• Title/Summary/Keyword: Breaking Process

Search Result 338, Processing Time 0.027 seconds

Fabrication of TiO2 Nanotube Arrays by Anodic Oxidation Method and its Photoelectrochemical Properties (양극산화법에 의한 TiO2 나노튜브 어레이의 제조 및 광전기화학적 특성에 관한 연구)

  • Kim, Seon-Min;Cho, Kwon-Koo;Choe, Yeong-Jin;Kim, Ki-Won;Ryu, Kwang-Sun
    • Journal of Powder Materials
    • /
    • v.17 no.3
    • /
    • pp.216-222
    • /
    • 2010
  • Self-standing $TiO_2$ nanotube arrays were fabricated by potentiostatic anodic oxidation method using pure Ti foil as a working electrode and ethylene glycol solution as electrolytes with small addition of $NH_4F$ and $H_2O$. The influences of anodization temperature and time on the morphology and formation of $TiO_2$ nanotube arrays were investigated. The fabricated $TiO_2$ nanotube arrays were applied as a photoelectrode to dye-sensitized solar cells. Regardless of anodizing temperature and time, the average diameter and wall thickness of $TiO_2$ nanotube show a similar value, whereas the thickness show a different trend with reaction temperature. The thickness of $TiO_2$ nanotube arrays anodized at $20^{\circ}C$ and $30^{\circ}C$ was time-dependent, but on the other hand its at $10^{\circ}C$ are independent of anodization time. The conversion efficiency is low, which is due to a morphology breaking of the $TiO_2$ nanotube arrays in manufacturing process of photoelectrode.

Failure of the Transition to Adulthood among Homeless Young Men and their Family Experience (남성 노숙 청년의 성인기 독립 이행 실패와 원가족 경험)

  • Kim, Soyoung
    • Korean Journal of Social Welfare
    • /
    • v.69 no.3
    • /
    • pp.213-240
    • /
    • 2017
  • In the harsh period for young adults to prepare their successful life, this study aimed to understand the specific experiences of independence transition among homeless young adults. Also this article explored how their family perform as a supportive system for their independence. Using in depth interview materials of 19~39 aged 8 young homeless males, the research analyzed their family's weak support; no family members, no economic support and breaking relationship. As to occasion of independence, the participants sometimes experienced loss of house, evacuation by their family or runaway from their home. It was abrupt and unexpected leaving home. Also their process of independence was beyond their capacity that they suffered from instability job and destitute rather than continuous mental trauma and isolation. In the end they faced serious risky situations that they cannot manage without any help. The findings of this study suggest that quality of family relationship would be more important than economic capital from family and transition to adulthood of vulnerable young adults who don't have family support need much alternative supportive system and social capital.

  • PDF

Application and Analysis of the Steady State Spectral Wave Model for Coastal Waters at Busan New Port Site (부산신항만수역에서 정상상태 스펙트럼 파랑모델의 적용 및 분석)

  • 이학승;이우철;황호동;양상용;이중우
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
    • /
    • 2003.05a
    • /
    • pp.157-164
    • /
    • 2003
  • Introduction of wave model, considered the effect of tide, wind and wave induced currents at the coastal waters of complex bathymetry, is a very important factor for most coastal engineering design and disaster protection problems. As the steady state spectral wave model could simulate depth induced wave shoaling and refraction, current induced refraction effect, steepness induced wave breaking, diffraction, wind wave growth, and wave-wave interaction that redistribute energy, this would support and compensate the gap in the real field of design where other wave models could not deal and cause wrong estimation. In this study, for that sense, we applied the spectral wave model t the large coastal waters near Gaduck Island where the Busan new port construction project is going on, for better understanding and analysis of wave transformation process. We also compared the simulation results with the calculated from the existing model. From such a trial of this study, we hope that broader and sager use of the spectral model in the area of port design and disaster prevention system come through in near future.

  • PDF

CHARACTERISTICS OF DIAMONDLIKE CARBON COATED ALUMINA SEALS AT TEMPERATURES UP TO $400^{\circ}C$ (플라즈마 증착방식에 의해 DLC코팅된 알루미나 세라믹의 코팅박막 특성에 관한 연구)

  • Ok, Chul-Ho;Kim, Byoung-Yong;Kang, Dong-Hun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.11a
    • /
    • pp.397-397
    • /
    • 2007
  • Diamondlike carbon (DLC) coatings were deposited on alumina ceramic seals using a plasma immersion ion deposition technique (PIID). Then they were subjected to tribological tests using a pin-on-disc tribometer under a high load (1.3 GPa) and under elevated temperatures up to 400C. Coefficients of friction (COFs) were recorded and compared with that of the untreated alumina while the wear tracks were analyzed using SEM with EDS to characterize the DLC films. To enhance the DLC adhesion to the substrate, various interlayers including Si and Cr were deposited using the PIID process or an ion beam assisted deposition (IBAD) method. It was observed that the DLC coating, if adhering well to the substrate, reduced the COFs significantly, from 0.4-0.8 for the uncoated alumina to about 0.05-0.1, within the tested temperature range. The adhesion was determined by the interlayer type and possibly by the application method. Cr interlayer did not perform as well as the Si interlayer. This could also be due to the fact that the Cr interlayer and the subsequent DLC coating had to be done in two different processing systems, while both the Si interlayer and the subsequent DLC film were deposited in one system without breaking the chamber. The coating failure mode was found to be delamination between the Cr and the alumina substrate. In contrast, the Si interlayer with proper DLC deposition procedures resulted in very good adhesion and hence excellent tribological performance. Further study may lead to future DLC applications of ceramic seals.

  • PDF

Socio economic Approach to the Chronic State of Famine and Exploitation of Famine Relief Food in the Later Half of Chosun Period (조선후기(朝鮮後期) 기근(飢饉) 만성화(慢性化)와 구황식품(救荒食品) 개발(開發)의 사회(社會).경제적(經濟的) 고찰(考察))

  • Kim, Hee-Sun;Kim, Sook-Hee
    • Journal of the Korean Society of Food Culture
    • /
    • v.2 no.1
    • /
    • pp.81-92
    • /
    • 1987
  • This treatise deals with chronic state of famine and exploitation of famine relief food in the later half of Chosun Period and especially in relation with socio-economic changes. There with the impact of socio-economic factors on the chronic state of famine and exploitation of famine relief food is studied mainly with a literary approach. The influential factors which lead to the chronic state of famine were not only climatic restrictions such as flood and drought but socio-economic factors such as foreign invasion (Japanease invasion and Ching's invasion), frequent breaking out of revolt and technological development of agriculture (rice transplantation). And disorder of land system and cultivation of cash crops by the richer peasantry, lowering the economic status of the poorer peasantry who were a major constituents of the population, aggravated the famine state. Because the poorer peasantry were under the shortage of food, they had to seek something edible in the fields and mountains. In this process various kinds of famine relief foods were exploited by the poorer peasantry. The majority of famine relief foods were wild vegetables. Consequently the Chronic state of famine was a cause to introduce various edible wild vegetables into Korean food, which influenced modern vegetarian food habits and firmed the Korean's favorite taste to be hot and salty. These wild vegetables couldn't have a marvelous effect on the relief of starved people. Potatoes and sweet potatoes, which were newly introduced foreign crops, were encouraged to be cultivated for famine relief. But these tubers, unable to be staple food, didn't contribute to an increase in population.

  • PDF

Comparative Assessment of Quantitative Methods determining the Amount of Calcium Carbonate Minerals derived from Biocalcification (생물학적 칼슘화에 의해 생성된 CaCO3 광물의 정량분석 방법 비교 평가)

  • Ahn, Chang-Min;Bae, Young-Shin;Ham, Jong-Heon;Cheon, Seung-Kyu;Kim, Chang-Gyun
    • Journal of Soil and Groundwater Environment
    • /
    • v.18 no.5
    • /
    • pp.1-6
    • /
    • 2013
  • This study was performed to develop a method for quantitative analysis obtaining the amount of calcium carbonate minerals formed when Ca salts biomimetically reacted with carbon dioxide. There were two methods compared; 1) volumetric calcimeter method that determining the amount of released carbon dioxide after calcium carbonate minerals were acidified by 4N HCl and 2) Thermogravimetry-Differential Thermal Analysis (TG-DTA) adopting differential decomposition temperature breaking-up the structural link within calcium carbonate minerals. The comparisons were made by batch experiment (i.e., biocalcification process) along with control (i.e., nominal concentration of $CaCO_3$ prepared). For the control, TG-DTA took a minor root mean square deviation (RMSD) of 1.1~5.9 mg, whereas volumetric calcimeter exposed a greater RMSD of 28.3 mg. For the biocalcification, the amount of $CaCO_3$ was more precisely obtained for TG-DTA rather than that of volumetric calcimeter. It was decided that TG-DTA was more successfully used for quantitative analysis to observe the amount of calcium carbonate minerals derived from biocalcification.

Microstructure of Cu-Ag Filamentary Nanocomposite Wires Annealed at Different Temperatures (어닐링한 Cu-Ag 나노복합재 와이어의 미세조직)

  • Kwak, Ho Yeon;Hong, Sun Ig;Lee, Kap Ho
    • Korean Journal of Metals and Materials
    • /
    • v.49 no.12
    • /
    • pp.995-1000
    • /
    • 2011
  • The microstructure of Cu-24 wt.%Ag filamentary nanocomposite fabricated by a thermo-mechanical process has been investigated by transmission electron microscopy (TEM) observations. This study is focused on the stability of Ag filaments formed by cold drawing; the effects of thermal treatment on the precipitation behavior and distribution of Ag-rich precipitates were also investigated. The Ag filaments elongated along the <111> orientation were observed in Cu-rich ${\alpha}$ phase of the as-drawn specimen and the copper matrix and the silver filament have a cube on cube orientation relationship. Annealing at temperatures lower than $200^{\circ}C$ for the as-drawn specimen caused insignificant change of the fibrous morphology but squiggly interfaces or local breaking of the elongated Ag filaments were easily observed with annealing at $300^{\circ}C$. When samples were annealed at $400^{\circ}C$, discontinuous precipitation was observed in supersaturated Cu solid solution. Ag precipitates with a thickness of 7-20 nm were observed along the <112> direction and the orientation relationship between the copper matrix and the Ag precipitates maintained the same orientation relationship in the as-drawn specimen. The interface between the copper matrix and the Ag precipitates is parallel to {111} and micro-twins were observed in the Ag precipitates.

A Study on Optimization of Picking Facilities for e-Commerce Order Fulfillment (온라인 주문 풀필먼트를 위한 물류센터 피킹 설비 최적화에 대한 연구)

  • Kim, TaeHyun;Song, SangHwa
    • The Journal of Society for e-Business Studies
    • /
    • v.26 no.1
    • /
    • pp.67-78
    • /
    • 2021
  • The number of domestic e-commerce transactions has been breaking its own record by an annual average growth rate of over 20% based on volume for the past 5 years. Due to the rapid increase in e-commerce market, retail companies that have difficulty meeting consumers in person are in fierce competition to take the lead in the last mile service, which is the only point of contact with customers. Especially in the delivery area, where competition is most intense, the role of the fulfillment center is very important for service differentiation. It must be capable of fast product preparation ordered by consumers in accordance with the delivery service level. This study focuses on the order picking system for rapid order processing in the fulfillment center as an alternative for companies to gain competitive advantage in the e-commerce market. A mixed integer programming model was developed and implemented to optimize the stock replenishment in order picking facilities. The effectiveness was scientifically and objectively verified by simulation using the actual operation process and data.

Understanding Physical Mechanism of 2022 European Heat Wave (2022년 발생한 기록적인 유럽 폭염 발생의 역학적 원인 규명 연구)

  • Ju Heon Kim;Gun-Hwan Yang;Hyun-Joon Sung;Jung Hyun Park;Eunkyo Seo
    • Atmosphere
    • /
    • v.33 no.3
    • /
    • pp.307-317
    • /
    • 2023
  • This study investigates the physical mechanisms that contributed to the 2022 European record-breaking heatwave throughout May-August (MJJA). The European climate has experienced surface warming and drying in the recent decade (1979~2022) which influences the development of the 2022 European heatwave. Since its spatial pattern resembles the 2003 European heatwave which is a well-known case developed by the strong coupling of near-surface conditions to land surface processes, the 2022 heatwave is compared with the 2003 case. Understanding heatwave development is carried out by the European Centre for Medium-Range Weather Forecasts (ECMWF) Reanalysis version 5 (ERA5) and daily maximum surface temperature released by NCEP (National Centers for Environmental Prediction) CPC (Climate Prediction Center). The results suggest that the persistent high pressure along with clear sky tends to increase the downward shortwave radiation which leads to enhanced sensible heat flux with the land surface dryness. Terrestrial Coupling Index (TCI), a process-based multivariate metric, is employed to quantitatively measure segmented feedback processes, separately for the land, atmosphere, and two-legged couplings, which appears to the development of the 2022 heatwave, can be viewed as an expression of the recent trends, amplified by internal land-atmosphere interactions.

Rock cutting behavior of worn specially-shaped PDC cutter in crystalline rock

  • Liu, Weiji;Yang, Feilong;Zhu, Xiaohua;Zhang, Yipeng;Gong, Shuchun
    • Geomechanics and Engineering
    • /
    • v.31 no.3
    • /
    • pp.249-263
    • /
    • 2022
  • The specially-shaped Polycrystalline Diamond Compact (PDC) cutter is widely used in drill bit design due to its advantages of high rock cutting efficiency, strong impact resistance and long service life in hard and abrasive formation drilling. A detailed understanding of rock cutting behavior of worn specially-shaped PDC cutter is essential to improve the drilling efficiency and decrease the drilling costs. In this paper, the theoretical models of two new principles (loading performance (LP) and cutting performance (CP)) are derived for evaluating the cutting process of worn specially-shaped cutter, the theoretical models consider the factors, such as cutter geometry, aggressiveness, stress state, working life, and rock cutting efficiency. Besides, the numerical model of heterogeneous granite is developed using finite element method combined with Voronoi tessellation, the LP and CP of 12 kinds of worn specially-shaped PDC (SPDC) cutters are analyzed. The results found that the mechanical specific energy (MSE) of worn cutters first increase and then decrease with increasing the cutting depth, and the MSE increase with the increase of back rake angle except for Conical cutter and Wedge-shaped cutter. From the perspective of CP, the worn PDC cutters are more suitable for the smaller cutting depths, and the back rake angle has little effect on the CP of the specially-shaped worn PDC cutters. Conical cutter, Saddle-shaped cutter and Ellipse-shaped cutter have the highest CP value, while Rhombus-shaped cutter, Convex cutter and Wedge-shaped cutter have the lowest value in selecting cutters. This research leads to an enhanced understanding of rock-breaking mechanisms of worn SPDC cutters, and provides the basis to select of specially-shaped PDC cutters for the specific target formation.