• Title/Summary/Keyword: C/N ratio of POM

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Annual Change and C:N:P ratio in Particulate Organic Matter in Chinhae Bay, Korea (한국진해만 입자유기물 함량과 C:N:P 비의 연변화)

  • LEE, PIL-YONG;KANG, CHANG-KEUN;PARK, JONG-SOO;PARK, JOO-SUCK
    • 한국해양학회지
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    • v.29 no.2
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    • pp.107-118
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    • 1994
  • An investigation of the annual change and C:N:P ratio in particulate organic matter (POM) in Chinhae Bay, a semi-enclosed bay of the southern coast of Korean Peninsula, was carried out for a period of 12 months between January and December, 1993. The concentrations of POM have a broad range: 198∼4,416 ugC/l, 24∼792 ugN/l and 4.5∼69.0 ugP/l, Marked seasonal changes of POM, particularly particulate organic carbon (POC) and nitrogen (PON), were observed in the surface water. Generally, the concentration of POM peaks in summer. The C:N:P composition ratio of particulate organic matter, which is high in summer, also shows a seasonal change. The C:N assimilation ratio is constant at 6.53, which is consistent with the Redfield ratio. The significant linear relationship between POM and chlorophyll-a in the surface water during the survey period (except for January and February) and the C:N ratio suggest that the concentration of POM is controlled by phytoplankton biomass. POM peaks in summer, a period characterized by high freshwater input and the strong stratification, as a result of the intense proliferation of phytoplankton by a large amount of nutrient loading from the tributaries. On the other hand, the high C:P and N:P ratios in summer indicate that P is limited for phytoplankton growth owing to N-enrichment from a high input of freshwater with a high dissolved inorganic N:P ratio.

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A Study on Vertical Distribution and Origin of Particulate Organic Matter in Shingu Reservoir in Pre-monsoon and Post-monsoon Period - Application of Carbon and Nitrogen Stable Isotope Ratio - (하계 강우기 전.후 신구저수지 내 입자성유기물의 수직분포 및 기원 연구 - 탄소 및 질소 안정동위원소비의 활용 -)

  • Kim, Min-Seob;Lee, Yeon-Jung;Shin, Kyung-Hoon;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.41 no.spc
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    • pp.27-34
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    • 2008
  • The vertical distribution and origin of particulate organic matter (POM) were investigated in Shingu reservoir on 4th July (pre-monsoon) and 7th August (post-monsoon) 2006. High turbid water (120 NTU) were found at 4.5 m water depth in postmonsoon period. The average C/N ratio of POM was about 5.70 and 6.96 in surface water and bottom water, respectively in pre-monsoon period, exhibiting the close values to its ratio in phytoplankton cell. However, the average C/N ratio was 7.10 in surface water and 12.81 in bottom water in post-monsoon period. In addition, the ${\delta}^{13}C$ values of POM in pre-monsoon period ranged from -25.1%o to -26.1%o in whole water column, but the ${\delta}^{13}C$ values of POM in post-monsoon period showed relatively wide range between -23.2%o and -27.5%o. The apparently lighter values (average -27.5%o) in near bottom water (4.5 m water depth) demonstrate that POM in high turbid water in post-monsoon period may be derived from the outside terrestrial plants through heavy rainfall during the summer monsoon period. The present study suggests that carbon and nitrogen stable isotope ratios as well as C/N ratios should be useful indexes to clarify the origin of POM.

The Origin and Characteristics of Sedimentary Organic Matter on Sindu-ri Tidal Flat, Korea (신두리 갯벌 퇴적 유기물의 기원과 특성)

  • Shin, Woo Seok
    • Journal of Wetlands Research
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    • v.22 no.2
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    • pp.59-65
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    • 2020
  • The purpose of this study is to determine the origin of organic matter on sediment at Sindu-ri tidal flat. Grain size, organic matter, C/N ratio and the 13C and δ15N ratio were measured at three stations (Stn. A, B, C) of the tidal flat. As a result, the spatial variation in sediment properties showed that organic matter was related positively to the sediment mud content. Organic matters originating from marine particulate organic matter (marine POM) and fish farm particulate organic matter (fish farm POM) showed sedimentation of organic matters at Stn. A, sandy tidal flat, though terrestial plant (TP) and benthic microalgae (BMA) did at Stn.C, muddy tidal flat. Meanwhile, Stn. B, the intermediate property of Stn. A and C, was affected by marine POM and BMA. Furthermore, it was revealed that the amount and origin of organic matters in the sediments depended on spatial variation, and the factors were different from the stations. Particularly, at the Stn. C, the sediment showed high concentration of TOC in terrestrial organic matter and smaller size particles (< 63 ㎛). These facts suggest the many small size particles and organic matter will affect the sediment environmental condition in the Stn. C.

Contribution of Marine Microbes to Particulate Organic Matter in the Korea Strait

  • Kang, Hun;Kang, Dae-Seok
    • Journal of the korean society of oceanography
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    • v.37 no.1
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    • pp.35-44
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    • 2002
  • To assess the relative contribution of bacterial and phytoplankton biomasses to particulate organic matter (POM) in the water column, microbial abundance and biomass were from two transects in the western channel of the Korea Strait in 1996. Bacterial abundance had a mean value of $5.9{\times}10^5$ cells/ml and chlorophyll-a averaged 0.14 ${\mu}g/l$. Bacterial abundance in the Korea Strait showed a positive relationship with chlorophyll-a concentration, while the distribution of POM did not covary with chlorophyll-a. Particulate organic carbon (POC) and nitrogen (PON) concentrations were greater in August than in October. Bacterial carbon (POC) and nitrogen (PON) concentrations were greater in August than in October. Bacterial carbon and nitrogen biomasses were 7.29 ${\mu}gC/l$ and 1.24 ${\mu}gN/l$, respectively, during the study periods. Bacterial biomass was larger in October than in August due to the autumn phytoplankton bloom. Phytoplankton biomass based on chlorophyll-a was 7.67 ${\mu}gC/l$ for carbon and 1.10${\mu}gN/l$l for nitrogen. The ratio of bacterial carbon (BC) to phytoplankton carbon (Cp) averaged 0.95 in the Korea Strait in 1996. Bacteria may play a more significant role in the dynamics of POM than phytoplankton do in August, with BC/Cp ratio of 1.26. The ratio of BC to Cp increased with a decrease in chlorophyll-a concentration. Averaged over all the samples in both cruises, the contribution of microbial biomass to POC and PON was about 43% and 51%, respectively. Bacterial assemblage constituted a significant fraction of POC (21%) and PON (27%). Phytoplankton accounted for 22% of POC and 24% of PON. Microbial biomass played a more important role in the dynamics of POC and PON in October than in August due to a significant increase in microbial biomass in the southern transect (transect-B) in October by the autumn phytoplankton bloom. This study showed that marine microbes may constitute a significant part in the reservoir of POM in the Korea Strait.

Characteristics of Allochthonous Organic Matter in Large Dam Reservoir, Lake Soyang (소양호에서 외부기원유기물의 유입, 유출 특성)

  • Park, Hae-Kyung;Kwon, Oh-youn;Jung, Dong-Il
    • Journal of Korean Society on Water Environment
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    • v.27 no.1
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    • pp.88-97
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    • 2011
  • To identify the inflow and outflow characteristics of allchthonous organic matters and examine the change of allochthonous organic matter load pattern due to the climate change, we investigated the temporal variations of DOC and POC concentrations within inflow water and dam discharge water and spatio-temporal distribution of POM within the lake water in Lake Soyang which is the largest dam reservoir in Korea in 2006. Most of allochthonous DOC flowed into the lake water during initial rain and was not affected by the amount of precipitation, whereas most of allochthonous POC flowed into during concentrated heavy rain and the concentration of POC was significantly associated with the amount of inflow water and precipitation. Calculated annual allochthonous organic matter loads in Lake Soyang from 2003 to 2006 using the regression equation between the amount of inflow water and the concentration of POC indicate allochthonous organic matter loads are mainly affected by total influx and extreme influx of inflow water. The spatio-temporal distribution of POM indicated allochthonous organic matter of inflow river during flood period in July transported from upper part to middle and lower part of the lake a month later respectively along the middle layer of water column in Lake Soyang.

Effect of Styrene and Maleic Anhydride Content on Properties of PP/Pulp Composites and Reactive Extrusion of Random PP (랜덤 PP의 반응압출 및 PP/Pulp 복합체 특성에 대한 스티렌과 무수말레인산 함량의 영향)

  • Lee, Jong Won;Kim, Ji Hyun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.318-323
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    • 2014
  • In order to analyze the effect of maleic anhydride (MAH) content and styrene monomer (SM)/MAH mole ratio on reactive extrusion of maleic anhydride grafted random polypropylenes (MAH-g-rPP), MAH-g-rPPs were prepared by using a twin screw extruder. MAH contents were 0.5, 1.0, 3.0, and 5.0 phr and SM/initiator mole ratio was 0.0, 1.0, and 2.0. Dicumyl peroxide (DCP) was used as an initiator. The graft degree of MAH was confirmed by the existence of carbonyl group (C = O) stretching peak at $1700cm^{-1}$ from FT-IR spectrum. The degree of graft reaction increased up to 3.0 phr MAH and showed the optimum value at 1.0 SM/MAH mole ratio from the area ratio of C = O and C-H stretching peak. Thermal and crystallization properties of MAH-g-rPP and PP/MAH-g-rPP/pulp composites were investigated by DSC, TGA, XRD, and POM. There was a decrease in non-isothermal crystallization temperature of PP/MAH-g-PP/pulp composites. Based on tensile properties and SEM pictures for the fractured surface of PP/MAH-g-PP/pulp composites, MAH content of 1.0 wt% and SM/MAH mole ratio of 1.0 were the optimum formulation as the compatibilizer. The rheological properties of the composites were measured by dynamic Rheometer to compare the processability of the composites with and without compatibilizer. The power law index showed slightly low value at the composites with compatibilizer.

Temporal and Spatial Variations of Particulate Organic Matter in the Southeastern Coastal Bays of Korea (한반도 남동 연안내만 입자유기물질의 시$\cdot$공간 변동 특성)

  • LEE Pil-Yong;KANG Chang-Keun;CHOI Woo-Jeung;LEE Won-Chan;YANG Han-Soeb
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.1
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    • pp.57-69
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    • 2001
  • The chemical, elemental and biochemical components of the suspended particulate matter (SPM) were investigated in order to quantify particulate organic matter (POM) and assess diet quality for suspension feeders in the southern coastal bay systems of Korea where the marine farming of the suspension feeders are most active, The intense field observation program was carried out seasonally in the three coastal bay systems of Chinhae, Gosung and Kangjin bays, The SPM was characterized as collective properties of organic carbon (POC), nitrogen (PON), phosphorus (PP) and more refined collective properties of protein (PPr), carbohydrate (PCHO) and chlorophyll a (Chl a) compound. Although the three coastal bays are regarded as phytoplankton based ecosystem, the SPM is not composed entirely with phytoplankton cells. Due to the shallow water depth, resuspension of bottom sediment contributes significantly to some of the regions. Therefore, concentration of SPM in the surface water did not co-vary with Chl a or PPr, PCHO. In general, temporal variation of POC, PON and Chl a contents in seawater were closely associated with phytoplankton biomass in the three coastal bays, However, PPr and PCHO contents in seawater were higher in Chinhae bay than in Gosung and Kangjin bays and Chl a PPr-N ratio was higher in Chinhae bay than in Kosung and Kangjin bays, since Chinhae bay is more eutrophicated than other bays. Average C : N ratios from regressions of POC and PON of SPM were 6.6, 6.6 and 5.0 in Chinhae, Gosung and Kangjin bays, respectively. SPM in Chinhae and Gosung bays appears to be made of largely phytoplankton cells and SPM in Kangjin bay appears to be contributed from the bacterial biomass due to the shallow water depth. N : P ratios from regressions of PON and PP of SPM were 10.8 and 14.7 in spring, and 18.2 and 24.6 in Chinhae and Gosung bays, respectively. With respect to the hypothetical Redfield molecule, phytoplankton appears to be limited by the lack of N and f in spring and summer, respectively, in the two bays, In Kangjin bay, N : P ratios from regressions of PON and PP of SPM were varied from 6.3 to 12.8 throughout the year. The low N : P ratio with resepct to the hypothetical Redfield molecule, phytoplankton growth appears to be limited by the lack of N-nutrients.

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Nitrification and Denitrification of Land-based Fish Farm Wastewater using an Anaerobic-Aerobic Upflow Biological Aerated Filter (혐기-호기 상향류 필터 공정에서 양식배출수의 질산화 및 탈질 연구)

  • Park, Noh-Back;Lee, Hyun-Young;Kim, Seong-Min;Lee, Jun-Sang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.47 no.5
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    • pp.622-629
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    • 2014
  • This study induced biological denitrification and nitrification via a biofiltration process with the view of removing nitrogen from land-based fish farm effluent. To achieve this, we operated an aquaculture nitrogen-removal system that includes a denitrification and nitrification reactor [working volume 40 L, flow rate 64.8 L, HRT (hydraulic retention time) 14.8 h, HRT considering recycling of NOx 7.4 h]. In the continuous process, the nitrification rate of ammonium nitrogen exceeded 90% at a steady state and the denitrification efficiency exceeded 80% with recycling to a pre-anoxic reactor. In addition, the pH in the final effluent was lower with a low influent water alkalinity averaging 100 mg/L (as $CaCO_3$). For effective denitrification reactions, carbon must be supplied via particulate organic matter (POM) hydrolysis because of the low C/N (carbon/nitrogen) ratio in the water.