• Title/Summary/Keyword: Bulk samples

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Application of Exchange Equations for NH4-K NH4-Ca Equilibria (NH4-K 와 NH4-Ca 평형에 대한 양이온 치환식의 적용)

  • Chung, Jong-Bae;Sa, Tong-Min
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.3
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    • pp.218-226
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    • 1995
  • Ion exchange equilibria in bulk and rhizosphere soil collected from peach seedlings were studied to find exchange equations that could be used in chromatographic models dealing with movement and distribution of fertilizer ammonium and exchangeable cations in soil profiles. Soil samples were equilibrated with mixtures of $NH_4Cl$, KCI, and $CaCl_2$ solutions and then extracted with $Sr(NO_3)_2$ solution to determine exchangeable cation compositions at equilibrium. Exchange data were fitted to Vanselow's, Gapon's, and Kerr's equations, but those formulations did not adequately describe the equilibria. An empirical equation of the form : ${\frac{\alpha_i^m}{a_j^n}}=K{\frac{(iX)^{mPi}}{(jX)^{nPj}}}$ which has an exponent on each of the exchangeable cation concentrations could describe the equilibria very well over the range of treatments. In this equation ${\alpha}^i$ and ${\alpha}^j$ are activities of cation i and j with valences m and n respectively. (iX) and (jX) are concentrations of exchangeable cations. Mole or equivalent fractions can be considered as the exchangeable ion concentration unit. Arbitrary constants $P_i$ and $P_j$, and distribution coefficient K can be found with multiple regression for the logarithmic form of the equation.

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Quality Characteristics and Antioxidant Activities of Cookies Added with Pleurotus eryngii Powder (새송이버섯 분말을 첨가한 쿠키의 품질 및 항산화활성)

  • Kim, Ye-Ji;Jung, In-Kyung;Kwak, Eun-Jung
    • Korean Journal of Food Science and Technology
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    • v.42 no.2
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    • pp.183-189
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    • 2010
  • This study examined the quality characteristics and antioxidant activities of cookies added Pleurotus eryngii powder. There were no significant differences in bulk density or water content between the doughs. Spread factors and leavening rates of cookies decreased with increasing Pleurotus eryngii powder content. However, the loss rates of cookies showed no significant differences. L values decreased with increasing Pleurotus eryngii powder content while a values were gradually increased. b values showed no significant differences among the samples. Hardness, total phenol compound content, ferric reducing antioxidant power (FRAP) and DPPH radical scavenging activity of cookies were significantly increased with increasing Pleurotus eryngii powder content. In a descriptive test, the color, flavor, palatability, hardness and graininess were all increased with increasing Pleurotus eryngii powder content. In a preference test, color and flavor were the highest in the 10% group without significant differences. Texture was preferred in the control-20% groups without significant differences. However, taste and overall acceptability were the highest in the 10% group.

Frequency Dependency of Electrical Property Stabilization during Vulcanization of Modified NR/IR Blends (개질된 NR/IR 블랜드의 가황 반응에서 나타나는 전기적 특성 안정화의 주파수 의존성)

  • Ahn, Won-Sool
    • Elastomers and Composites
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    • v.39 no.3
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    • pp.179-185
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    • 2004
  • Frequency dependency or electrical property stabilization during vulcanization of modified NR/IR composite materials was studied using in-situ electrical property measuring technique. Volume resistivity(p) before and after vulcanization reaction of the sample was measured as the function or frequency in the range or 1Hz to 10kHz at reaction temperatures of 130, 140, 150, and $160^{\circ}C$, respectively. A double stabilization mode of frequency dependency was observed, in which a slow stabilization process of p to a value of ca. $1.0{\times}10^7\;{\Omega}-cm$ occurred after a drastic initial decrease from ca. $9.0{\times}10^7\;{\Omega}-cm$. In addition, notable temperature dependencies of p values were also observed before and after vulcanization reaction, that is, p values at 130 and $140^{\circ}C$ after vulcanization were observed as about 1/3 of those values before vulcanization. All the observed facts were considered as the results from the interaction between the electrode and the bulk sample materials, i.e., electronic charge-discharge, and from the structure change of samples including CB rearrangement by the vulcanization.

Effect of boron milling on phase formation and critical current density of MgB2 bulk superconductors

  • Kang, M.O.;Joo, J.;Jun, B.H.;Park, S.D.;Kim, C.S.;Kim, C.J.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.1
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    • pp.18-24
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    • 2019
  • This study was carried out to investigate the effect of milling of boron (B), which is one of raw materials of $MgB_2$, on the critical current density ($J_c$) of $MgB_2$. B powder used in this study is semi-amorphous B (Pavezyum, Turkey, 97% purity, 1 micron). The size of B powder was reduced by planetary milling using $ZrO_2$ balls (a diameter of 2 mm). The B powder and balls with a ratio of 1:20 were charged in a ceramic jar and then the jar was filled with toluene. The milling time was varied from 0 to 8 h. The milled B powders were mixed with Mg powder in the composition of (Mg+2B), and the powder mixtures were uniaxially pressed at 3 tons. The powder compacts were heat-treated at $700^{\circ}C$ for 1 h in flowing argon gas. Powder X-ray diffraction and FWHM (Full width at half maximum) were used to analyze the phase formation and crystallinity of $MgB_2$. The superconducting transition temperature ($T_c$) and $J_c$ of $MgB_2$ were measured using a magnetic property measurement system (MPMS). It was found that $B_2O_3$ was formed by B milling and the subsequent drying process, and the volume fraction of $B_2O_3$ increased as milling time increased. The $T_c$ of $MgB_2$ decreased with increasing milling time, which was explained in terms of the decreased volume fraction of $MgB_2$, the line broadening of $MgB_2$ peaks and the formation of $B_2O_3$. The $J_c$ at 5 K increased with increasing milling time. The $J_c$ increase is more remarkable at the magnetic field higher than 3 T. The $J_c$ at 5 K and 4 T was the highest as $4.37{\times}10^4A/cm^2$ when milling time was 2 h. The $J_c$ at 20 K also increased with increasing milling time. However, The $J_c$ of the samples with the prolonged milling for 6 and 8 h were lower than that of the non-milled sample.

Assessment of Resistance Spot Weldability of Dissimilar Joints of Austenitic Stainless Steels/IF Steels and Ferritic Stainless Steels/IF Steels (페라이트계 및 오스테나이트계 스테인리스강과 IF강의 이종 접합부의 저항 점 용접성 평가)

  • Lee, Jin-Beom;Kim, Dong-Cheol;Nam, Dae-Geun;Kang, Nam Hyun;Kim, Soon-Kook;Yu, Ji-Hun;Rhym, YoungMok;Park, Yeong-Do
    • Korean Journal of Metals and Materials
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    • v.49 no.1
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    • pp.64-72
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    • 2011
  • The spot weldability of dissimilar metal joints between austenitic stainless steels (STS316)/IF steels and ferritic stainless steels (STS430)/IF steels was investigated. This study was aimed to determine the spot welding parameters for a dissimilar metal joint and to evaluate the dissimilar metal joint's weldability, including its welding nugget shape, tensile-shear strength, hardness, and microstructure. The comparison of these results was described in terms of fracture behavior. Compared with the weld lobe of similar metal joints, dissimilar metal joints (STS430/IF) had reduced weld current range. However, the weld lobe of STS316/IF steel joint showed increased weld current range. This is because the dilution of chemical composition in the molten weld pool suppressed the heat input being caused by Joule heat with current flow through the samples. The microstructure of the fusion zone was fully martensite and mixture of ferrite and martensite for austenitic stainless steel/IF steel and ferritic stainless steel/IF steel combination, respectively. The experimental results showed that the shape of nugget was asymmetric, in which the fusion zone of the austenitic and ferritic stainless steel sheet was larger due to the higher bulk-resistance. The predicted microstructure by using the Schaeffler diagram was well matched with experimental results. After peel test, the fracture was initiated from heat affected zone of ferritic stainless steel sheet side, however the final fracture was propagated into the IF steel sheet side due to its lower strength.

Quality Characteristics of Firm Tofu Made from Various Soybeans (콩 원료에 따른 일반 두부의 품질 비교)

  • Sim, Eun-Yeong;Lee, Yu Young;Park, Hye-Young;Choi, Hye-Sun;Kwak, Jieun;Kim, Mijung;Kim, Hong-Sik;Kim, Jin-Sook
    • The Korean Journal of Food And Nutrition
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    • v.33 no.6
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    • pp.710-720
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    • 2020
  • This study was conducted to compare the quality characteristics of firm tofu (coagulant calcium chloride, CaCl2 used) made from eight imported and four domestic soybeans selling in Korean markets. The 100-seed weight of soybeans imported from China and Seonpung cultivated in Korea was the highest at 33.23 g and 32.51 g, respectively. Soybeans imported from the USA (bulk type) showed the lowest at 16.12 g, followed by Ukraine at 16.94 g, and Brazil at 18.51 g. The range of protein and fat in the 12 soybeans was 37.08~41.36% and 18.35~22.17%, respectively. The isoflavone contents were the highest in Daepung2 cultivated in Korea at 3,764.10 ㎍/g and the lowest in soybeans imported from Brazil at 1,439.85 ㎍/g. Tofu yield among the samples was in the following order: Seonpung (235.2%), China (232.0%) Daepung2 (228.7%), Daechan (225.7%), and Brazil (208%). Tofu made with soybeans cultivated in Korea (including from China) showed a higher yield compared to that made from soybeans from seven other countries. In the analysis of the correlation of quality factors of tofu, the hardness of the tofu was correlated with 100-seed weight (r=0.676⁎) and protein content of the soybeans (r=0.837⁎⁎). Tofu yield was correlated with 100-seed weight (r=0.748⁎⁎) and protein content of the soybeans (r=0.583⁎).

Risk Assessment of Smoke Generated During Combustion for Some Wood (일부 목재의 연소 시 발생되는 연기의 위험성 평가)

  • Chung, Yeong-Jin;Jin, Eui
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.373-380
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    • 2022
  • In this study, Chung's equations 1, 2, and 3 were extended to standardize smoke safety rating evaluation in case of fire, and Chung's equations-V, smoke performance index-V, and smoke growth index-V were calculated. Five types of wood were selected and their smoke indices were measured using the cone calorimeter method according to ISO 5660-1. The smoke risk was graded by the smoke risk index-VI according to Chung's equation-VI. Smoke risk index-VI increased in the order of PMMA (1) ≈ maple (1.01) < ash (1.57) < needle fir (4.98) < paulownia (46.15) < western red cedar (106.26). It was predicted that maple and ash had the lowest smoke risk, and paulownia and western red cedar had the highest. The five samples' CO mean production rate (COPmean) was 0.0009~0.0024 g/s, indicating that these woods were incompletely burned than the polymethyl methacrylate (PMMA) reference material. Regarding the smoke properties of the chosen woods, the smoke performance index-V (SPI-V) increased as the bulk density increased, and the smoke risk index-VI (SRI-VI) decreased.

Nature of the Interfacial Regions in the Antiferromagnetically-coupled Fe/Si Multilayered Films

  • Moon, J.C.;Y.V. Kudryavtsev;J.Y.Rhee;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.174-174
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    • 2000
  • A strong antiferromagnetic coupling in Fe/Si multilayered films (MLF) had been recently discovered and much consideration has been given to whether the coupling in the Fe/Si MLF system has the same origin as the metal/metal MLF. Nevertheless, the nature of the interfacial ron silicide is still controversial. On one hand, a metal/ semiconductor structure was suggested with a narrow band-gap semiconducting $\varepsilon$-FeSi spacer that mediates the coupling. However, some features show that the nature of coupling can be well understood in terms of the conventional metal/metal multilayered system. It is well known that both magneto-optical (MO) and optical properties of a metal depend strongly on their electronic structure that is also correlated with the atomic and chemical ordering. In this study, the nature of the interfacial regions is the Fe/Si multilayers has been investigated by the experimental and computer-simulated MO and optical spectroscopies. The Fe/Si MLF were prepared by rf-sputtering onto glass substrates at room temperature with the number of repetition N=50. The thickness of Fe sublayer was fixed at 3.0nm while the Si sublayer thickness was varied from 1.0 to 2.0 nm. The topmost layer of all the Fe/Si MLF is Fe. In order to carry out the computer simulations, the information on the MO and optical parameters of the materials that may constitute a real multilayered structure should be known in advance. For this purpose, we also prepared Fe, Si, FeSi2 and FeSi samples. The structural characterization of Fe/Si MLF was performed by low- and high -angle x-ray diffraction with a Cu-K$\alpha$ radiation and by transmission electron microscopy. A bulk $\varepsilon$-FeSi was also investigated. The MO and optical properties were measured at room temperature in the 1.0-4.7 eV energy range. The theoretical simulations of MO and optical properties for the Fe/Si MLF were performed by solving exactly a multireflection problem using the scattering matrix approach assuming various stoichiometries of a nonmagnetic spacer separating the antiferromagnetically coupled Fe layers. The simulated spectra of a model structure of FeSi2 or $\varepsilon$-FeSi as the spacer turned out to fail in explaining the experimental spectra of the Fe/Si MLF in both intensity and shape. Thus, the decisive disagreement between experimental and simulated MO and optical properties ruled out the hypothesis of FeSi2 and $\varepsilon$-FeSi as the nonmagnetic spacer. By supposing the spontaneous formation of a metallic ζ-FeSi, a reasonable agreement between experimental and simulated MO and optical spectra was obtained.

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Relationship between Grain Size and Organic Carbon Content of Surface Sediments in the Major Estuarine Areas of Korea (국내 주요 하구역 표층퇴적물의 입도와 유기탄소 함량 관계)

  • BOO-KEUN KHIM;JU-YEON YANG;HYUK CHOI;KWANGKYU PARK;KYUNG HOON SHIN
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.28 no.4
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    • pp.158-177
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    • 2023
  • An estuary is a transitional water area that links the land and sea through rivers and streams, transporting various components from the land to the sea, which plays an important role in determining primary productivity in the coastal environment, and this coastal ecosystem captures a huge amount of carbon into biomass, known as blue carbon, which mitigates climate change as a potential carbon reservoir. This study examined the variation of mean grain size and organic carbon content of the surface sediments for 6 years and analyzed their relationship in the western and southern estuarine areas (Han River Estuary, Geum River Estuary, Yeongsan River Estuary, Seomjin River Estuary, and Nakdong River Estuary) and the East Sea upwelling area. During the sampling period (2015 to 2020), seasonal variation of both properties was not observed, because their variations might be controlled by diverse oceanographic environments and hydrographic conditions within each survey area. However, despite the synoptic problem of all samples, the positive relationship was obtained between the averages of mean grain size and organic carbon content, which clearly distinguishes each survey area. The unique positive relationship in all estuarine areas implies that the same process by sediment clay particles is important in the organic carbon accumulation. However, additional important factor may be expected in the organic carbon accumulation in the East Sea upwelling area. Further necessary data (sedimentation rate, dry bulk density etc) should be required for the estimation of carbon stock to evaluate the major estuaries in Korea as potential carbon reservoirs in the coastal environment.

Geotechnical Properties of Pelagic Red Clay in Northeast Equatorial Pacific (북동태평양 원양성 적점토의 지질공학적 특성에 관한 연구)

  • Chi, Sang-Bum;Lee, Hyun-Bok;Hyeong, Ki-Seong;Ju, Se-Jong;Lee, Gun-Chang;Ham, Dong-Jin
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.3
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    • pp.286-294
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    • 2008
  • In order to understand the physical properties of deep-sea sediments, which mainly consist of pelagic red clays, sediment samples were collected at 24 stations using a multiple corer in the Clarion-Clipperton fracture zone of the northeast equatorial Pacific. The sampled sediment cores were examined for the mass physical properties(i.e. grain size distribution, mean grain size, water content, specific grain density, wet bulk density, void ratio, and porosity) and the geotechnical properties(i.e. shear strength and consistency limits) with the content of biogenic opal and mineral composition. Although KR1 and KR2 areas on the same latitude are logitudinally far from each other, the mass physical properties of these areas are not distinctly different except for shear strengths. The maximum shear strength of surface sediments in KR2 area is higher than that in KR1 due to the appearance of a consolidated lower layer(Unit 3) in the sediment core from KR2.