• Title/Summary/Keyword: Borax

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Characterization of vanadium carbide coating deposited by borax salt bath process

  • Aghaie-Khafri, M.;Daemi, N.
    • Advances in materials Research
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    • v.1 no.3
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    • pp.233-243
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    • 2012
  • Thermal reactive diffusion coating of vanadium carbide on DIN 2714 steel substrate was performed in a molten borax bath at $950-1050^{\circ}C$. The coating formed on the surface of the substrate had uniform thickness ($1-12{\mu}m$) all over the surface and the coating layer was hard (2430-2700 HV), dense, smooth and compact. The influence of the kinetics parameters, temperature and time, has been investigated. Vanadium carbide coating was characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and X-ray diffraction analysis (XRD). The corrosion resistance of the coating was evaluated by potentiodynamic polarization in 3.5% NaCl solution. The results obtained showed that decrease of coating microhardness following increasing time and temperature is owing to the coarsening of carbides and coating grain size.

Growth of $ZrO_2$ Single Crystal Using Flux Method (융제법의 의한 $ZrO_2$ 단결정 성장)

  • 이희훈;오근호;이종근;신건철
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.3-8
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    • 1985
  • $ZrO_2$ single crystals were grown by slow cooling flux method using Borax $(Na_2B_4O_7)$ and KF as flux agent. The morphology of grown crystals was observed under a petrographic microscope. And the results obtained from grow crystals were as follows : 1. $ZrO_2$ crystals grown in the present work are morphologically divided into two shapes ; tabular and den-dritic crystals. 2. The maximum size of the crystals grown reaches to $4{\times}15{\times}2mm$ on edge into length at $ZrO_2$ 15mole% Borax 50mole% and KF 35mole% 3. $ZrO_2$ single crystals grown by flux method have monoclinc structure. 4. The content of KF as flux agents was limited by 60mole% KF. Since alumina crucible was heavily damaged by increasing KF content.

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Formation of Wear Resistant Layer on Steel by Immersion in Borax Bath After Nitriding (질화후 붕사욕 침적에 의한 강의 내마모성 피복층 형성에 관한 연구)

  • 김선규;유정광
    • Journal of the Korean institute of surface engineering
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    • v.28 no.6
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    • pp.361-367
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    • 1995
  • When steels are heated at $1000^{\circ}C$ in a fused borax bath containing $V_2O_5$ and $B_4C$powders, vanadium carbide layers are formed on the steel surfaces. Since a decrease in carbon concentration and in microhardness in the substrate just below the carbide layer has been observed, gas nitrocarburizing and vanadium carbide forming processes were combined to form a V(C,N) type layer which prevented the decrease in carbon concentration in the substrate. EPMA analysis was done for this V(C,N) type layer. Hardness just below the layer and wear resistance properties of such treated specimens were investigated.

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Rheology Analysis of Cement Paste According to the Concentration of Borax Diluted Solution (붕사 희석액 농도에 따른 시멘트 페이스트의 레올로지적 분석)

  • Lee, Hyang-Sun;Lee, Yu-Jeong;Han, Dong-Yeop
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.110-111
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    • 2019
  • Concrete with high thixotropy has a lower plastic viscosity when pour in, thus demonstrating fluidity, and After poured, the viscosity can be restored again to ensure stable progress without additional liquidity and material separation. Therefore, in this study, a basic study of thixotropy of concrete was proceeded through cross-linked bond of PVA and Borax. Therefore, it is judgment that the higher the concentration of boron solutions, the higher the strength of the interconnections between PVA and boron.

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Strength properties of inorganic adhesives using dead burned magnesia and phosphate according to addition ratio of borax (사소마그네시아와 인산염을 활용한 무기접착재의 붕사첨가율에 따른 강도특성)

  • Kim, Dae-Yeon;Pyeon, Su-Jeong;Lim, Jeong-Jun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.48-49
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    • 2018
  • Recently the old buildings have been increasing and increasing reconstruction. As a result, the frequency of use of architectural adhesives has increased. Adhesives are not only used for bonding but also for building materials used in various fields. However, since the adhesive is made of an organic material, it causes various skin diseases and sick house syndrome, and when a fire occurs, harmful substances are generated, and incomplete combustion may cause personal injury. Therefore, in this study, to solve the disadvantages of conventional adhesives, we tried to develop inorganic adhesives using inorganic materials.

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Redrying Fire - Retardant - Treated Structural Plywood (구조용(構造用) 내화처리(耐火處理) 합판(合板)의 재건조(再乾燥)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Schaffer, E.L.
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.4
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    • pp.1-21
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    • 1981
  • Exterior grades of Douglas-fir and aspen plywood were impregnated with interior fire-retardant chemicals and redried under low-, intermediate-, and high-temperature drying conditions. Fire-retardant treatments included borax-boric acid, chromated zinc chloride, minalith, pyresote, and a commercial formulation. Drying processes included kiln and press-drying. Evaluated were drying rates and defects generated. The borax-boric acid and the commercial treatments redried at rates similar to water-treated controls. Other salt treatments were significantly slower drying and more defect prone. Chromated zinc chloride treatment was consistently the slowest drying and most defect prone. Press drying was three times faster at an equivalent temperature level. However, thickness shrinkage doubled because of 50 1b/in. platen pressure.

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Physical and Mechanical Properties and Fire-endurance Characteristics of Recycled Particleboards

  • Suh, Jin-Suk;Han, Tae-Hyung;Park, Joo-Saeng;Park, Jong-Young
    • Journal of the Korea Furniture Society
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    • v.19 no.6
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    • pp.475-486
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    • 2008
  • In this study, fire-retardant chemicals were melt with mixed composition ratios of dibasic ammonium phosphate and each half of boric acid and borax in hot water, in which hammer-milled chips were immersed to increase swelling of waste particleboards. Also, fire-retardant treated particles from sawn lumber chip and recycled particleboard chip were composed in ratio of 70:30 in core layer to improve boards' properties. Retention ratio of fire-retardant chemicals for the particles for face layer was high due to high specific surface area, and that of sawn lumber chips was somewhat higher than that of recycled particleboard chips. The mixture of particles from sawn lumber chips and recycled PB of 70:30 in weight ratio exceeded bending strength of 100 $kgf/cm^2$. It seemed that the relatively greater portions of dibasic ammonium phosphate affected adversely to dimensional stability, however fire-retardants treatment resulted in distinct effect lowering formaldehyde emission such as $E_0$ type(0.5mg/$\ell$ or less) in KS F 3104. In fire-retardancy, the recycled boards with a mixed ratio of dibasic ammonium phosphate to boric acid borax(50:50 mixture) of 70% to 30% in weight satisfied fire-retardancy 3rd grade in KS F 2271, and also this composition from cone calorimeter test met same standard grade figuring total heat release of 4.6MJ/$m^2$.

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Fundamental Properties of MgO Base Ceramic Mortar for Concrete Repair Material (MgO계 세라믹 모르타르를 활용한 콘크리트 보수재료의 기초물성평가)

  • Park, Joon-Woo;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.29 no.4
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    • pp.407-413
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    • 2017
  • The fundamental property of magnesia phosphate cement (MPC) for concrete repair material was investigated in this research. For mechanical properties, setting time, compressive strength and tensile/flexural bond strength were measured, and hydration products were detected by X-ray diffraction. The specimens were manufactured with dead burnt magnesia and potassium dihydrogen phosphate was admixed to activate the hydration of magnesia and a borax was used as a retarder. To observe the pore structure and ionic permeability of MPC mortar, mercury intrusion porosimetry was performed together with rapid chloride penetration test (RCPT). As a result, time to set of Fresh MPC mortar was in range of 16 to 21 min depend on the M/P ratio. Borax helped delaying setting time of MPC to 68 min. The compressive strength of MPC with M/P of 4 was sharply developed to 30 MPa within 12 hours. The compressive strength of MPC mortar was in range of 11.0 to 30.0 MPa depend on the M/P ratio at 12 hours of curing. Both tensile and flexural bond strength of MPC to old substrate (i.e. MPC; New substrate to OPC; Old substrate) were even higher than ordinary Portland cement mortar (i.e. [OPC; New substrate] to [OPC; Old substrate]) does, accounting 19 and 17 MPa, respectively. The total pore volume of MPC mortar was lower than that of OPC mortar. MPC mortar had the entrained air void rather than capillary pore. The RCPT showed that total charge passed of OPC mortar had more than that of MPC mortar, which can be explained by the pore volume and pore distribution.

Studies on the Mulberry Sapling II. Several Factors Affected to the Non-sprouting Sapling (뽕나무 접목묘에 관한 연구 II. 활착불량묘의 발생 원인에 관한 연구)

  • 이원주;권영하
    • Journal of Sericultural and Entomological Science
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    • v.27 no.2
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    • pp.1-6
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    • 1985
  • To study the non-sprouting causes of mulberry saplings, 8 treatments, borax + lime + compost, borax, lime, Jamsi fertilizer No. 1, heavy nitrogen application, branch harvest, heavy harvest and no treatment were applied on the nursery garden. The tract used as the paddy field before sapling produced was very poor in the soil chemical and physical properties. The results were as follows; 1. The survial rates of saplings were higher than 98% in the treatments of borax, lime, Jamsi fertilizer No. 1, whereas were higher than 98% in the treatments of borax, lime, Jamsi fertilizer No. 1, whereas heavy nitrogen 59% and heavy harvest 71%. 2. The survial rate was showed deeper relationship with the chemical concentration in stem cortex than in root cortex, especially the content of B, Cu and Zn. 3. The nitrogen content in stem cortex was much higher in the heavy nitrogen treatment by 0.89%, where as 0.6∼0.7% in the other treatments. However, treatments of the heavy harvest and the branch harvest were around 5%. 4. In order to decrease the non-sprouting sapling rate, nursery garden should be good in soil chemical and physical properties. Harvest from saplings and heavy nitrogen application should be prevented and lime or Jamsi fertilizer should be applied to saplings.

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