• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.45-45
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• 2022

산업화에 따른 화학물질 사용량의 증가는 담수로의 유해화학물질 유출사고의 위험을 증가시키며, 이러한 사고는 하천수 수질과 수환경 생태계에 심각한 위해와 손상을 야기한다. 이러한 수질사고 발생시 신속 대응을 위해, 하천에 유입된 물질의 거동을 신속하게 예측하는 것이 필요하며 이 경우 1차원 추적모형이 주로 사용된다. 1차원 물질혼합 모형은 하천을 하나의 유선으로 보며, 복잡한 하천흐름의 시스템을 현상학적으로 해석하고, 오염물질의 이송 및 혼합 메카니즘을 모델 매개변수에 반영하여 모형화한다. 이러한 매개변수들은 직접적으로 측정하기 어려우며, 이론에 기반한 매개변수 산정 기법이 구축되지 않은 실정이다. 따라서 대부분의 연구에서는 추적자 실험을 실시하여 유한한 하천구간에서 추적자의 시간-농도곡선(Breakthrough curve, BTC)을 취득하고, 이를 통하여 대상 구간의 매개변수를 역산하는 최적화 기법에 의존하고 있다. 하지만, 모든 하천구간에 대하여 추적자 실험을 수행하여 데이터를 확보하는 것이 어렵기 때문에 최적화 기법의 적용성에 한계가 있다. 본 연구는 흐름정보가 제공되지 않은 미계측 하천구간에서 BTC를 신속하게 예측할 수 있는 회귀모형을 구축하는 것을 목표로 한다. 국내 하천에서 수행한 4회의 추적자 실험으로부터 취득한 28개 구간 케이스의 데이터에 대하여 농도곡선 전처리를 수행하고 14개의 통계적 특징을 추출하였으며, 계측된 흐름특성과의 상관관계를 분석하였다. 분석 결과, 대상 구간에서의 BTC의 변화가 추적자의 유하거리에 매우 높은 상관관계를 보였으며, 이를 이용하여 회귀모형을 제시하였다. 제안된 회귀모형을 적용하여 하류의 지점에서의 BTC를 예측하였으며, 1차원 이송-분산 방정식과 하천저장대모형을 활용한 예측결과와 비교하여 검증하였다. 그 결과, BTC의 변화특성을 활용한 회귀적 예측이 하천 지형 및 흐름의 변동성이 작은 구간에서 1차원 혼합모형들을 이용한 예측보다 더 높은 정확도를 보였으며, 이러한 장점은 장거리 예측에서 더 분명하게 나타났다.

• Korean Journal of Agricultural and Forest Meteorology
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• v.2 no.4
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• pp.190-197
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• 2000

Anions such as C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, P $O_4$$^{3-}$, and organic anions, that do not become a part of the clay mineral crystal lattice, are of considerable interest in soils which are a potential sink caused by acid rain. In this paper, elution of native sulfate and breakthrough curves (BTC) were obtained from miscible displacement of non-specifically or specifically adsorbed anions through non-saturated or saturated Bt soil of Chungwon series. The shape and position of the BTC's could be affected by adsoprtion and ion exchange onto the soil particle surfaces. Measured BTC's for oxalic acid under unsaturated and saturated conditions showed that less pore volumes were required to displace the native S $O_4$$^{2-}$S from the soil column, and that maximum detection limit of oxalic acid reached earlier than under unsaturated. The retarded BTC's to the righthand side could be attributed by different adsorption behavior of each anion, although BTC's may be influenced by the smaller order of velocity change. The alternate breakthrough and elution curves show the rapid approach to the maximum detection limit of C/Co = 1, compared to progressive tailing of elution curve to reach to C/Co = 0. The probable explanation for asymmetric elution patterns for both anion is that the anion was selectively adsorbed on the positively charged soil surface from the solution passing in the soil column. On the other hand, the variations of pH in effluent showed that pH was increased to 7 in the first 6 pore volume and then gradually decreased to pH 4.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.1
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• pp.21-28
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• 2006

We investigated the mobilization of Cd, Pb, and Cr in two different soils in response to sorption capacities and competition for available sorption site while they moved under saturated water conditions. Two soil samples that were clay and sandy clay loam were collected within 20 cm from the upland surface. To do this, we used three different systems of heavy metal combinations such as single, binary, and ternary as solution phase. And then we observed the breakthrough curve (BTC) and elution as a function of pore volume by applying heavy metal solution and displacing K solution until these curves reached to maximum and minimum. The results showed that BTC and elution curves were not symmetric and it required more pore volumes with increasing species of heavy metals in solution phase, as well as longer tailings. Compared the areas over and under BTC and elution curve, relatively small amount of heavy metal was displaced by K even though there were differences in electronegativity among heavy metals. Conclusively, we assumed that heavy metals transport in soil could be influenced by soil physical nonequilibrium and chemical equilibrium in solution as far as there were more than two species of heavy metals existed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.06a
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• pp.43-49
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• 1998

Retardation effect of heavy metals in soils caused by adsorption onto the surfaces of solids particles is well known phenomena. The adsorption of metal ions has been recognized more strong in clay mineral and organic matter contents rather than sands and gravels. In this study, we investigated the retardation effect in two sandy soils by conducting batch and column tests. The column tests were conducted to obtain the relationship between concentration and time known as breakthrough curve (BTC). We applied pulse type injection of ZnCl$_2$solution on the inlet boundary and monitored the effluent concentration at the exit boundary under steady state condition using EC-meter and ICP-AES. Batch test consisted of an equilibrium procedure for fine fractions collected from two sandy soils for various initial ZnCl$_2$concentrations, and analysis of Zn ions in equilibrated solution using ICP-AES. The results of column test showed that i) the peak concentration of Zn analyzed by ICP was far less than that detected by EC-meter for both soils and ii) travel times for peak concentration were more less identical for two different monitoring techniques. The first result can be explained by ion exchange between Zn and other cations initially present in the soil particles since ICP analysis showed a significant amount of Ca, Mg ions in the effluent. From the second result, we found that retardation effect was not present in these soils due to strong cation exchange capacity of Zn ion over other cations since we did not apply a solution containing more adsorptive cations such as Al. The result of batch test also showed high distribution coefficients (K$_{d}$) for two soils supporting the dominant ion exchange phenomena. Based on the retardation factor obtained from the Kd, we predicted the BTC using CDE model and compared with the BTC of Zn concentration obtained from ICP The predicted BTC, however, disagreed with the monitored in terms of travel time and magnitude of the peak concentrations. The only way to describe the prominent decrease of Zn ion was to introduce decay or sink coefficient in the CDE model to account for irreversible decrease of Zn ions in liquid phase.e.

• Journal of Korea Water Resources Association
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• v.55 no.1
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• pp.23-32
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• 2022

This paper performs two-dimensional numerical simulation of surface water-groundwater coupled flow and solute transport to investigate the effect of the hyporheic exchange at the sediment-water interface (SWI) on surface solute transport. For the impermeable bed case in the absence of hyporheic flow, the trapping effect of flow recirculation associated with the ripple bed controls the shape of breakthrough curves (BTCs). However, the permeable bed case with hyporheic flow stimulates the extended tailing of the BTCs more significantly due to the elevated concentration of the BTC tailing resulting from slow hyporheic velocity. Also, the increased bottom pressure at the SWI with an increase in surface velocity shortens the BTC tailing because of increasing hyporheic velocity. These results infer that hyporhiec flow is critically important in predicting solute residence times in surface water.

• Journal of the Korean Society of Groundwater Environment
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• v.6 no.2
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• pp.95-100
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• 1999

Hydrocarbon compounds in vadose zone soils caused by adsorption onto the surfaces of solid particles are generally considered to show retardation effect. In this study, we investigated the retardation effect on the transport of Benzene in a sandy soil by conducting batch and column tests. The batch test was conducted by equilibrating dry soil mass with Benzene solutions of various initial concentrations. and by analyzing the concentrations of Benzene in initial and equilibrated solutions using HPLC. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used KCl and Benzene solutions with the concentration of 10 g/L and 0.88 g/L as a tracer, and injected them into the inlet boundary of the soil sample as a square pulse type respectively, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and HPLC. From the batch test, we obtained a distribution coefficient assuming that a linear adsorption isotherm exists and calculated the retardation factor based on the bulk density and porosity of the column sample. We also predicted the column BTC curve using the retardation factor obtained from the distribution coefficient and compared with the measured BTC of Benzene. The results of the column test showed that i) the peak concentration of Benzene was much smaller than that of KCl and ⅱ) the travel times of peak concentrations for the two tracers were more or less identical. These results indicate that adsorption of Benzene onto the sand panicles occurred during the pulse propagation but the retardation of Benzene caused by adsorption was not present in the studied soil. Comparison of the predicted with the measured BTC of Benzene resulted in a poor agreement due to the absence of the retardation phenomenon. The only way to describe the absolute decrease of Benzene concentration in the column leaching experiment was to introduce a decay or sink coefficient in the convection-dispersion equation (CDE) model to account for an irreversible sorption of Benzene in the aqueous phase.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.3
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• pp.155-161
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• 1998

Retardation effect of heavy metals in soils caused by adsorption onto the surfaces of solids particles is well known phenomenon. In this study, we investigated the retardation effect on the mobility of a Zn in a sandy soil by conducting batch and column tests. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used NaCl and ZnCl$_2$ solutions with the concentration of 10 g/L as a tracer, and injected them respectively into the inlet boundary of the soil sample as a square pulse type, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and ICP-AES. The batch test was conducted based on the standard procedure of equilibrating fine fractions collected from the soil with various initial ZnCl$_2$ concentrations, and analysis of Zn ions in the equilibrated solutions using ICP-AES. The results of column test showed that i) the peak concentration of ZnCl$_2$analyzed by ICP was far less than that of either NaCl or bulk electrical conductivity and ⅱ) travel times of peak concentrations for two tracers were more less identical. The relatively low concentration of Zn can be explained by ion exchange between Zn and other cations, and possible precipitation of Zn in the form of Zn(OH)$_2$due to high pH range (7.0∼7.9) of the effluent. The identical result of travel times of peak concentrations indicates that the retardation effect is not present in the soil. The only way to describe the prominent decrease of Zn ion was to introduce decay or sink coefficient in the CDE model to account for irreversible decrease of Zn ions in the aqueous phase.

• Journal of Korea Soil Environment Society
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• v.4 no.1
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• pp.109-118
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• 1999

Recently, transport parameters of conservative solutes such as KCl in a porous medium have been successfully determined using time domain reflectometry (TDR) . This study was initiated to Investigate the applicability of TDR technique to monitoring the fate of a heavy metal ion in a sandy soil and the distribution of its concentration along travel distance with time. A column test was conducted in a laboratory that consists of monitoring both resident and flux concentrations of $ZnCl_2$in a sandy soil under a breakthrough condition. A tracer of $ZnCl_2$(10 g/L) was injected onto the top surface of the sample as pulse type as soon as a steady-state condition was achieved. Time-series measurements of resistance and electrical conductivity were performed at 10 cm and 20 cm of distances from the inlet boundary by horizontal-positioning of parallel TDR metallic rods and using an EC-meter for the effluent exiting the bottom boundary respectively. In addition. Zn ions of the effluent were analyzed by ICP-AES. Since the mode and position of concentration detected by TDR and effluent were different, comparison between ICP analysis and TDR-detected concentration was made by predicting flux concentration using CDE model accommodating a decay constant with the transport parameters obtained from the resident concentrations. The experimental results showed that the resident concentration resulted in earlier and higher peak than the flux concentration obtained by EC-meter, implying the homogeneity of the packed sandy soil. A close agreement was found between the predicted from the transport parameters obtained by TDR and the measured $ZnCl_2$concentration. This indicates that TDR technique can also be applied to monitoring heavy metal concentrations in the soil once that a decay constant is obtained for a given soil.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.33-42
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• 2000

Adsorption onto the surfaces of solid particles is a well known phenomenon that causes the retardation effect of heavy metals in soils. For adequate remediation of soil and groundwater contamination, it is important to investigate the mobility of heavy metals that largely depends on pH conditions in the soil water since adsorption of heavy metals is pH-dependent. In this study, we investigated the transport of Zn ion under various pH conditions in a sandy soil by conducting batch and column tests. The batch test was performed using the standard procedure of equilibrating fine fractions collected from the soil with eleven different initial $ZnCl_2$ concentrations, and analysis of Zn ion in the equilibrated solutions using ICP-AES. The column test consisted of monitoring the concentrations of soil solutions exiting the soil column with time known as a breakthrough curve (BTC). We injected respectively $ZnCl_2$ and KCl solutions with the concentration of 10 g/L as a tracer in a square pulse type under three different pH conditions (7.7, 5.8, 4.1) and monitored the flux concentration at the exit boundary using an EC meter and ICP-AES. The resident concentration was also monitored at the 10cm-depth by Time Domain Reflectometry (TDR). The results of batch test showed that ion exchange process between Zn and other cations (Ca, Mg) was predominant. The retardation coefficients obtained from adsorption isotherms (Linear, Freundlich, Langmuir) resulted in the various values ranging from 1.2 to 614.1. No retardation effect but ion exchange was found for the BTCs under all pH conditions. This can be explained by the absence of other cations to desorb Zn ion from soil exchange sites under the conditions of ETC experiment imposing blank water as leachate in steady-state flow. As pH decreased, the peak concentration of Zn increased due to the competition of Zn with hydrogen ions ($H^+$) and the concentrations of other cations decreased. The peak concentration of Zn was increased by 12.7 times as pH decreased from 7.7 to 4.1.