• Elastomers and Composites
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• v.36 no.2
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• pp.111-120
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• 2001

Mechanical properties and their adhesion behavior with zinc- and brass-plated steel cords of natural rubber/acrylonitrile-butadiene blend compounds were investigated as a function of blend ratio. The Mooney viscosity and stress relaxation time were found to be lowered with increasing NBR content. Tensile modulus generally increased with increasing NBR content. Tensile stress at break stayed constant up to about 40 phr and showed minimum at $50{\sim}60 phr$, and thereafter increased with increasing NBR content. Strain at break decreased linearly below 50 phr, and above the level it showed nearly constant value. Based on the abrupt drops in elastic modulus and tan ${\delta}$ peak, the glass transition temperature of NR and NBR were found to be -55 and $-10^{\circ}C$, respectively. In the case of NR/NBR blend compounds, two distinct transition points were observed and each transition position was not affected by NBR level indicating an incompatible nature of NR/NBR blend system. The pullout force and rubber coverage decreased to the level of about 40% to that of pure m compound, when the 50 phr of NR was replaced by NBR. However, the pure NBR compound showed the comparable adhesion performance with NR(${\sim}90%$). The sulfur concentration was found to become lower with the increased NBR content at the adhesion interface based on the Auger spectrometer results, representing a lack of adhesion layer formation, and this was explained for a possible cause of low adhesion performance with adding NBR.

• Proceedings of the Korean Environmental Health Society Conference
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• 2004.12a
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• pp.72-72
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• 2004

• Proceedings of the Korean Vacuum Society Conference
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• 2003.02a
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• pp.186-186
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• 2003

• Bulletin of the Korean Chemical Society
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• v.24 no.1
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• pp.13-14
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• 2003

• Proceedings of the Materials Research Society of Korea Conference
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• 2005.05a
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• pp.59-59
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• 2005

• Bulletin of the Korean Chemical Society
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• v.15 no.2
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• pp.103-104
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• 1994

• Bulletin of the Korean Chemical Society
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• v.10 no.1
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• pp.114-116
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• 1989

• Journal of the Korean Chemical Society
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• v.34 no.5
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• pp.430-437
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• 1990

Various tris (${\eta}^4$-diene) molybdenums were easily synthesized by the reaction of various 1,3-dienes and molybdenum metal vapors by using metal atom reactor. The methyl substituent effect of the tris (${\eta}^4$-diene) molybdenum produced were discussed. And some alkadiene-molybdenum complexes which were easily decomposed in the air at room temperature were also formed.(C$_6$H$_{10}$)$_2$(CO)$_3$Mo were synthesized and its molybdenum-diene bond type were discussed.

• International Journal of Highway Engineering
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• v.10 no.2
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• pp.205-219
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• 2008

The polymers, low-density polyethylene (LDPE) and styrene-butadiene-styrene(SBS) -modified asphalt mixtures are advanced asphalt pavement materials in which $3{\sim}6%$ of them, and/or some other additive, by weight of total binder are added. The purpose of modifying asphalt material is to improve typical weakness such as rutting and cracking resistance of normal asphalt mixtures. These materials have been proved to show many advantages and practical applicability in the plant and field. Wet processed PMA binder and/or dry processed asphalt mixtures are developed as field products for many years. The objective of this paper is to show the characteristics of the LDPE and SBS-modified asphalt mixtures by comprehensive evaluation and comparison with those of normal asphalt mixtures.

• Applied Chemistry for Engineering
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• v.5 no.5
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• pp.786-794
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• 1994

The strength and durability of polymer-cement mortars were investigated. The specimens of polymer-cement mortar were prepared by using styrene-butadiene rubber(SBR) latex, ethylene-vinyl acetate(EVA) emulsion and polyacrylic ester(PAE) emulsion with various polymer-cement ratios(5, 10, 15, 20wt%). For the evaluation of durability of polymer-cement mortars, freezing-thawing, acid resistance and heat resistance tests were conducted. With an increase of polymer-cement ratio, the frost resistance of polymer-cement mortars was greatly improved, but acid and heat resistance were deteriorated. The compressive and flexural strengths of SBR polymer-cement mortars were improved with an increase of polymer-cement ratio, whereas those of EVA and PAE polymer-cement mortars reached maximum value at polymer-cement ratio of 10wt%.