• 제목/요약/키워드: Buffer material

검색결과 542건 처리시간 0.026초

Variation of the Si-induced Gap State by the N defect at the Si/SiO2 Interface

  • 김규형;정석민
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.128.1-128.1
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    • 2016
  • Nitrided-metal gates on the high-${\kappa}$ dielectric material are widely studied because of their use for sub-20nm semiconductor devices and the academic interest for the evanescent states at the Si/insulator interface. Issues in these systems with the Si substrate are the electron mobility degradation and the reliability problems caused from N defects that permeates between the Si and the $SiO_2$ buffer layer interface from the nitrided-gate during the gate deposition process. Previous studies proposed the N defect structures with the gap states at the Si band gap region. However, recent experimental data shows the possibility of the most stable structure without any N defect state between the bulk Si valence band maximum (VBM) and conduction band minimum (CBM). In this talk, we present a new type of the N defect structure and the electronic structure of the proposed structure by using the first-principles calculation. We find that the pair structure of N atoms at the $Si/SiO_2$ interface has the lowest energy among the structures considered. In the electronic structure, the N pair changes the eigenvalue of the silicon-induced gap state (SIGS) that is spatially localized at the interface and energetically located just above the bulk VBM. With increase of the number of N defects, the SIGS gradually disappears in the bulk Si gap region, as a result, the system gap is increased by the N defect. We find that the SIGS shift with the N defect mainly originates from the change of the kinetic energy part of the eigenstate by the reduction of the SIGS modulation for the incorporated N defect.

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고준위 폐기물 처분용기 주변에서의 지하수의 방사분해에 의한 음 전류 밀도 유도 (Derivation of the Cathodic Current Density around the HLW Canister Due to the Radiolysis of Groundwater)

  • 최희주;조동건;최종원;한필수
    • Journal of Radiation Protection and Research
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    • 제31권2호
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    • pp.105-113
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    • 2006
  • 사용후핵연료의 처분을 위해 사용되는 캐니스터 주변 완충재의 공극 내 지하수는 방사분해에 의해 산화제를 발생한다. 캐니스터 주변의 탄소강의 부식을 결정하는 산화제에 의해 야기된 음 전류 밀도를 계산하기 위하여 수학적 모델을 이용하였다. 실린더 좌표계에서 음 전류 밀도를 구할 수 있는 해석해를 유도하였다. 직교 좌표계와 실린더 좌표계에서 구한 음 전류 밀도를 서로 비교하였다. 방사분해 계산을 위한 선원항 및 흡수선량률은 ORIGEN2와 MCNP 컴퓨터 코드를 이용하여 계산하였다. 새로운 모델을 이용하여 부식을 억제할 수 있는 처분용기 반경을 결정하였다. 계산 결과 실린더 좌표계에서의 해를 이용할 경우 기존의 Marsh 모델보다 음 전류 밀도 값을 25 % 감소시켰다.

Synthesis and Characterization of Hollow Silicon-Carbon Composites as a Lithium Battery Anode Material

  • Han, Won-Kyu;Ko, Yong-Nam;Yoon, Chong-Seung;Choa, Yong-Ho;Oh, Sung-Tag;Kang, Sung-Goon
    • 한국재료학회지
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    • 제19권10호
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    • pp.517-521
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    • 2009
  • Si-C composite with hollow spherical structure was synthesized using ultrasonic treatment of organosilica powder formed by hydrolysis of phenyltrimethoxysilane. The prepared powder was pyrolyzed at various temperatures ranging from 900 to 1300 $^{\circ}C$ under nitrogen atmosphere to obtain optimum conditions for Li-ion battery anode materials with high capacity and cyclability. The XRD and elemental analysis results show that the pyrolyzed Si/C composite at 1100 $^{\circ}C$ has low oxygen and nitrogen levels, which is desirable for increasing the electrochemical capacity and reducing the irreversible capacity of the first discharge. The solid Si-C composite electrode shows a first charge capacity of $\sim$500 mAhg$^{-1}$ and a capacity fade within 30 cycles of 0.93% per cycle. On the other hand, the electrochemical performance of the hollow Si-C composite electrode exhibits a reversible charge capacity of $\sim$540 mAhg$^{-1}$ with an excellent capacity retention of capacity loss 0.43% per cycle up to 30 cycles. The improved electrochemical properties are attributed to facile diffusion of Li ions into the hollow shell with nanoscale thickness. In addition, the empty core space provides a buffer zone to relieve the mechanical stresses incurred during Li insertion.

공간성, 호소유형 및 형태복잡도 지수를 이용한 토지이용과 호소수질의 관계 연구 (Investigation on the Relationship between Land Use and Water Quality with Spatial Dimension, Reservoir Type and Shape Complexity)

  • 이상우;황순진
    • 한국조경학회지
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    • 제34권6호
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    • pp.1-9
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    • 2007
  • Land use types within a watershed closely are related with the water quality characteristics of receiving water bodies. Despite of a numerous studies suggesting a strong relationship between water quality and land use, there have been increasing concerns about the geographical variation and a lack of spatial integration in that relationship, which are essential to implementing these findings into land use planning and management. In the meantime, edges mediate the material flux between adjacent systems. This mediating effect of edges is strongly related to the complexity of their shapes. Land use activities within a watershed have a direct impact on the water quality of adjacent aquatic systems, and hydrological processes carry residuals from watershed into adjacent aquatic ecosystems through the edges. Therefore, the geometry of reservoirs theoretically affects the relationship between land uses in the watershed and the quality of receiving bodies of water. In this light, this study integrates the geo-spatial dimensions of land uses in the watershed using GIS and landscape indices in order to explore the relationship between land uses and water quality. Water quality characteristics, land uses and geometry of 133 randomly sampled reservoirs were correlated, based on buffer zones and types of reservoirs. The findings showed that land uses, particularly urban land uses, significantly affect water quality characteristics including BOD, COD, TN and TP, and geometry of reservoirs reduces the concentration of pollutant and nutrients in reservoirs. One of results indicates that the relationship between land use and water quality and effects of spatial dimension may vary with types of reservoirs and pollutants. These results suggest that lakeshore areas are important, particularly for TN reduction and call for a caution to land use activities nearby shoreline areas for sustaining better water quality.

도시 단독주택 정원의 공간적 특징과 유지.관리에서 보이는 거주자의 정원 인식에 관한 연구 (Research on the Characteristics of Garden Design and Dwellers' Understanding of Garden Maintenance in Single Detached Urban Dwellings)

  • 조동범;김수란;김근호
    • 한국조경학회지
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    • 제34권6호
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    • pp.54-65
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    • 2007
  • There is little research on the exterior spaces or gardens of single detached urban dwellings in Korea because apartments are the general housing type of most inhabitants. However there is an increasing demand for idyllic houses in the urban fringe and for environmentally friendly dwellings or healthy houses that is represented in urban residents gardening activities. The purpose of this research is to analyze residents' preferences and problems in gardening and management of single detached urban dwellings, and to evaluate the possibility of gardens as biotopes. It also addresses the issue of providing public amenities in the urban landscape. One hundred thirty-six dwellings were selected in residential areas of the city of Gwangju. The layout and plant composition, residents' evaluation and understanding of their own gardens, and maintenance and management were investigated. The results indicated that residents associate gardening with mental health and recognized a lack of space as one environmental restriction. Watering was seen as a primary difficulty for maintaining gardens. This research suggests that providing space for gardening could be a tool for participatory community making. When considering the important aspects of gardening, residents responded that gardens offer naturalness, scenic beauty, and practicality and also felt that gardens provide a buffer from environmental pollution and relief from mental duress. Results from the factor analysis using 15 semantic differential variables showed that 'spatial openness', 'natural variety' and 'familiarity' were representative factors. Although a garden is mainly considered as a space for the appreciation of nature with plant material, our results suggest that meaning and environmental symbolism are important elements.

Keloid와 Hypertrophic Scar ( 비후성반흔 )의 형태학적 관찰 (Electron Microscopic Studies of Human Keloid and Hypertrophic Scars)

  • 김정숙;유재덕
    • Applied Microscopy
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    • 제3권1호
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    • pp.29-38
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    • 1973
  • Introduction. The human cutaneous scars manifest themselves many ways in different types according to the factors such as the age, sex, race of the patient as well as the location,. kind and heal ing process of the wound. Among the scars it is quiet difficult to verify the clinical course of the hypertrophic or keloidal scars from the true keloids. However, clinical observations indicate that stress, either mechanical or in the forms of chronic infections, can induce a functional change in the fibroblasts causing an excessive production of collagenous matrix. In this study, we preliminary attempt to justify any difference of the cellular structure between keloids and hypertrophic scars by using electron microscope. Material and Methods. A total of 23 cases: 2 scars, 2 hypertrophic scars and 19 keloids are examined. Immediately, the biopsy tissue was fixed in 10% neutral formalin and 4% glutaraldehyde solution in phosphate buffer for 4 hours, post fixed in 1 % osmium tetraoxide for two hours, dehydrated with graded alcohol, and embedded in Epon 812. Thick sections were stained with hematoxylin eosin, periodic acid-Schiff(PAS) and Van Gieson stain. Thin sections were cut and uranyle acetate, lead citratestain and examined with the electron microscope. Result. The morphologic features of keloid showed thick, homogenously eosinophilic bands of collagen and numberous large active fibroblasts. The hypertrophic scar and soft scar are more cellular than keloid and composed thinner collagenous fiber. For this paper in the etiology of keloids can not as be defined, but and interesting keloidal tissue fibroblast showed irregular nucleus with irregular shape dense bodies and fibril materials contained in to the cytoplasm.

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고준위 방사성폐기물 처분장 불량 용기 발생 시나리오에 대한 폐쇄후 장기 방사선적 안전성 평가 (Post Closure Long Term Safely of the Initial Container Failure Scenario for a Potential HLW Repository)

  • 황용수;서은진;이연명;강철형
    • 방사성폐기물학회지
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    • 제2권2호
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    • pp.105-112
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    • 2004
  • 고준위 방사성폐기물 처분장에서 적용하고 있는 다중 방벽의 한 부분인 처분 용기는 벤토나이트 완충재의 팽윤과 지압으로부터 폐기물을 역학적으로 안정하게 보호함과 동시에 일정 기간 방사성폐기물의 유출을 억제하는 역할을 한다. 처분용기의 건전성은 엄격한 재질 선정과 품질 보증을 통해 확보된다. 그러나 용기 제작 과정이나 수송 중 예상치 못한 사건으로 인해 불량 용기가 발생할 가능성이 있다. 본 논문에서는 이와 같은 경우 방사성폐기물로 인해 생태계에 미치는 환경 영향을 연간 개인 선량으로 평가하였다. 연구결과 일부 불량 처분 용기가 발생하더라도 현 평가에 사용한 입력 데이터 범위에서는, 국내 고준위 방사성폐기물 처분 개념이 방사선적 안전성을 확보할 수 있는 것으로 판명되었다.

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남조류 Synechocystis PCC 6803을 이용한 생물전기화학적 물분해 전기 생산 (Electricity Generation Using Cyanobacteria Synechocystis PCC 6803 in Photosynthetic Bio-Electrochemical Fuel Cell)

  • 김민진;오유관;김미선
    • 한국수소및신에너지학회논문집
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    • 제19권6호
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    • pp.529-536
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    • 2008
  • Cyanobacteria Synechocystis PCC 6803 or the extracted thylakoid membrane from this strain was appled to photosynthetic bio-electrochemical fuel cell(PBEFC) for the production of hydrogen under the illumination of 48Klux using halogen lamp. PBEFC was composed of anode, cathode and membrane between them. Electrode material was carbon paper while electron mediator and receptor were added phenazine methosulfate(PMS) and potassium ferricyanide respectively. When water and 50 mM tricine buffer and $300{\mu}M$ PMS were added to the anode under the light condition, PBEFC produced the current density $4.4{\times}10^{-5}\;mA/cm^2$, $1.4{\times}10^{-4}\;mA/cm^2$ and $2.4{\times}10^{-4}\;mA/cm^2$, respectively. And the addition of the thylakoid membrane to the system increased current density to $1.3{\times}10^{-3}\;mA/cm^2$. Two times increase of the thylakoid membrane into the anode doubled the current density to $2.6{\times}10^{-3}\;mA/cm^2$. But the current density was not increased proportionally to the amount of thylakoid membrane increased. The system was unstable to measure the electricity output due to the foam production in the anode. Addition of triton X-100 and tween 80 stabilized the system to measure the electricity output but the current density was not increased higher than $8.4{\times}10^{-4}\;mA/cm^2$ and $2.3{\times}10^{-3}\;mA/cm^2$. When the thylakoid membrane was substituted to Synechocystis PCC 6803 cells of four-day culture which has chlorophyll contents $20.5{\mu}g/m{\ell}$, maximum current density was $1.3{\times}10^{-3}\;mA/cm^2$ with $1\;k{\Omega}$ resistance.

악안면부 충격시 치아와 악골의 응력 분포에 대한 구강보호장치의 역할에 관한 유한요소분석 - 상악 중절치에 가해진 충격에 대하여 (EFFECT OF A MOUTHGUARD ON STRESS DISTRIBUTION IN TEETH, MAXILLA AND MANDIBLE FOR MAXILLA AND MANDIBULAR IMPACT USING FINITE ELEMENT ANALYSIS)

  • 박지혜;이성복;권긍록;최대균
    • 대한치과보철학회지
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    • 제44권5호
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    • pp.537-548
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    • 2006
  • Statement of problem : The use of mouthguard is important as the leisure life is popular today. Purpose: The purpose of this study is to investigate the effect of a mouthguard on stress distribution in teeth, maxilla and mandible for maxilla impact. Material and methods: The 3-dimensional finite element model was based on a CT scan film of an average korean adult when the subject is using a customized mouthguard which was made with the Signature Mouthguard system of Dreve. The load was applied to the upper central incisor cervical area parellel impact force for 0.1sec(L1). The Von-mises stress analysis with a mouthguard and without a mouthguard was compared. Results: The results of this study were as follows: 1. Without the mouthguard, stress was concentrated on teeth and alveolar bone in all load conditions. 2. With the mouthguard. maximum stress value was decreased and stress was dispersed in all load conditions. 3. Stress extinction with the mouthguard was faster than without the mouthguard in all load conditions. Conclusion: We acknowledged that the mouthguard has a stress buffer effect as the maximum stress value was decreased and stress was dispersed when impact force was applied.

TOC와 통계적 분석에 의한 플라스틱보트 제조공정 개선에 관한 연구 (A Study on the Improvement of Plastic Boat Manufacturing Process Using TOC & Statistical Analysis)

  • 윤건구;김태구;이동형
    • 산업경영시스템학회지
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    • 제39권1호
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    • pp.130-139
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    • 2016
  • The purpose of this paper is to analyze the problems and the sources of defective products and draw improvement plans in a small plastic boat manufacturing process using TOC (Theory Of Constraints) and statistical analysis. TOC is a methodology to present a scheme for optimization of production process by finding the CCR (Capacity Constraints Resource) in the organization or the all production process through the concentration improvement activity. In this paper, we found and reformed constraints and bottlenecks in plastic boat manufacturing process in the target company for less defect ratio and production cost by applying DBR (Drum, Buffer, Rope) scheduling. And we set the threshold values for the critical process variables using statistical analysis. The result can be summarized as follows. First, CCRs in inventory control, material mix, and oven setting were found and solutions were suggested by applying DBR method. Second, the logical thinking process was utilized to find core conflict factors and draw solutions. Third, to specify the solution plan, experiment data were statistically analyzed. Data were collected from the daily journal addressing the details of 96 products such as temperature, humidity, duration and temperature of heating process, rotation speed, duration time of cooling, and the temperature of removal process. Basic statistics and logistic regression analysis were conducted with the defection as the dependent variable. Finally, critical values for major processes were proposed based on the analysis. This paper has a practical importance in contribution to the quality level of the target company through theoretical approach, TOC, and statistical analysis. However, limited number of data might depreciate the significance of the analysis and therefore it will be interesting further research direction to specify the significant manufacturing conditions across different products and processes.