• Title/Summary/Keyword: Butadiene

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Development of Single-Channel Thread Sensor for Rotary Bobbin by Optical Sensing (광센서를 이용한 로터리 보빈용 단채널 밑실 감지기 개발에 관한 연구)

  • Jung, Yong-Sub;Cho, Janghyun;Byeon, Clare Chisu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.10
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    • pp.1085-1091
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    • 2014
  • We developed a single-channel thread sensor for a rotary bobbin by optical sensing and analyzed the signal characteristics. A specially designed mount made of ABS (acrylonitrile-butadiene-styrene) resin that encapsulated an optical sensor was fabricated by using a 3D printer and was attached to the rotary bobbin system. Stable control on a weaving machine was achieved by observing the difference in the output signals of an optical sensor system, which vary significantly according to the states of the thread in the weaving operation. The optical sensor effectively detects an unintentional thread cut and run-out during weaving fast enough to enable prompt stopping of the weaving machine, thereby minimizing the loss of expensive fabrics.

Effect of Polyurethane on Fracture Toughness in CTBN/PU/Epoxy (CTBN/PU/Epoxy의 파괴인성에서 폴리우레탄의 영향)

  • Kim, Jong Seok;Hong, Suk Pyo
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.172-176
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    • 1998
  • Epoxy adduct carboxyl terminated butadiene acrylonitrile(CTBN) was prepared by blending of CTBN and epoxy resin. CTBN/PU/epoxy was prepared from polyurethane(PU), epoxy resin, and CTBN. The CTBN/PU/epoxy using 5 wt% of CTBN content showed shifting damping peak as PU content increased. It suggested that CTBN/PU/epoxy had good compatibility for all composition at 5 wt% of CTBN content. But miscibility of CTBN/PU/epoxy decreased with the increase of the CTBN content. PU content for maximum flexural properties of CTBN/PU/epoxy was 10 wt%, but decreased with the increase of the PU content. The fracture toughness of CTBN/epoxy was improved by addition of the PU. Fracture surfaces of CTBN/PU/epoxy showed the shear deformation and generation of stress whitening which is associated with the cavitation. Cavitation in the CTBN and shear defomation in the PU modified epoxy matrix are the toughening mechanisms for CTBN/PU/epoxy.

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Effects of Compatibilizer on Mechanical, Morphological, and Rheological Properties of Polypropylene/Poly(acrylonitrile-butadiene-styrene) Blends

  • Kum, Chong-K.;Sung, Yu-Taek;Kim, Yong-Su;Lee, Hyung-Gon;Kim, Woo-Nyon;Lee, Heon-Sang;Yoon, Ho-Gyu
    • Macromolecular Research
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    • v.15 no.4
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    • pp.308-314
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    • 2007
  • The effects of a compatibilizer on polypropylene (PP)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were studied. Blends of the PP/ABS, with PP-g-SAN copolymer as a compatibilizer, were prepared using a twin screw extruder. The flexural and impact strength of the PP/ABS blends with the PP-g-SAN copolymer increased significantly with PP-rich compositions on the addition of the PP-g-SAN copolymer at 3 phr. The increase in the mechanical properties of the PP/ABS/PP-g-SAN blend may have been due to the toughening effects of the ABS in the PP-rich compositions. In the morphology study of the PP/ABS/PP-g-SAN (80/20) blend with the PP-g-SAN copolymer, the minimum droplet size, $5.1{\mu}m$, was observed with the addition on phr of the PP-g-SAN copolymer. The complex viscosity of the PP/ABS/PP-g-SAN (80/20) blends increased with the addition of3 phr of the PP-g-SAN copolymer. From the above mechanical properties, morphology and complex viscosity results for the PP/ABS blends, it is suggested that the compatibility is more increased with the PP-rich composition (PP:ABS=80/20 wt%) of the PP/ABS blend on the addition of 3 phr of the PP-g-SAN copolymer.

Morphological, Mechanical and Rheological Properties of Poly(acrylonitrile-butadiene-styrene)/Polycarbonate/Poly$({\varepsilon}-caprolactone)$ Ternary Blends

  • Hong, John-Hee;Song, Ki-Heon;Lee, Hyung-Gon;Han, Mi-Sun;Kim, Youn-Hee;Kim, Woo-Nyon
    • Macromolecular Research
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    • v.15 no.6
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    • pp.520-526
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    • 2007
  • The effects of poly($({\varepsilon}$-caprolactone) (PCL) on poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate (PC) blends were studied. Blends of ABS/PC (70/30, wt%) with PCL as a compatibilizer were prepared by a twin screw extruder. From the glass transition temperature $(T_g)$ results of the ABS/PC blends with PCL, the $T_g$(PC) of the ABS/PC (70/30) blends decreased with increasing PCL content. From the results of the morphology of the ABS/PC (70/30) blends with PCL, the phase separation between the ABS and PC phases became less significant after adding PCL in the ABS/PC blends. In addition, the morphological studies of the ABS/PC blends etched by NaOH indicated that the shape of the droplet was changed from regular round to irregular round by adding PCL in the ABS/PC blends. These results for the mechanical properties of the ABS/PC blends with PCL indicated that the tensile, flexural and impact strengths of the ABS/PC (70/30) blends peaked at a PCL content of 0.5 phr. From the results for the rheological properties of the ABS/PC (70/30) blends with PCL content, the storage modulus, loss modulus and complex viscosity increased at PCL content up to 5 phr. From the above results of the $T_g$, mechanical properties, morphology and complex viscosity of the ABS/PC blends with PCL, it was concluded that the compatibility was increased with PCL addition in the ABS/PC (70/30, wt%) blends and that the optimum concentration of PCL as a compatibilizer is 0.5 phr.

Improvement of Frictional Property of BR/CIIR Composite Rubber for Shoes Outsole (운동화 겉창용 BR/CIIR 고무 복합체의 마찰특성 향상에 대한 연구)

  • Pyo, Kyungduk;Choi, Jungsu;Lee, Jongnyun;Park, Chacheol
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.255-261
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    • 2013
  • This paper introduced a new preparation method of a composite rubber by mixing BR (butadiene rubber) and CIIR (chloro-isobutyl rubber) for the purpose of improving frictional property of BR. Since BR has high abrasion and low frictional properties, its frictional property needs to be enhanced in order to be used as an outsole of a sport shoe. Such enhancement was difficult to achieve by simple blending of CIIR. In here, CIIR was added into BR matrix after CIIR was pre-crosslinked for a time period, and both high frictional and high abrasion resistance properties were achieved. Our experiments showed that the composite rubber blend of 60% of BR and 40% of pre-crosslinked CIIR had desired BR's frictional and abrasion resistance properties for sport shoes.

3D Printing Design for Minimizing Flection Phenomenon (3D 프린팅 휘어짐 현상 최소화를 위한 설계)

  • Choi, Seong-Ook;Hwang, Suk-Seung
    • The Journal of the Korea institute of electronic communication sciences
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    • v.9 no.12
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    • pp.1415-1420
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    • 2014
  • 3D printer is based on an additive manufacturing technology, which helps in creating the three-dimensional object using a 3D drawing. It is used in various fields, because it prints out a variety of three-dimensional products in a short period of time. In this paper, we consider a technique using the FDM(Fused Deposition Modeling) method by dissolving the ABS(Acrylonitrile Butadiene Styrene) resin among a diversity of printing technique and materials. This kind of the 3D printer prints out a product in high temperature and cools down it. In this process, a flection phenomenon is occurred according to the size of the printing product and the surrounding environment. Conventional methods for mitigating this phenomenon maintain the temperature at the optimum level, but they require using additional devices. In order to minimize the flection phenomenon in 3D printing products without additional devices, in this paper, we propose a noble technique, which creates holes on suitable positions when they are designed by 3D drawing tools. Also, we suggest mathematical model for the proposed method, and measure and analyse a printing output using a proposed technique.

Enhancement in the physical properties of inorganic pigment layer in the color block by incorporation of n liquid additive (액상첨가제에 의한 칼라로도 블록 무기 안료층의 특성 향상)

  • Lee, D.M.;Park, D.W.;Lee, J.H.;Kim, S.M.;Kim, D.Y.;Kim, J.J.;Kim, J.K.;Cho, H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.5
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    • pp.222-226
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    • 2006
  • Effects of a carboxylated styrene-butadiene-based liquid additive on the microstructure, mechanical strength and decolorization resistance of inorganic pigment layer in the color block have been examined. More dense inorganic pigment layer characterized by lower apparent porosity, lower water absorption and uniform pigment distribution has been achieved by incorporation of a liquid additive. Also significant enhancements in the mechanical strength and decolorization resistance have been observed.

Extraction Property of Plasticizer in LPG High Pressure Rubber Hose (LPG용 고압고무호스에서 가소제 추출특성)

  • Kim, Young-Gu
    • Journal of the Korean Chemical Society
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    • v.48 no.2
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    • pp.156-160
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    • 2004
  • The extraction rates of plasticizer of LPG high pressure rubber are studied. Submerging solvents are composed of propane, n-butane, n-pentane, n-hexane, n-heptane, propylene, 1,3-butadiene, 1-pentene, 1-hexene, ethanethiol, t-butanethiol, dimethyl sulfide, methyl ethyl sulfide. The relationship between the extraction rate of plasticizer and the descriptors of submerging solvent by using multiple linear regression is as follows; PE(wt%) = 7.5193 - 0.58500Carbon${\sharp}$ + 2.3294DB + 2364SH, (N = 13, F = 24.135, R$^2$ = 0.8894, R$_{adj}^2$ = 0.8526, Variance = 7.588) Plasticizer is well extracted by LPG composed of the high vapour pressure and polarity compounds. The mass of extracted plasticizer becomes increasing in proportion to the contents of thiol sulfur compound and unsaturated hydrocarbon such as propylene and 1,3-butadiene in LPG. While the heavier hydrocarbons are, the less the quantities of plasticizer extracted from rubber are.

Preparation of Properties of PC/PBT Alloy Using MBS Compatibility (MBS상용화제를 사용한 PC/PET Alloy의 제조와 그 물성)

  • Lee, Yong-Moo;Kang, Doo-Whan
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.54-62
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    • 1994
  • Bisphenol A polycarbonate(PC) and polyethylene terephthalate(PET) was blended with methylmethacrylate-butadiene-styrene(MBS) copolymer for the improvement of impact resistance strength PC/PET alloy blending with PC more than 15 parts to 100 parts of PET usually have poor compatability, but increased the compatability characteristics of PC/PET alloy prepared by addition of MBS compatabilizer. The compatability of PC and PET using compatabilizer, MBS was determined by measuring the thermal characteristics of Tg difference between PC and PET, and crystallization temperature, Tcc. As the Tg difference becoming narrow to $60^{\circ}C$, and Tcc decreasing to $150^{\circ}C$, the comparability of PC and PET was increased. And also tough rate impact strength to PC/PET alloy using MBS was increased, in case more than 15 parts of PC being blended to PET.

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Evaluation of Nuclear Medicine Applications of 3D Printing Phantom - Gamma Camera Centrically (3D 프린팅 팬텀의 핵의학분야 적용 평가 - 감마카메라 중심으로)

  • Park, Hoon-Hee;Lee, Juyoung;Kim, Ji-Hyeon
    • The Korean Journal of Nuclear Medicine Technology
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    • v.21 no.2
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    • pp.65-73
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    • 2017
  • Purpose 3D 프린팅 기술은 3D 스캔이나 모델링을 통하여 적측가공 방식으로 제작하는 기공기술로서 금형 없이 직접 생산이 가능하고 빠른 시간 내에 제작이 가능하여 최근 다양한 산업분야에서 본격적으로 적용되고 있다. 3D 프린팅 기술은 의료분야에 있어, 영상의학 및 방사선 치료분야에서 다양하게 활용되고 있지만 핵의학 분야에서는 관련 연구가 미비한 실정이다. 그러므로 본 연구는 기존에 적용되고 있는 핵의학분야 팬텀과 3D 프린팅 기술로 제작된 텀의 특성을 비교하고 적용 가능성을 평가하는데 목적을 두었다. Materials and Methods 방사선 투과도 변화측정 국제기준 팬텀인 알루미늄(Aluminum) 계단 쐐기(step wedge)를 기준($140mm{\times}62mm{\times}35mm$)으로 PMMA(Poly Methyl Meta Acrylate)와 ABS(Acrylonitrile Butadiene Styrene)재질로 각각 동일한 크기의 팬텀을 제작하였다. PMMA 팬텀은 핵의학 분야에서 주로 적용되는 팬텀의 성분과 동일한 소재로 제작하였고, ABS 팬텀 제작은 3D 프린팅 기술의 액체 기반형의 SLA(Stereo Lithography Apparatus)기법을 사용하여 제작하였다. 본 연구는 SPECT/CT장비 BrightView XCT(Philips Health Care, Cleveland, USA)를 이용하였다. 영상 획득은 Rectangular Flood phantom(Biodex, New York, USA) $^{99m}TcO_4$ 3, 6 mCi와 $^{57}Co$ lood phantom(adqual, New Hampshire, USA) $^{57}Co$ 20 mCi를 이용하여 Aluminum, PMMA, ABS 팬텀에 대해 60 min 리스트모드(List mode)로 획득하였다. 획득한 영상의 분석을 위해 관심영역(ROI)을 설정하여 각 팬텀의 단계별로 평가하였다. Results 방사선원의 종류 및 방사선량에 따라 ABS 팬텀의 계수치는 PMMA 팬텀의 계수치와 유사한 값을 나타내며, 두께의 증가에 따라 선형적으로 감소하였다. Aluminum, PMMA, ABS 팬텀의 선감약계수를 비교했을 때, Aluminum 팬텀의 선감약계수는 나머지 두 팬텀보다 수치가 높았고, PMMA, ABS 팬텀에서는 근사치의 선감약계수가 나타났다. Conclusion 3D 프린팅 기술로 제작된 ABS 팬텀을 기준으로 PMMA 팬텀은 두께가 증가함에 따른 계수치의 변화가 유사하게 선형적으로 감소하였고, 선감약계수도 근사치로 나타내었다. ABS 팬텀의 핵의학적 적용 가능성을 확인할 수 있었으며, 추후 연구를 통해 세부적인 교정치(correction value)를 적용한다면 활발한 적용이 가능하리라 사료된다.

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