• Title/Summary/Keyword: Butadiene

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A Study on the Emission Changes in Reduction Chemical Substances in Korea (유해화학물질 배출량 변화에 관한 연구: 배출저감계획서 작성 대상물질 중심으로)

  • Im, JiYoung;Lee, MyeongJi;Kim, HyunJi;Ryu, JiSung;Yun, DaeSik;Jang, YongChul;Lee, ChungSoo
    • Journal of Environmental Health Sciences
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    • v.46 no.2
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    • pp.159-169
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    • 2020
  • Objectives: The purpose of this study was to investigate changes among the nine kinds of reduction chemical substances in Korea over the period of 2008-2017. We will define basic data for improving the management methods for reducing chemical substances. Methods: A survey of hazardous pollutant emissions for 2008-2017 was conducted through the pollutant Release and Transfer Register homepage. Nine kinds of designated reduction chemical substances (Benzene, Vinyl chloride, Trichloro ethylene, 1,3-butadiene, Dichloro methane, Tetrachloro ethylene, N,N-dimethylformamide, Acrylo nitrile, and Chloroform) provided the study subjects. The emission of hazardous chemicals and health effects used the National Health Statistics and Integrated Chemicals Information System (ICIS) as a reference. Results: Hazardous pollutant emissions increased by 1.2 times over the past decade, and nine types of reduction chemical substances increased by 1.6 times. By region, the emissions of reduction chemical substances over the last 10 years were in the order of Chungbuk, Gyeonggi, and Gyeongbuk. Emissions of Dichloro methane was the highest in Chungbuk and Gyeongbuk. N,N-dimethylformamide was the highest in Gyeonggi. Carcinogen pollutant emissions showed a tendency to increase continuously. In addition, group 1 carcinogen emissions showed a tendency to decrease. Conclusion: In the last decade, the amount of hazardous chemical emissions has been continuously increasing. Hazardous chemical emissions require facility improvement for continuous emissions reduction. More research on reduction of emissions is needed.

Durability of Polymers for Cement Modifier in Autoclave Cure (오토클래이브양생에 의한 시멘트 혼화용 폴리머의 내구성)

  • Joo, Myung-Ki;Lee, Youn-Su
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.888-893
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    • 2003
  • The purpose of this study is to make clear the durability of the polymer films formed in the autoclaved polymer-modified mortars and concretes. The polymer films prepared with polymer dispersions such as a styrene-butadiene rubber (SBR) latex, a poly (ethylene-vinyl acetate)(EVA) emulsion and a polyacrylic ester (PAE) emulsion for polymeric admixtures are exposed to autoclaving at 18$0^{\circ}C$ in temperature and 1.01 MPa in vapor pressure, and subjected to tensile test and infrared spectroscopy. The durability of the polymer films is evaluated from the application of autoclaving to the polymer films under saturated Ca(OH)$_2$ solution immersion causes no degradation for SBR films and a significant degradation due to the saponification of the polymers for EVA and PAE films. Accordingly, in the application of autoclaving to polymer-modified mortars and concretes, it is suggested that SBR-modified mortars and concretes are hardly degraded but EVA- and PAE-modified mortars and concretes are markedly degraded by the saponification of the polymers.

Effects of Thickness, Elastomer Types and Thinner Content on Actuation Performance of Electro Active Dielectric Elastomers (탄성체의 두께, 종류 및 희석제 함유량이 전기활성 유전탄성체의 구동 성능에 미치는 영향)

  • Li, Bin;Lin, Zheng-Jie;Ryu, Sang-Ryeoul;Lee, Dong-Joo
    • Composites Research
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    • v.27 no.1
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    • pp.25-30
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    • 2014
  • The actuation performance of an EADE (Electro-active dielectric elastomer) is studied as functions of thinner content, thickness and types of the dielectric elastomer such as natural (NR), acrylonitrile-butadiene (NBR), and silicon (KE-12) rubbers. With a decrease in elastomer thickness ($1{\rightarrow}0.5{\rightarrow}0.25{\rightarrow}0.1{\rightarrow}0.05$ mm) and an increase in thinner content ($0{\rightarrow}30{\rightarrow}50$ phr), the actuating displacement of KE-12 elastomer is increased, however their breakdown occurs at low voltage. For the same thickness (1 mm), the displacement of KE-12 elastomer shows a higher value (2.24 mm) compared to that of NR or NBR at the same applied voltage of 25 kV. The KE-12 has the lowest elastic modulus and the NBR has the highest one among the tested elastomers. However, the displacement of NBR elastomer is higher compared to that of NR because of high dielectric constant. It is found that the important factors of EADE actuator are a thickness, modulus and dielectric constant of the elastomer.

Design and Analysis of Aluminum Melting Machine in Fused Deposition Modeling Method (압출 적층 방식의 알루미늄 용융기의 설계 및 해석)

  • Lee, Hyun-Seok;Na, Yeong-Min;Kang, Tae-Hun;Park, Jong-Kyu;Park, Tae-Gone
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.14 no.4
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    • pp.62-72
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    • 2015
  • Interest in three-dimensional (3D) printing processes has grown significantly, and several types have been developed. These 3D printing processes are classified as Selective Laser Sintering (SLS), Stereo-Lithography Apparatus (SLA), and Fused Deposition Modeling (FDM). SLS can be applied to many materials, but because it uses a laser-based material removal process, it is expensive. SLA enables fast and precise manufacturing, but available materials are limited. FDM printing's benefits are its reasonable price and easy accessibility. However, metal printing using FDM can involve technical problems, such as suitable component supply or the thermal expansion of the heating part. Thus, FDM printing primarily uses materials with low melting points, such as acrylonitrile butadiene styrene (ABS) or polylactic acid (PLA) resin. In this study, an FDM process for enabling metal printing is suggested. Particularly, the nozzle and heatsink for this process are focused for stable printing. To design the nozzle and heatsink, multi-physical phenomena, including thermal expansion and heat transfer, had to be considered. Therefore, COMSOL Multiphysics, an FEM analysis program, was used to analyze the maximum temperature, thermal expansion, and principal stress. Finally, its performance was confirmed through an experiment.

Performance Evaluation of RAP and WMA Mixtures Located in MN/Road Test Cells through Air Voids Analyses (MN/Road 시험포장 구간내의 공기량 측정 및 결과값 분석을 통한 RAP 및 저온 아스팔트(WMA) 혼합물의 특성 평가)

  • Moon, Ki Hoon;Falchetto, Augusto Cannone;Jeong, Jin Hoon
    • International Journal of Highway Engineering
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    • v.16 no.4
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    • pp.63-74
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    • 2014
  • PURPOSES: This research is to evaluate the mechanical performance of different types of Hot Mix Asphalt (HMA) pavement cells prepared for MN/Road field testing section through an extensive experimental analysis of air voids and simple statistical evaluation tools (i.e. hypothesis test). METHODS: An extensive experimental work was performed to measure air voids in 82 asphalt mixture cores (238 samples in total) obtained from nine different types of road cell located in MN/Road testing field. In order to numerically and quantitatively address the differences in air voids among the different test Cells built in MN/Road, a simple statistical test method (i.e. t-test) with 5% significance was used. RESULTS: Similar trends in air voids content were found among the mixtures including conventional HMA, Reclaimed Asphalt Pavement (RAP) and Warm Mix Asphalt (WMA) combined with taconite aggregate this provides support to the use of RAP and WMA technology in the constructions of asphalt pavement. However, in case of acid modified HMA mixtures, significant differences in air void content were observed between on the wheel path and between wheel path location, which implies negative performances in rutting and thermal cracking resistances. Conclusions : It can be concluded that use of RAP and WMA technology in the construction of conventional asphalt pavement and the use of PPA (Poly Phosphoric Acid) in combinations with SBS (Styrene Butadiene Styrene) in asphalt binder production provide satisfactory performance and, therefore, are highly recommended.

Effect of Mixing Ratio of Amphoteric and Anionic Latices on Print Quality of Coated Papers (라텍스의 혼합비율이 도공지 품질에 미치는 영향)

  • 강태근;박규재;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.72-79
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    • 1999
  • The binder plays important roles in determining the quality of pigment coating. In addition to its primary role of binding the pigment to the base paper, the binder performs several other important functions. The binder, also referred to as the adhesive, is the dominant in the aqueous phase of the formulation. Thus it plays a major role in determining viscosity, rheology, water release, and setting time for the coating. Latices based on styrene-butadiene dominate the market for synthetic paper coating binders. Consumption is high and is expected to increase further due to the present tendeyncy toward high-solids coating. The purpose of this study is understanding the impact of various parameters of latex(i.e. Tg, Particle size) affecting prontabilities and optical properties of the coated papers, as well as providing basic information on the use of amphoteric latex for improving print qualities of coated papers. Recently, amphoteric latices, Which are cationic at low pH's but turn anionic at high pH's have attracted interests of paper scientists and engineers. Therefore we investigated the effect of the Tg(glass transition temperature) and particle size of amphoteric latex on the coating qualities. We also studied the effect of mixing ratios (Amphoteric / Anionic)of latex on the coating qualities. Our results showed that Tg and particle size of amphoteric latex have to be controlled for optimizing coated paper qualities. The formulation consisting of 10 parts of amphoteric latex and 5 parts of anionic latex gave best results in ink receptivity, smoothness, air permeability, opacity and sheet gloss. If the results hold for the industrial paper coatings, the amount of expensive amphoteric latex can be reduced while achieving best available printing quality.

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Monitoring Study on Exposure Levels of Environmental Pollutants in Residents of a Non-Industrial Area, Korea (비산단지역 환경오염 수준 및 주민의 생체지표 모니터링)

  • Kim, Dae-Seon;Ahn, Seung Chul;Ryu, Jung Min;Yu, Seung Do
    • Journal of Environmental Health Sciences
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    • v.38 no.6
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    • pp.482-492
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    • 2012
  • Objectives: The main purpose of this study is to produce background data which can be compared with data on vulnerable areas such as industrial complexes in Ulsan, SihwaBanwol, Gwangyang, Yeosu, Pohang, Cheongju and Daesan in Korea. Methods: This study was performed on 1,007 local residents in Gangneung using personal questionnaires and medical check-up. Environmental pollutants including heavy metals in blood and urine were analyzed and the results are as follows. Results: According to the results of medical check-up, 705 subjects were "Normal (A and B)", 232 subjects were "Disease doubtful (R1)" and 70 subjects were "High blood pressure or Diabetes doubtful (R2)". Regarding geometric mean concentration, blood lead was 1.57 ${\mu}g/dL$, urine cadmium was 0.82 ${\mu}g/g-cr$, urine mercury was 0.98 ${\mu}g/g-cr$ and urine arsenic was 15.78 ${\mu}g/g-cr$. In the analysis of 11 kinds of VOCs in blood, vinyl chloride, 1,3-butadiene and dichloroethylene were not detected, while the detection rate of other chemicals was above 70% except chloroform(49.7%) and trichloroethylene(19.0%). In analysis of 16 kinds of PAHs in blood, 10 kinds showed more than 80% in detection rate. Also, detection rate of 4 kinds of PCBs in blood ranged 52 to 78%. Conclusions: Compared with industrial compelxes, the concentration of blood lead was lower, while urine cadmium and mercury levels were similar. Also, urine arsenic ranged at a significant level. Further study is required to find the cause of regional differences in concentrations of environmental pollutants.

A Study on Emission Characteristics of VOCs During Cold Start Test Mode for Motorcycles (냉간모드에서의 이륜자동차 VOCs 배출특성연구)

  • Lee, Jongtae;Yoo, Heung-Min;Son, JiHwan;Yun, Changwan;Mun, SunHee;Park, Gyu-Tae;Kim, JeongSoo
    • Journal of ILASS-Korea
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    • v.20 no.1
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    • pp.28-34
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    • 2015
  • Recently, some researchers have been carried out risk assessment of vehicles exhaust on human health. Especially, some of VOCs which is non-controlled, was classified to hazardous pollutant, such as 1,3-Butadiene and BTEX(Benzene, Toluene, Ethylbenzene and Xylene). Therefore, the profile on non-controlled pollutant may be needed in the future, because it would be critical data or information to control them. Additionally, with increasing amount of motorcycle, the source profiling is essential for estimating emission factor and amount on motorcycle exhaust. For these, in this study, imported motorcycles (8 vehicles) were selected as a test model while considering the increasing ratio on sales volume between 2013 and 2014; it was also compared with domestic motorcycles on those. The experiment was conducted by driving mode, UDC and ECE+EUDC that made from EURO III. In addition, it was performed at cold start driving mode without effect by displacement, for evaluating only correlation of BTEX with HC. In order to apply the ratio (m,p-Xylene/o-Xylene) as a marker, the ratio was compared with those of tunnel, road side and residential area. As a result, it showed best correlation ($R^2=0.98$) among those. In the future, it has to be considered as a marker for effect evaluation to atmospheric environment by exhaust emission.

Study of The Relation between Smoke Component and Sensory Evaluation of Cigarettes with the Different Leaf Blending (엽배합 특성에 따른 담배 연기성분과 관능특성과의 상관관계 구명)

  • 황건중;이문수;나도영
    • Journal of the Korean Society of Tobacco Science
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    • v.25 no.2
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    • pp.144-153
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    • 2003
  • This study was carried out to determine the relationship between smoke components and sensory evaluation by changes tobacco leaf blending. Seven different cigarettes were made by adding different types of oriental, reconstituted and expanded tobacco leaves. 62 kinds of smoke components which were 6 of general components, 34 of semi-volatile and volatile components, 9 of acid components, and 13 of phenolic components were analyzed. Eight kinds of sensory item were evaluated and also electronic nose system data was collected. All smoke components and sensory characteristics of mainstream smoke were changed by the different blending. To determine the relationship between smoke components and sensory test, the correlation and regression analysis were carried out by using SPSS statistical program. Tar, pH, and CO showed a high correlation with sensory evaluation item. As tar related to hotness, CO have a high correlation with offensive aroma. Semi-volatile and volatile components of smoke related to sensory characteristics such as aroma, taste, irritation, hotness and smoothness. When propylene, l,3-butadiene, butane, isoprene, and 2-methylfuran showed a high correlation with aroma; methyl chloride, methanol, toluene, ethyl benzene showed a high correlation with irritation. Some acidic components and phenolic components of smoke also had a high relation to smoke volume. Especially the acidic components such as 2-furoic acid, 2-hydroxybutyric acid, phenylacetic acid and palmitic acid; the phenolic components such as 4-vinyl phenol, pyrocatechol, 3-methyl catechol, hydroquinone showed a high correlation with smoke volume. As using regression analysis, it was possible to estimate the results of sensory evaluation from the smoke analysis data. From the results of electronic nose system analysis, we can find the different pattern by adding expanded tobacco leaf.

Development of nonwoven fabric and new adhesive system to manufacture hybrid corrugated board (농산물용 복합 골판지 제조를 위한 부직포 및 신규 접착시스템에 대한 연구)

  • Lee, Ji-Young;Yoon, Hee-Youl;Oh, Seok-Ju;Sung, Yong-Joo;Kim, Byeong-Ho;Lim, Gi-Baek;Choi, Jae-Sung;Kim, Sun-Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.3
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    • pp.49-55
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    • 2012
  • Even though corrugated boards are the most common packaging materials for agricultural products, conventional corrugated boards are not able to maintain the freshness of agricultural products. In order to overcome the limitations of conventional corrugated boards, a new hybrid corrugated board-composed of linerboard, a corrugating medium, and non-woven fabric-was designed to possess antibacterial, high porous and shock-absorbing properties. In this study, we compared the physical properties of non-woven fabric to those of the base papers of conventional corrugated boards and developed a new adhesive system as a first step toward manufacturing the hybrid corrugated board. We found that the non-woven fabric, which had relatively high elongation, was applicable in the corrugated board process, and that the manufacturing conditions must be controlled in order to prevent the break of the non-woven fabric. The mixture of starch and styrene-butadiene (SB) latex showed high adhesive strength, but the addition level of SB latex should not exceed 30% in starch solution.