• Bulletin of the Korean Chemical Society
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• 제29권1호
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• pp.191-196
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• 2008

Kinetic studies of the reactions of a-bromoacetanilides [YC6H4NHC(=O)CH2Br] with substituted benzylamines (XC6H4CH2NH2) have been carried out in dimethyl sulfoxide at 35.0 oC. The Hammett plots for substituent (Y) variations in the substrate (log kN vs. sY) are biphasic concave upwards/downwards with breaks at Y = 4-Cl (sY = 0.23). The Hammett coefficients rY and the cross-interaction constant rXY (= +0.16) are positive for sY 0.23, while the rY values are positive/negative [rY > 0 for X = (4-MeO and 4-Me) and rY < 0 for X = (H, 4-Cl and 3-Cl)] and the rXY (= -1.51) value is negative for sY ³ 0.23. Based on these and other results, the benzylaminolyses of a-bromoacetanilides are proposed to proceed through rate-limiting expulsion of the bromide leaving group from a zwitterionic tetrahedral intermediate, T, with a bridged transition state for s Y 0.23, while the reaction proceeds through concerted mechanism with an enolate-like TS in which the nucleophile attacks the a-carbon for s Y ³ 0.23.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
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• pp.154-155
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• 2003

Substituting transition metals such as V, Cr, Mn, Fe, Co and Ni into semiconductors have been of interest because of its unique electrical and magnetic properties. It was reported that the magnetoresistance(MR) ratio of CrGe was 1.7% and 1 4% at 120 K in fields of 0.5 and 5 T, respectively. The MR ratio of FeGe was 19% at 180K. The electrical resistivity of CrGe changed according to Cr concentration. In this talk, we report transport properties of V-doped Ge single crystals with several different V concentrations. The carrier densities and mobilities will be determined from Hall measurement.

• 열처리공학회지
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• 제6권4호
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• pp.194-203
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• 1993

Rapid solidified splats Al-(1, 3, 5Cr) Alloys were produced by atomization-splat quenching method. Effects of mechanical alloying on the structure and mechanical properties of rapidly solidified Al-(1, 3, 5)Cr alloys were studied. Degree of mechanical alloying of Al-(1, 3, 5)Cr alloys can be determined by observing the microstructural refinement, microhardness and microstructure of Al-(l, 3, 5)Cr splats during processing. In the initial stage of mechanical alloying of the Al-(1, 3, 5)Cr splats fracturing of the grain boundaries occured first, followed after fracturing of zone A regions. Saturation hardness of Al-(1, 3, 5)Cr alloys increased proportionally with increasing concentration of the solute (Cr). Age hardening was not observed in these alloys. Decomposition temperature of Al-1Cr splats after mechanical alloying was higher than that of Al-5Cr splats. The density of $Al_7$ Cr precipitates increased proportionally with increasing chromium content, as a result, there was a transition to finely and spherically dispersed phase after mechanical alloying.

• Bulletin of the Korean Chemical Society
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• 제32권1호
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• pp.95-99
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• 2011

$CaTi_{1-x}Fe_xO_3(0{\leq}x{\leq}0.4)$ solid solution photocatalysts were synthesized by iron doping during the conventional solid state reaction at $1100^{\circ}C$ for 5 h and characterized by ultraviolet-visible (UV-vis) absorption spectroscopy, X-ray diffraction, morphological analysis. We found that $CaTi_{1-x}Fe_xO_3$ samples not only absorb UV but also the visible light photons. This is because the Fe substitution at Ti-site in $CaTi_{1-x}Fe_xO_3$ lattice induces the band transition from Fe3d to the Fe3d + Ti3d hybrid orbital. The photocatalytic activity of Fe doped $CaTiO_3$ samples for hydrogen production under UV light irradiation decreased with the increase in the Fe concentration. There exists an optimized concentration of iron in $CaTiO_3$, which yields a maximum photocatalytic activity under visible light ($\lambda\geq420nm$) photons.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2009년도 춘계학술대회 논문집
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• pp.267-269
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• 2009

In this paper, insulations characteristics by temperature changes($+10{\sim}-60[^{\circ}C]$) of $SF_6$ 9as in the experimental chamber were studied. From this result, The breakdown characteristics classify the gas & liquid coexisted stage of voltage value increases & much deviation and the $V_B$ low stage as the interior of chamber gets filled with mixture of $SF_6$ that are not liquefacted and remaining air which couldn't be ventilated. In addition the ability of insulation of liquid $SF_6$ was higher than that of the highly pressurized $SF_6$ gas. In this research, we want to provide the base data on designing insulation of high-temperature superconductor and the cryogenic equipments by investigating the insulation characteristics of $SF_6$.

• 한국전기전자재료학회논문지
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• 제27권12호
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• pp.797-802
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• 2014

In this study, in order to develop the capacitor composition ceramics with the good dielectric properties, $(Ba_{1-x}Ca_x)(Ti_{0.85}Zr_{0.12}Sn_{0.03})O_3$ (abbreviated as BCTZ) ceramics were prepared by the conventional solid-state reaction method. The effects of Ca substitution on the microstructure and dielectric properties was investigated. The X-ray diffraction patterns demonstrated that all the specimens showed perovskite phase, and secondary phases are indicated in the measurement range of X-ray diffraction. Also, all the specimens indicated an rhombohedron phase structure. It was identified from the X-ray diffraction patterns that the secondary phase formed in grain boundaries and then decreased the dielectric properties. For all the specimens, observed one peak was tetragonal cubic phase transition temperature($T_c$), which is located in the vicinity of room temperature.

• Journal of Magnetics
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• 제16권1호
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• pp.15-18
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• 2011

We have studied the $TiO_2$ doping effects on the flux pinning behavior of an $MgB_2$ superconductor synthesized by the in-situ solid-state reaction. From the field-cooled and zero-field-cooled temperature dependences of magnetization, the reversible-irreversible transition of $TiO_2$-doped $MgB_2$ was determined in the H-T diagram (the temperature dependence of upper critical magnetic field and irreversibility line). For comparison, the similar measurements are also obtained from SiC-doped $MgB_2$. The critical current density was estimated from the width of hysteresis loops in the framework of Bean's model at different temperatures. The obtained results manifest that nano-scale $TiO_2$ inclusions served as effective pinning centers and lead to the enhanced upper critical field and critical current density. It was concluded that the grain boundary pinning mechanism was realized in a $TiO_2$-doped $MgB_2$ superconductor.

• 한국재료학회지
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• 제22권11호
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• pp.569-574
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• 2012

Large single grain $Gd_{1.5}Ba_2Cu_3O_{7-y}$ (Gd1.5) bulk superconductors were fabricated by a top-seeded melt growth (TSMG) process using an $NdBa_2Cu_3O_{7-y}$ seed. The seeded Gd1.5 powder compacts with a diameter of 50 mm were subjected to the heating cycles of a TSMG process. After the TSMG process, the diameter of the single grain Gd1.5 compact was reduced to 43 mm owing to the volume contraction during the heat treatment. The superconducting transition temperature ($T_c$) of the top surface of the single grain Gd1.5 sample was as high as 93.5 K. The critical current densities ($J_cs$) at 77 K and 1T and 1.5 T were in ranges of 25,200-43,900 $A/cm^2$ and 10,000-23,000 $A/cm^2$, respectively. The maximum attractive force at 77 K of the sample field-cooled using an Nd-B-Fe permanent magnet (surface magnetic field of 0. 527 T) was 108.3 N; the maximum repulsive force of the zero field-cooled sample was 262 N. The magnetic flux density of the sample field-cooled at 77 K was 0.311T, which is approximately 85% of the applied magnetic field of 0.375 T. Microstructure investigation showed that many $Gd_2BaCuO_5$ (Gd211) particles of a few ${\mu}m$ in size, which are flux pinning sites of Gd123, were trapped within the $GdBa_2Cu_3O_{7-y}$ (Gd123) grain; unreacted $Ba_3Cu_5O_8$ liquid and Gd211 particles were present near the edge regions of the single grain Gd1.5 bulk compact.

• 한국해양공학회지
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• 제25권3호
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• pp.66-72
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• 2011

This is the fourth of a series of companion papers dealing with the mechanical property reductions of various marine structural steels. Even though a reduction of the elastic modulus according to temperature increases has not been obtained from experiments, high temperature experiments from room temperature to $900^{\circ}C$ revealed that initial the yield strength and tensile strength are both seriously degraded. The mechanical properties obtained from high temperature experiments are compared with those from EC3 (Eurocode 3). It is found that the high temperature test results generally comply with the prediction values by EC3. Based on the prediction of EC3, time domain nonlinear finite element analyses were carried out for a blast wall installed on a real FPSO. After applying the reduced mechanical properties, corresponding to $600^{\circ}C$ to the FE model of the blast wall, more than three times the deflections were observed and it was observed that most structural parts experience plastic deformations exceeding the reduced yield strength at the high temperature. It is noted that a protection facility such as PFP (passive fire protection) should be required for structures likely to be directly exposed to fire and explosion accident.

• Journal of the Korean Wood Science and Technology
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• 제27권2호
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• pp.15-22
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• 1999

진동 충격음 흡수성능을 지니는 샌드위치구조 목질 복합재료 제조용 폴리머는 넓은 온도범위(또는 주파수 범위)에서 높은 손실계수를 지니면서, 동시에 $5{\times}10^7\sim-10^9\;dyne/cm^2$의 탄성율을 지녀야 한다. 본실험에서는 이러한 점탄성 거동율 나타내는 고분자재료의 제조를 목적으로 에폭시 수지/아크릴 수지 상호침투망목고분자(IPNs)를 동시망목형성법으로 합성하였다. 고분자의 동적 점탄성은 Rheovibron을 사용하여 110Hz에서 측정하였으며, 복합체의 손실계수 및 동탄성 계수는 Rheovibron을 개조한 양단지지 강제 휨 진동법으로 주파수 110Hz에서 측정하였다. 동력학적 측정 결과, 손실탄성율의 최대값 온도 및 손실계수의 최대값 온도가 이동하고, 유리전이 영역이 확대되어, 이 IPNs계는 부분 상용계임을 알 수 있었다. 특히, 70/30 및 50/50 조성의 Epikote871/P(n-BMA) IPNs는 넓은 온도 범위에서 비교적 높은 손실계수 및 적당한 탄성율을 나타냈다. 또한 이를 적층한 목질 복합체는 넓은 온도 범위에서 비교적 높은 진동흡수 계수를 나타냈다.