• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.13-18
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• 2017

Sodium borohydride, $NaBH_4$, shows a number of advantages as hydrogen source for UAV PEMFC (Unmaned Aerial Vehicle Proton Exchange Membrane Fuel Cells). In order to use for UAV, the weight and volume of byproduct should be small after $NaBH_4$ hydrolysis reaction. Therefore, the weight and volume of byproduct were studied after $NaBH_4$ hydrolysis reaction using unsupported catalyst. The effect of catalyst type, concentration of $NaBH_4$, concentration of NaOH and thickness of catalyst pack on the weight and volume of byproduct were studied. Most of byproduct was $NaB(OH)_4$ and superficial volume of byproduct increased due to foam evolved from byproduct. The weight and volume of byproduct were not affected by concentration of NaOH used stabilizer. The weight of byproduct decreased as concentration of $NaBH_4$ solution increased, but maximum volume of byproduct obtained at 23 wt% of $NaBH_4$. Suitable defoaming agent reduced the volume of byproduct.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.369-375
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• 2008

To achieve zero-emission, one of the main goals of an eco-industrial park (EIP), it is needed to develop an effective water exchange network. The network includes various subsystems and decision making processes, which make the modeling process extremely complicated. Agent-based modeling was used to simulate water exchange network in an EIP. Firm agents were created based on the behavior pattern of firms, and an agent-based model (ABM) was made with the agents, showing the growth of the exchange network. An existing steel and iron making industrial park was chosen as a case study, and the ABM model shows eco-efficient behavior with a decreased environmental cost. Water reuse network based on the ABM model results in 35% decrease of the fresh water supply and 50% reduction of the wastewater generation in EIP. A case study shows that agent-based model can be a powerful tool in modeling and designing complex eco-industrial parks, especially when a part of the system needs to be changed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2002.04a
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• pp.18-23
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• 2002

Liquid phase mixing of impinging injector is a resultant byproduct from the momentum exchange between a pair of impinging jets and penetration of opponent jet. Principal aim of the present study is revealing the liquid phase mixing mechanism of split triplet impinging injection sprays, and thus extending our understanding on this particular injection element. Overall mixing extent is estimated from patternation tests by the use of purified tap water and kerosene to simulate the real propellant components, respectively, and with the liquid jet momentum ratio, a controlling mixing parameter, in the range of 0.5 to 6.0. Emphasis is placed on the effect of liquid sheet superposition and disintegration, and the results with detailed spray visualization revealed the fact that superposed liquid sheet disintegration is the main pathway of liquid phase mixing of split triplet impinging injector to yield enhanced mixing qualities.

• Journal of Powder Materials
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• v.27 no.4
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• pp.287-292
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• 2020

The subject of this study is a zeolite generated as a by-product of recycling LAS (lithium-aluminum-silicate) resources, a kind of glass and ceramic produced by induction. The zeolite by-product is modified into Mg-zeolite using Mg as a cation to absorb Pb, a heavy metal generated from water pollution caused by recent industrial wastewater. An ion-exchange method is used to carry out the modification process, from zeolite byproduct to Mg-zeolite, and simultaneously absorb the Pb in the heavy-metal solution (99.032 mg/L). It is found that the sodium zeolite in the raw material residue can be modified to magnesium zeolite by reacting it with a mixture solution at 1 M concentration for 24 h. As a result, it is found that the residual Pb (0.130 mg/L) in the heavy metal solution is shown to be absorbed by 99.86%, with successful formation of a Mg-modified zeolite.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.670-676
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• 2016

Hydrogen town in Republic of Korea was established in 2013. Hydrogen as a byproduct produced by various processes of factories is used in hydrogen town facilities. As cell performance is affected by contaminations in fuel gas, various standards about impurities of fuel have been determined by many countries. This study shows performance degradation of single cell with impurities concentrations. Traces of carbon monoxide (CO) and hydrogen sulfide ($H_2S$)can cause considerable cell performance losses. For comparing the performances by poisoning of CO, acceleration test, I-V curve, constant current are performed. Both the CO and $H_2S$ poisoning rate are a function of their concentration. With the higher concentrations the higher poisoning rates are observed. And, it was confirmed that, oxidation behavior and side reaction generation are not affected. Under the lower $H_2S$ concentration condition, the poisoning rate is much higher than that of CO because of its different adsorption intensity. It can be possible that the result of this study can be used for enacting regulation as a baseline data.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.3
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• pp.169-176
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• 2023

This study aims to develop a thermally conductive backfill by applying the prepacked concrete concept, in which a coarse aggregate with relatively high thermal conductivity was first filled and then the voild filled with grout. Backfill with improved thermal conductivity can increase the heat exchange efficiency of underground heat exchangers or underground transmission facilities. The backfills was prepared by using crushed concrete as the coarse aggregate, fly ash-based grout, and a small amount of cement for solidification. The results of this study showed that the fly ash-cement-sand-based grout with a flow of at least 450 mm accor ding to ASTM D 6103 could fill the void of pr epactked coar se aggr egates with a maximum size of 25 mm. The thermal conductivity of the backfil with coarse aggregate was over 1.7 W/m·K, which was higher than that of grout-type backfills.

• Food Science of Animal Resources
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• v.20 no.2
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• pp.159-165
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• 2000

Glycomacropeptide(GMP) was purified from cheese whey which is obtaining as a byproduct in cheese producing. Cheese whey was first concentrated 10 times with a ultrafiltration aparratus, and then heated at 95$^{\circ}C$ for 5 min. The concentrated fraction was centrifuged at 20,000$\times$g for 30 min to remove fat layer. The supernatant layer enriched GMP protein was fractionated by ion exchange chromatography on DEAE-Sepharose Fast Flow column. GMP was bound to DEAE resin and eluted with 0.1~0.25 M NaCl when using a linear NaCl gradient from 0 M to 0.5 M. The purified GMP gave a single band of 24 kDa which seems to be trimer molecular weight in SDS-PAGE, and migrated to the same molecular weight with control GMP obtained commercially. Its amino acid composition were consistent with that of standard GMP. About 0.71 g of GMP was recovered from 1 L of cheese whey. These results indicate that glycomacropeptide could be simply purified from cheese whey by using ultrafiltration and DEAE column chromatography.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.27 no.6C
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• pp.544-561
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• 2002

In this paper, we propose a new hybrid type of the routing protocol (Virtual Cluster-based Routing Protocol: VCRP) for mobile ad-hoc networks, based on a virtual cluster, which is defined as a narrow-sense network to exchange the basic information related to the routing among the adjacent nodes. This particular approach combines advantage of proactive routing protocol (PRP), which immediately provides the route collecting the network-wide topological and metric information, with that of reactive routing protocol, which relies on the route query packet to collect the route information on its way to the destination without exchanging any information between nodes. Furthermore, it also provides the back-up route as a byproduct, along with the optimal route, which leads to the VCBRP (Virtual Cluster-based Routing Protocol with Backup Route) establishing the alternative route immediately after a network topology is changed due to degradation of link quality and terminal mobility, Our simulation studies have shown that the proposed routing protocols are robust against dynamics of network topology while improving the performances of packet transfer delay, link failure ratio, and throughput over those of the existing routing protocols without much compromising the control overhead efficiency.

• Journal of Soil and Groundwater Environment
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• v.19 no.4
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• pp.62-69
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• 2014

In the results of monitoring nitrate concentration in more than 8,000 groundwater wells around agro-livestock, the average and maximum nitrate concentration was 9.4 mg/L and 101.2 mg/L, respectively. Since about 31% of the monitoring wells was exceed the quality standard for drinking water, nitrate control such as remediation or source regulation is required to conserve safe-groundwater in South Korea. Typical nitrate-treatment technologies include ion exchange, reverse osmosis, and biological denitrification. Among the treatment methods, biological denitrification by indigenous microorganism has environmental and economic advantages for the complete elimination of nitrate because of lower operating costs compared to other methods. Major mechanism of the process is microbial reduction of nitrate to nitrite and nitrogen gas. Three functional genes (nosZ, nirK, nirS) that encode for the enzyme involved in the pathway. In this work, we tried to develop simple process to determine possibility of natural denitrification reaction by monitoring the functional gene. For the work, the functional genes in nitrate-contaminated groundwater were monitored by using PCR with specific target primers. In the result, functional genes (nosZ and nirK) encoding denitrification enzymes were detected in the groundwater samples. This method can help to determine the possibility of natural-nitrate degradation in target groundwater wells without multiplex experimental process. In addition, for field-remediation application we selected nitrate-contaminated site where 200~600 mg/L of nitrate is continuously detected. To determine the possibility of nitrate-degradation by stimulated-natural attenuation, groundwater was sampled in two different wells of the site and nitrate concentration of the samples was 300 mg/L and 616 mg/L, respectively. Fumarate for different C/N ratio was added into microcosm bottles containing the groundwater to examine denitrification rate depending on carbon concentration. In the result, once 1.5 times more than amount of fumarate stoichiometry required was added, the 616 mg/L of nitrate and 300 mg/L of nitrate were completely degraded in 8 days and 30 days. The nitrite, byproduct of denitrification process, was also completely degraded during the experimental period.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.4
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• pp.11-19
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• 2018

This study was conducted to develop the manufacturing method of biochar using pruned stems of pear tree and its application effect on the crop growth and soil physico-chemical properties. In this study, biochar derived from pruned stems of pear tree at heating temperature of $300^{\circ}C$, $500^{\circ}C$ and $700^{\circ}C$ in heating times of 2, 3 and 4 hours, were tested in the changes of their chemical properties during biochar processing. The pH, Exch. K, Exch. Mg and cation exchange capacity (CEC) increased as the pyrolysis temperature increased during the production of biochar, and the change of these properties rapidly occurred at $500^{\circ}C$. However, as the pyrolysis temperature increased, ash content increased and total carbon (T-C), yield decreased. And the change of the properties in response to the heating time was not shown. It was thought that it would be desirable to set the production conditions of biochar at $500^{\circ}C$ for 2 hours in consideration of the change of chemical properties and the ash content and yield. And also, were conducted the experiments to establish manufacturing method of farm-made biochar using drum biochar manufacturing machine and investigate the application effects of biochar on the cultivation of chinese cabbage and tomato. Application of biochar derived from pruned stems of pear tree could enhance pH, organic matter (OM), total carbon (T-C) of soil. On the other hand, soil electrical conductivity (EC), NO3-N were lowered compared to the control which has no application. The bulk density, porosity and aggregate formation of soil were improved by biochar application. The fresh matter yields of chinese cabbage and tomato were significantly increased in proportion to the application rate of biochar. This study demonstrated the effect of the biochar derived from agricultural byproduct to be as a low cost potential soil ameliorant by physico-chemical properties in eco-friendly greenhouse cultivation.