39-42
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    • 1999
  • Perfluoropolymers represent the ultimate resistance to hostile chemical environments and high service temperature, attributed to the presence of fluorine in the polymer backbone, i.e. to the high bond energy of C-F and C-C bonds of fluorocarbons. Copolymers of Tetrafluoroethylene (TEE) and 2, 2, 4Trifluoro-5Trifluorometoxy- 1, 3Dioxole (TTD), commercially known as HYFLON AD, are amorphous perfluoropolymers with glass transition temperature (Tg)higher than room temperature, showing a thermal decomposition temperature exceeding 40$0^{\circ}C$. These polymer systems are highly soluble in fluorinated solvents, with low solution viscosities. This property allows the preparation of self-supported and composite membranes with desired membrane thickness. Symmetric and asymmetric perfluoropolymer membranes, made with HYFLON AD, have been prepared and evaluated. Porous and not porous symmetric membranes have been obtained by solvent evaporation with various processing conditions. Asymmetric membranes have been prepared by th wet phase inversion method. Measure of contact angle to distilled water have been carried out. Figure 1 compares experimental results with those of other commercial membranes. Contact angles of about 120$^{\circ}$for our amorphous perfluoropolymer membranes demonstrate that they posses a high hydrophobic character. Measure of contact angles to hexandecane have been also carried out to evaluate the organophobic character. Rsults are reported in Figure 2. The observed strong organophobicity leads to excellent fouling resistance and inertness. Porous membranes with pore size between 30 and 80 nanometers have shown no permeation to water at pressures as high as 10 bars. However high permeation to gases, such as O2, N2 and CO2, and no selectivities were observed. Considering the porous structure of the membrane, this behavior was expected. In consideration of the above properties, possible useful uses in th field of gas- liquid separations are envisaged for these membranes. A particularly promising application is in the field of membrane contactors, equipments in which membranes are used to improve mass transfer coefficients in respect to traditional extraction and absorption processes. Gas permeation properties have been evaluated for asymmetric membranes and composite symmetric ones. Experimental permselectivity values, obtained at different pressure differences, to various single gases are reported in Tab. 1, 2 and 3. Experimental data have been compared with literature data obtained with membranes made with different amorphous perfluoropolymer systems, such as copolymers of Perfluoro2, 2dimethyl dioxole (PDD) and Tetrafluorethylene, commercialized by the Du Pont Company with the trade name of Teflon AF. An interesting linear relationship between permeability and the glass transition temperature of the polymer constituting the membrane has been observed. Results are descussed in terms of polymer chain structure, which affects the presence of voids at molecular scale and their size distribution. Molecular Dyanmics studies are in progress in order to support the understanding of these results. A modified Theodoru- Suter method provided by the Amorphous Cell module of InsightII/Discover was used to determine the chain packing. A completely amorphous polymer box of about 3.5 nm was considered. Last but not least the use of amorphous perfluoropolymer membranes appears to be ideal when separation processes have to be performed in hostile environments, i.e. high temperatures and aggressive non-aqueous media, such as chemicals and solvents. In these cases Hyflon AD membranes can exploit the outstanding resistance of perfluoropolymers.

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