• 제목/요약/키워드: Breakdown Mechanism

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A Comparative Study of Numerical Methods on Aerodynamic Characteristics of a Compressor Rotor at Near-stall Condition

  • Kim, Donghyun;Kim, Kuisoon;Choi, Jeongyeol;Son, Changmin
    • International Journal of Aeronautical and Space Sciences
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    • 제16권2호
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    • pp.157-164
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    • 2015
  • The present work performs three-dimensional flow calculations based on Reynolds Averaged Navier-Stokes (RANS) and Delayed Detached Eddy Simulation (DDES) to investigate the flow field of a transonic rotor (NASA Rotor 37) at near-stall condition. It is found that the DES approach is likely to predict well the complex flow characteristics such as secondary vortex or turbulent flow phenomenon than RANS approach, which is useful to describe the flow mechanism of a transonic compressor. Especially, the DES results show improvement of predicting the flow field in the wake region and the model captures reasonably well separated regions compared to the RANS model. Besides, it is discovered that the three-dimensional vortical flows after the vortex breakdown from the rotor tip region are widely distributed and its vortex structures are clearly present. Near the rotor leading edge, a part of the tip leakage flows in DES solution spill over into next passage of the blade owing to the separation vortex flow and the backflow is clearly seen around the trailing edge of rotor tip. Furthermore, the DES solution shows strong turbulent eddies especially in the rotor hub, rotor tip section and the downstream of rotor trailing edge compared to the RANS solution.

Nucleophilic Substitution Reactions of Aryl Thiophene-2-carbodithioates with Pyridines in Acetonitrile

  • Oh, Hyuck-Keun;Lee, Jae-Myon
    • Bulletin of the Korean Chemical Society
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    • 제25권2호
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    • pp.203-206
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    • 2004
  • The kinetics of reactions between Z-aryl thiophene-2-carbodithioates and X-pyridines in acetonitrile at 60.0 $^{\circ}C$ have been investigated. The Bronsted plots obtained for the pyridinolysis of aryl thiophene-2-carbodithioates are curved, with the center of curvature at $pK_a$ ~ 5.2 ($pK_a^{\circ}$). The Bronsted plots for these nucleophilic reactions show a change in slope from a large ( ${\beta}_X{\cong}$0.78-0.87) to a small ( ${\beta}_X{\cong}$0.33-0.35) value, which can be attributed to a change in the rate-determining step from breakdown to formation of a zwitterionic tetrahedral intermediate in the reaction path as the basicity of the pyridine nucleophile increases. A clear-cut change in the crossinteraction constants, ${\rho}_{XZ}$, from +0.92 to -0.23 supports the proposed mechanistic change. The breakpoint at $pK_a$ = 5.2 for R = thiophene ring in the present work is in agreement with those for the pyridinolysis of R = Me and 2-furyl, and attests to the insignificant effects of acyl group, R, on the breakpoint.

A study on the formation and properties of silicone thin film by the plasma polymerization. (플라즈마를 이용한 유기 실리콘 박막의 합성과 그 특성에 관한 연구)

  • Kim, I.S.;Kang, D.P.;Han, D.H.;Yun, M.S.;Park, S.H.
    • Proceedings of the KIEE Conference
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    • 대한전기학회 1991년도 하계학술대회 논문집
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    • pp.233-237
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    • 1991
  • In the study, samples were made on the electrode in internal glass bell jar by the radio frequency discharge polymerization. The polymerization rate of samples was observed as a function of r.f. discharge power. The characteristics of polymers obtained from TMDSO and HMDSO were analyzed by FT-IR and TGA, and their electrical properties were examined on insulation resistivity, breakdown voltage, dielectric constant, and tan ${\delta}$. (1) There was no difference between PPTMDSO and PPHMDSO in a polymerization rate and thermal and electrical properties. (2) The growing rates of thin film with discharge powers were from $0.42{\mu}/h$ to $1.2{\mu}m/h$. (3) According to IR spectra analysis, discharge power did not effect polymer structure due to polyermization mechanism and effected only polymerization rate. (4) PPTMDSO and PPHMDSO were thermally resistive polymers which did not decompose to $300^{\circ}C$.

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Effects of Air Void at the Steel-Concrete Interface on the Corrosion Initiation of Reinforcing Steel in Concrete under Chloride Exposure

  • Nam Jin-Gak;Hartt William H.;Kim Kijoon
    • Journal of the Korea Concrete Institute
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    • 제17권5호
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    • pp.829-834
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    • 2005
  • A series of reinforced G109 type specimens was fabricated and pended with a 15 weight percent NaCl solution. Mix design variables included 1) two cement alkalinities (equivalent alkalinities of 0.32 and 1.08), 2) w/c 0.50 and 3) two rebar surface conditions (as-received and wire-brushed). Potential and macro-cell current between top and bottom bars were monitored to determine corrosion initiation time. Once corrosion was initiated, the specimen was ultimately autopsied to perform visual inspection, and the procedure included determination of the number and size of air voids along the top half of the upper steel surface. This size determination was based upon a diameter measurement assuming the air voids to be half spheres or ellipse. The followings were reached based upon the visual inspection of G109 specimens that were autopsied to date. First, voids at the steel-concrete interface facilitated passive film breakdown and onset of localized corrosion. Based upon this, the initiation mechanism probably involved a concentration cell with contiguous concrete coated and bare steel serving as cathodes and anodes, respectively. Second, the corrosion tended to initiate at relatively large voids. Third, specimens with wire-brushed steel had a lower number of voids at the interface for both cement alkalinities, suggesting that air voids preferentially formed on the rough as-received surface compared to the smooth wire brushed one.

Cruciferous Vegetables: Dietary Phytochemicals for Cancer Prevention

  • Abdull Razis, Ahmad Faizal;Noor, Noramaliza Mohd
    • Asian Pacific Journal of Cancer Prevention
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    • 제14권3호
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    • pp.1565-1570
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    • 2013
  • Relationships between diet and health have attracted attention for centuries; but links between diet and cancer have been a focus only in recent decades. The consumption of diet-containing carcinogens, including polycyclic aromatic hydrocarbons and heterocyclic amines is most closely correlated with increasing cancer risk. Epidemiological evidence strongly suggests that consumption of dietary phytochemicals found in vegetables and fruit can decrease cancer incidence. Among the various vegetables, broccoli and other cruciferous species appear most closely associated with reduced cancer risk in organs such as the colorectum, lung, prostate and breast. The protecting effects against cancer risk have been attributed, at least partly, due to their comparatively high amounts of glucosinolates, which differentiate them from other vegetables. Glucosinolates, a class of sulphur-containing glycosides, present at substantial amounts in cruciferous vegetables, and their breakdown products such as the isothiocyanates, are believed to be responsible for their health benefits. However, the underlying mechanisms responsible for the chemopreventive effect of these compounds are likely to be manifold, possibly concerning very complex interactions, and thus difficult to fully understand. Therefore, this article provides a brief overview about the mechanism of such compounds involved in modulation of carcinogen metabolising enzyme systems.

LES Investigation of Pressure Oscillation in Solid Rocket Motor by an Inhibitor (고체모터의 인히비터에 의한 압력 진동 특성 LES 연구)

  • Hong, Ji-Seok;Moon, Hee-Jang;Sung, Hong-Gye
    • Journal of the Korean Society of Propulsion Engineers
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    • 제19권1호
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    • pp.42-49
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    • 2015
  • The pressure oscillation induced by inhibitor in a solid rocket motor has been investigated by 3D large eddy simulation(LES) and proper orthogonal decomposition(POD). The vortex generation and breakdown at inhibitor are periodically observed between the inhibitor and the nozzle by flow-acoustic coupling mechanism. The excitation of pressure oscillation occurs as the flow impinges on the submerged nozzle head which recirculate in the cavity in rear dome of the motor chamber. The vortex generation frequency is closely related with the shedding frequencies of the detached vorticities at the inhibiter, which fairly compared with the experimental data.

A Study on the Turbulent Flowfield in the Annular Combustor with the Multi Swirl Injectors (환형연소기의 Multi Swirl Injector 상호간섭 영향에 관한 연구(1))

  • Kim, Jong-Chan;Sung, Hong-Gye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 한국추진공학회 2009년도 춘계학술대회 논문집
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    • pp.289-292
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    • 2009
  • Injector dynamics of multi swirl injectors in an annular combustor have been investigated by LES(Large Eddy Simulation) turbulent model with MPI parallel computation technique. The present study employs the LM6000 lean premixed swirl-stabilized annular combustor. Real shape combustor is simulated in order to investigate the detail interaction mechanism among multi-injectors. The strong vortex breakdown occurs at the impinging surface between the adjacent injectors so that the complex and strong oscillatory pressure propagates inside of the combustor. Tangential pressure fluctuation mode was captured by including multi injectors in computational domain.

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Cholera Toxin Disrupts Oral Tolerance via NF-κB-mediated Downregulation of Indoleamine 2,3-dioxygenase Expression

  • Kim, Kyoung-Jin;Im, Suhn-Young
    • Biomedical Science Letters
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    • 제23권3호
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    • pp.175-184
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    • 2017
  • Cholera toxin (CT) is an ADP-ribosylating bacterial exotoxin that has been used as an adjuvant in animal studies of oral immunization. The mechanisms of mucosal immunogenicity and adjuvanticity of CT remain to be established. In this study, we investigated the role of indoleamine 2,3-dioxygenase (IDO), which participates in the induction of immune tolerance, in CT-mediated breakdown of oral tolerance. When IDO-deficient ($IDO^{-/-}$) mice and their littermates were given oral ovalbumin, significant changes in antibody responses, footpad swelling and $CD4^+$ T cell proliferation were not observed in $IDO^{-/-}$ mice. Feeding of CT decreased IDO expression in mesenteric lymph nodes (MLN) and Peyer's patch (PP). CT-induced downregulation of IDO expression was reversed by inhibitors of nuclear factor-kappa B (NF-${\kappa}B$), pyrrolidine dithiocarbamate and p50 small interfering RNA. IDO expression was downregulated by the NF-${\kappa}B$ inducers lipopolysaccharide and tumor necrosis factor-${\alpha}$. CT dampened IDO activity and mRNA expression in dendritic cells from MLN and PP. These data indicate that CT disrupts oral tolerance by activating NF-${\kappa}B$, which in turn downregulates IDO expression. This study betters the understanding of the molecular mechanism underlying CT-mediated abrogation of oral tolerance.

Chemical Properties of Insulation Paper in oil after Thermal Aging (열 열화에 따른 유입절연지의 화학적 특성)

  • Kim, Pil-Hwan;Kim, Jae-Hoon;Kim, Ju-Han;Lee, Won-Yeong;Han, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기설비전문위원
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    • pp.77-79
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    • 2004
  • It is caused that insulation paper, which had got a lot of thermal stress by over-load after installation, should have been deteriorated in electrical and mechanical characteristics. Beside, insulation material is decreased the insulating property and accelerated aging of them in case of dielectric loss when transformers are manufactured with some moisture or transformers would have been them because of moisture-permeation. Therefore, in this study we experienced the influence of moisture content in case of the thermal aged insulation paper. we have measured tan 6 and breakdown voltage in the ratio of paper' moisture content before the aging and then taken the same tests again after insulation paper thermally accelerating-aged. There is a purpose to gain data for a life-design and to establish aging mechanism in order to continuously study life expectancy of the insulation paper

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Analysis of Predischarge Processes of $SF_6$ Gas Stressed by lmpulse Voltages under Nonuniform Electric Field (불평등전계중에서 임펄스전압에 대한 $SF_6$ 기체의 전구방전과정의 분석)

  • 이복희;이경옥;이창준;백승권
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • 제13권1호
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    • pp.85-93
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    • 2000
  • In this paper, the predischarge propagation processes of SF\ulcorner gas stressed by impulse voltages under nonuniform electric field perturbed by a needle protrusion are described. The statistical and formative time-lags and the time interval between leader pulses were investigated on the basis of the predischarge current measured in the gas pressure range of 0.1~0.5 MPa. The predischarge current is closely related to the waveform, amplitude and polarity of applied votages, the gas pressure and the gap geometry. Both the positive and negative predischarge processes in nonuniform electric field develop in a regime of stepwise leader propagation leading to electrical breakdown. The mean of the time interval between leader pulses gives about a factor of 10 higher for the negative than for the positive leader current puls-es. According as the gas pressure increases, the statistical time-lag was almost unchangeable, but the formative time-lag was gradually decreased.

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