• Title/Summary/Keyword: Bulk concentration

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Synthesis and characterization of $Y_2O_3$:Eu nano phosphor powder by a new technique

  • Kwak, Min-Gi;Hong, Sung-Jei;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1367-1369
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    • 2006
  • In this paper, a new technique has been adopted for synthesis of nanophosphor particles of $Y_2O_3:Eu$ at low temperature. The optical properties of the prepared nanophosphor particles have been measured and the results have been compared with the properties of its bulk phosphor particles. The particle sizes of $Y_2O_3:Eu$ nanophosphor powder with doped-Eu concentration of 10wt% synthesized by our procedure is about 40nm. When the concentration of Eu was 10wt%, intensity of PL appeared the highest and 95% efficient as compared with bulk phosphor.

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Filmwise Condensation of Freon Vapor Including Air on a Horizontal Tube (공기를 함유한 프레온 증기의 수평관 외부에서의 막응축)

  • Kim, K.H.;Ko, H.J.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.1
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    • pp.20-29
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    • 1995
  • A theoretical model for film condensation of a vapor including a relatively lighter noncondensable gas on a horizontal tube has been formulated on the basis of the conservation laws and other fundamental physical principles. The model is applied to the prediction of the condensation heat transfer characteristics for the Freon vapor in the presence of air on a horizontal tube. Calculated results for the mean heat transfer coefficient, which is shown to depend strongly on the bulk concentration of air, are in good agreement with the available experimental results for a range of operating conditions. The distributions of physical quantities along the surface of tube are also calculated, such as the boundary layer thickness and local heat transfer coefficient. The present model is readily reduced to the Nusselt model as the bulk concentration of air decreases to zero. Therefore, the transition from the condensation of pure vapor to that of vapor-air mixture occurs continuously not abruptly.

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Analytical Study on the Reinforced Details of Orthotropic Steel Deck Bridge (강바닥판 교량의 보강상세에 관한 해석적 연구)

  • Kyung, Kab-Soo;Shin, Dong-Ho;Kim, Kyo-Hoon;Park, Kyung-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.20 no.4
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    • pp.443-451
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    • 2007
  • The improvement of stiffness by the increase of thickness of deck plate or the reinforcement of longitudinal rib is one method among the effective methods to control fatigue damages occurring in orthotropic steel deck. It is likely that the increase of stiffness is effective to restrain local deformation caused by axial load in the steel deck. Therefore, in this study, the parameter studies for the reinforced structural details such as the bulk-head plate and vertical rib which is established to reduce the resultant stresses in the connection parts of the longitudinal rib and floor beam were performed with FE analysis. From the results, it was known that the reinforced structural detail with the bulk-head plate in the longitudinal ribs reduced overall the principal stresses at the connection parts, but the stress concentration increased in the weld toe parts which are occurring fatigue cracks. Also, it was estimated that the reinforced structural detail with the vortical rib in the longitudinal ribs because of the reduction of stress concentration in the weld toe parts is more effective details than the bulk-head plate.

Activated Physical Properties at Air-Polymer Interface

  • Kajiyama, Tisato;Tanaka, Keiji
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.5-6
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    • 2006
  • Molecular motion at the surface of monodisperse polystyrene (PS) films with various chain end groups was studied by scanning probe microscopy. Surface glass transition temperature ($T_{g^s}$) of the PS films was much lower than the corresponding bulk value. And, the magnitude of $T_{g^s}$ was strongly dependent on chain end chemistry. This result can be explained in terms of the chain end concentration at the surface. Time-temperature superposition principle was applied to rheological analysis at the surface. The apparent activation energy of the surface ${\alpha}_{a}$-relaxation process was approximately a half of that for the bulk sample. This result clearly indicates that the cooperativity for the surface segmental motion was reduced in comparison with that in the bulk region.

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Properties of Silicon for Photoluminescence

  • Baek, Dohyun
    • Applied Science and Convergence Technology
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    • v.23 no.3
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    • pp.113-127
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    • 2014
  • For more than five decades, silicon has dominated the semiconductor industry that supports memory devices, ICs, photovoltaic devices, etc. Photoluminescence (PL) is an attractive silicon characterization technique because it is contactless and provides information on bulk impurities, defects, surface states, optical properties, and doping concentration. It can provide high resolution spectra, generally with the sample at low temperature and room-temperature spectra. The photoluminescence properties of silicon at low temperature are reviewed and discussed in this study. In this paper, silicon bulk PL spectra are shown in multiple peak positions at low temperature. They correspond with various impurities such as In, Al, and Be, phonon interactions, for example, acoustical phonons and optical phonons, different exciton binding energies for boron and phosphorus, dislocation related PL emission peak lines, and oxygen related thermal donor PL emissions.

Effects of Alkaline Treatment on the Characteristics of Chemical Pulps for Papermaking (알칼리 처리가 제지용 화학펄프의 특성에 미치는 영향)

  • Won, Jong-Myoung;Kim, Min-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.106-112
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    • 2011
  • The effects of alkaline treatment on the WRV, crystalline structure and sheet structure of softwood and hardwood bleached kraft pulp were investigated. Sodium hydroxide and sodium carbonate were used as chemicals for alkaline treatment and two levels of alkali dosage (5%, 10%) were applied respectively. Alkali treated and untreated pulp were refined to three levels (550, 450 and 350 mL CSF). WRV of the alkali treated pulps depended on the alkaline type and concentration. It was found that the crystalline structures of softwood and hardwood pulp were not changed by refining. Sodium carbonate and lower concentration of sodium hydroxide treatment did not caused any modification of cellulose crystalline structure, while higher concentration of sodium hydroxide treatment caused the partial modification of cellulose crystalline structure. Alkaline treatment of hardwood bleached kraft pulp led to the shrinkage of fiber diameter and bulky structure of sheet. Alkaline treatment of softwood bleached kraft pulp did not cause the significant change in fiber shrinkage and bulk of sheet.

The Optimum Condition of Anisotropic Bulk(10) Si Etching with KOH for High Selectivity and Low Surface Roughness

  • Lim, Hyung-Teak;Kim, Yong-Kweon;Lee, Seung-Ki
    • Journal of Electrical Engineering and information Science
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    • v.2 no.5
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    • pp.108-113
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    • 1997
  • In this paper, the optimum condition of (110) Si etching with the potassium hydroxide(KOH) etchant is presented. Although several researches on (110) Si anisotropic etching have been studied, there has been lack of effects of mask quality and etching conditions on the selectivity and the roughness o the etched surface. Three kinds of masks (film, emulsion and E-beam mask) were used in order to verify the effect of etching properties. Anisotropic bulk etching depends on the crystalline orientation and the concentration and temperature of the etchant. In order to investigate the effect of etching conditions on selectivity and the roughness of the etched surface, the concentration of the etchant was varied from 35 to 45 per cent in weight with increments by 5 per cent and the temperature was changed from 70 to 90$^{\circ}C$ with increments by 10$^{\circ}C$. The combination of the temperature of 70$^{\circ}C$ and the concentration of 40wt.% was found to be the optimum etching condition for high selectivity. Etched surfaces show minimum surfaces show minimum surface roughness at a temperature of 80$^{\circ}C$ and a concentation of 40wt.%. Comb structures with various comb widths were fabricated and the lengths of the combs wree measured with several etching time durations. A micro comb structure 525$\mu\textrm{m}$ high was fabricated for MEMS application.

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Boundary layer measurements for validating CFD condensation model and analysis based on heat and mass transfer analogy in laminar flow condition

  • Shu Soma;Masahiro Ishigaki;Satoshi Abe;Yasuteru Sibamoto
    • Nuclear Engineering and Technology
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    • v.56 no.7
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    • pp.2524-2533
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    • 2024
  • When analyzing containment thermal-hydraulics, computational fluid dynamics (CFD) is a powerful tool because multi-dimensional and local analysis is required for some accident scenarios. According to the previous study, neglecting steam bulk condensation in the CFD analysis leads to a significant error in boundary layer profiles. Validating the condensation model requires the experimental data near the condensing surface, however, available boundary layer data is quite limited. It is also important to confirm whether the heat and mass transfer analogy (HMTA) is still valid in the presence of bulk condensation. In this study, the boundary layer measurements on the vertical condensing surface in the presence of air were performed with the rectangular channel facility WINCS, which was designed to measure the velocity, temperature, and concentration boundary layers. We set the laminar flow condition and varied the Richardson number (1.0-23) and the steam volume fraction (0.35-0.57). The experimental results were used to validate CFD analysis and HMTA models. For the former, we implemented a bulk condensation model assuming local thermal equilibrium into the CFD code and confirmed its validity. For the latter, we validated the HMTA-based correlations, confirming that the mixed convection correlation reasonably predicted the sum of wall and bulk condensation rates.

The Effects of high Energy(1.5MeV) B+ ion Implantation and Initial Oxygen Concentration Upon Deep Level in CZ Silicon Wafer (고 에너지 (1.5 MeV) Boron 이온 주입과 초기 산소농도 조건이 깊은 준위에 미치는 영향에 관한 연구)

  • Song, Yeong-Min;Mun, Yeong-Hui;Kim, Jong-O
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.55-60
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    • 2001
  • The effect of high energy B ion implantation and initial oxygen concentration upon defect formation and gettering of metallic impurities in Czochralski silicon wafer has been studied by applying DLTS( Deep Level Transient Spectroscopy), SIMS(Secondary ton Mass Spectroscopy), BMD (Bulk Micro-Defect) analysis and TEM(Transmission Electron Microscopy). DLTS results show the signal of the deep levels not only in as-implanted samples but also in low and high temperature annealed samples. Vacancy-related deep levels in as- implanted samples were changed to metallic impurities-related deep levels with increase of annealing temperature. In the case of high temperature anneal, by showing the lower deep level concentration with increase of initial oxygen concentration, high initial oxygen concentration seems to be more effective compared with the lower initial oxygen one.

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Effect of High-Energy Ball Milling on Thermoelectric Transport Properties in CoSb3 Skutterudite (고에너지 볼 밀링이 Skutterudite계 CoSb3의 열전 및 전하 전송 특성에 미치는 영향)

  • Nam, Woo Hyun;Meang, Eun-Ji;Lim, Young Soo;Lee, Soonil;Seo, Won-Seon;Lee, Jeong Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.852-856
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    • 2015
  • In this study, we investigate the effect of high-energy ball milling on thermoelectric transport properties in double-filled $CoSb_3$ skutterudite ($In_{0.2}Yb_{0.1}Co_4Sb_{12}$). $In_{0.2}Yb_{0.1}Co_4Sb_{12}$ powders are milled using high-energy ball milling for different periods of time (0, 5, 10, and 20 min), and the milled powders are consolidated into bulk samples by spark plasma sintering. Microstructure analysis shows that the high-energy ball milled bulk samples are composed of nano- and micro-grains. Because the filling fractions are reduced in the bulk samples due to the kinetic energy of the high-energy ball milling, the carrier concentration of the bulk samples decreases with the ball milling time. Furthermore, the mobility of the bulk samples also decreases with the ball milling time due to enhanced grain boundary scattering of electrons. Reduction of electrical conductivity by ball milling has a decisive effect on thermoelectric transport in the bulk samples, power factor decreases with the ball milling time.