통합 검색 | Korea Science

설수덕
- Korean Chemical Engineering Research
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- 제48권5호
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- pp.556-560
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- 2010
부타디엔 고무 소재의 접착력을 향상시키기 위하여 대기압 표면개질방식을 적용시켰다. 평판형 플라즈마반응기의 최적의 반응조건을 구하기 위하여 반응기체(질소, 아르곤, 산소, 공기), 기체유량(30~100 mL/min), 플라즈마 처리시간(0~30초) 및 선처리제의 개질방법(GMA, 2-HEMA)을 변화시켜 실험하였다. 처리 전후의 소재의 표면변화는 SEM과 ATR-FTIR로 측정하였다. 기체의 유량과 처리시간이 증가함에 따라 접촉각이 감소하였고, 반응 기체는 공기로 유량 60 mL/min, 처리시간 5초 및 2-HEMA 첨가 선처리제를 사용하였을 때 최대의 접착박리강도를 나타내었다. 결과적으로 대기압식 평판형 플라즈마 처리방식으로 고무소재 표면의 젖음성과 접착박리강도가 개선되었음을 확인하였다.
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이진헌
- 한국산업보건학회지
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- 제20권1호
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- pp.70-78
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- 2010
The purpose of this study is to investigate the appropriate metabolite as biomarker for the biomonitoring of 1,3-butadiene(BD) inhalation exposure. We measured the hemoglobin adducts which were extracted from the blood of the ICR mice inhalation exposure with 100ppm and 500ppm 1,3-butadiene for 2 weeks(5 hr/day ${\times}$ 5 days/week). Hemoglobin adducts were the (N-2-hydroxy-3 -butenyl) valine (HB Val) and (N-2,3,4-trihydroxy-butyl)valine (THB Val). Body weights of the exposure groups were significantly lower from 11 exposure post-day in 100ppm BD inhalation mice and from 7 exposure post-day in 500ppm BD inhalation mice than in control. The levels of HB Val are 0.8~1.7pmol/mg globin for 100ppm BD inhalation exposure, and 2.1~4.4 pmol/mg globin for 500ppm BD inhalation exposure. The levels of THB Val are 15.0~22.0 pmol/mg globin in 100ppm BD inhalation exposure, and 34.8~45.7 pmol/mg globin for 500ppm BD inhalation exposure. So the levels of THB Val and HB Val are proportional relationship with BD exposure level. THB Val is 12.9~18.8 times higher level that HB Val in 100ppm BD exposure group and 10.4~16.6 times higher level than HB Val in 500ppm BD exposure group. We concluded that THB Val is an appropriate metabolite as biomarker for the biomonitoring for BD inhalation exposure.
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