• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.835-838
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• 2008

This study presents the nonlinear finite element analysis to predict the behavior of reinforced concrete (RC) beams shear-strengthened with fiber-reinforced polymer laminates (FRP). In this paper, modeling concept for the FRP is introduced to enable the use of finite element methods for the shear analysis of RC beams shear-strengthened with FRP composites. The numerical techniques are used to represent the FRP composite, bond properties between the FRP and the concrete, and the RC beams. According to the proposed modeling methods, a finite element analysis is performed using a two-dimensional nonlinear finite element analysis program, VecTor2, based on the Disturbed Stress Field Model (DSFM). To verify the application of the DSFM for the prediction of the behavior of the shear-critical beams strengthened with FRP composites in shear, a detailed comparison between experimental and numerical results for the response of the RC beams is carried out.

• Asia pacific journal of information systems
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• v.20 no.3
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• pp.51-72
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• 2010

Given the extensive role of IS in everyday life and the increasing presence of women in IS users, understanding gender differences in individual technology continuance usage decisions is an important issue. Nevertheless, much of the large body of research on gender differences has just examined mean differences between women and men in terms of abilities, usage habit, and traits. Even though lots of psychology studies have shown that women, more than men, were influenced by affective factors, gender-affection-continuance use linkage has not been examined in the context of on-line shopping services. Therefore, the primary purpose of this paper is to seek to examine gender differences in terms of influence of affective factor in the context of IS continuance use. Meanwhile, IS continuance has been an important subject of study in the IT research area. To date, to explain why and how users are motivated to continue to use on-line shopping services, lots of theory-based research such as expectation-confirmation model (ECM) has been proposed. In particular, various affective factors have been proposed to explain continuance use of on-line shopping services recently. Affective factors have been regarded as essential factors for increasing relational strength and satisfaction. Several affective factors have been studied by prior IS adoption and continuance studies. Among them are enjoyment and anxiety. In IS continuance research, positive affect has been commonly and narrowly conceptualized and measured as the enjoyment which a person derives from using computers. Hence, in this study, we introduced intimacy factor, which was conceptually related to the quality of interactions and relationships in previous research. It also has been regarded as essential factors for strengthening human relationships. As a result, we have observed gender effect while examining intimacy-continuance bond. As expected based on the previous literatures, women seem to be more sensitive in affective factors. The contribution point here is that we find evidence in the context of on-line shopping services.

• Earthquakes and Structures
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• v.17 no.6
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• pp.545-556
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• 2019

Bridge piers with bending failure mode are seriously damaged only in the area of plastic hinge length in earthquakes. For this situation, a modified method for the layout of longitudinal reinforcement is presented, i.e., the number of longitudinal reinforcement is increased in the area of plastic hinge length at the bottom of piers. The quasi-static test of three scaled model piers is carried out to investigate the local longitudinal reinforcement at the bottom of the pier on the seismic performance of the pier. One of the piers is modified by increased longitudinal reinforcement at the bottom of the pier and the other two are comparative piers. The results show that the pier failure with increased longitudinal bars at the bottom is mainly concentrated at the bottom of the pier, and the vulnerable position does not transfer. The hysteretic loop curve of the pier is fuller. The bearing capacity and energy dissipation capacity is obviously improved. The bond-slip displacement between steel bar and concrete decreases slightly. The finite element simulations have been carried out by using ANSYS, and the results indicate that the seismic performance of piers with only increasing the number of steel bars (less than65%) in the plastic hinge zone can be basically equivalent to that of piers that the number of steel bars in all sections is the same as that in plastic hinge zone.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3495-3501
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• 2014

A novel crystal, the mono-protonated metformin acetate (1), was obtained and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. It was found that one of the imino group in the metformin cation was protonated along with the proton transfer from the secondary amino group to the other imino group. Its crystal structure was then compared with the previously reported diprotonated metformin oxalate (2). The difference between them is that the mono-protonated metformin cations can be linked by hydrogen bonding to form dimers while the diprotonated metformin cations cannot. Both of them are stabilized by intermolecular hydrogen bonds to assemble a 3-D supermolecular structure. The four potential tautomer of the mono-protonated metformin cation (tautomers 1a, 1b, 1c and 1d) were optimized and their single point energies were calculated by Density Functional Theory (DFT) B3LYP method based on the Polarized Continuum Model (PCM) in water, which shows that the most likely existed tautomer in human cells is the same in the crystal structure. Based on the optimized structure, their Wiberg bond orders, Natural Population Analysis (NPA) atomic charges, molecular electrostatic potential (MEP) maps were calculated to analyze their electronic structures, which were then compared with the corresponding values of the diprotonated metformin cation (cation 2) and the neutral metformin (compound 3). Finally, the possible tautomeric mechanism of the mono-protonated metformin cation was discussed based on the observed phenomena.

• Journal of Korean Tunnelling and Underground Space Association
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• v.7 no.4
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• pp.305-311
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• 2005

Shotcrete adhesive strength in large section tunnels in jointed rock masses plays an important role in preventing rock block from falling and shotcrete debonding due to blasting vibration. Nevertheless, it has not been considered as a major factor such as shotcrete compressive strength in design and construction. For this reason, the purpose of this study is to analyze the effect on shotcrete adhesive strength for large-sectioned tunnels. First, the parametric study using numerical model similar to Holmgren's punch-loaded test was executed for various range of adhesive strength. It shows that the shotcrete bearing capacity is linearly proportioned to the adhesive strength between shotcrete layer and blocks. And then, distinct element analysis of a jointed rock tunnel for an adhesive strength of 1 MPa and a conventional fully-bonded condition between the shotcrete layer and the excavation face was compared in order to evaluate the effect of the shotcrete adhesive strength.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.19 no.1
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• pp.45-51
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• 1986

Equimolar aqueous solutions of D-glucose and glycine were heated at $50^{\circ}C\;and\;95^{\circ}C$ at pH 6.7. The headspace volatiles and the ether extracts from the reaction mixture were analyzed by gas chromatography and gas chromatography-mass spectrometry using a fused silica capillary column. The major components formed were identified as diacetyl, three furfurals, two pyrroles, one furanone, two pyranones and two amides. In order to elucidate the formation mechanisms of the amides formed front amino-carbonyl reaction, two model systems were adopted. N-butylacetamide were formed as major components from diacetyl-butylamine ana glyoxal-butylamine systems, respectively. The results obtained suggest that such ${\alpha}-dicarbonyls$ as 3-deoxy-D-erythro-2,3-hexodiulose and diacetyl generated in the amino-carbonyl reaction react with amino compounds, amides then being formed by cleavage of the C-C bond in the ${\alpha}-dicarbonyls$.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 1999.11b
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• pp.204-208
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• 1999

Friction was measured on filter paper sheets impregnated with model compounds representing wood extractives using an apparatus based on the horizontal plane principle. The best lubrication of paper surfaces was achieved when they were completely separated by a densely packed film of saturated long-chain amphophilic molecules, such as fatty acids. The fatty acids adsorbed with their polar ends on the paper surface, causing their hydrocarbon chaine to be orientated perpendicularly to the paper surface. The saturated C18-acid, stearic acid, was an efficient lubricator for paper surfaces. The introduction of a double bond in stearic acid eliminated its lubricating ability. The spatial length of the lubricating fatty acid thereby decreases from 24${\AA}$ to 11${\AA}$. However the transisomer of oleic acid, elidic acid, had the ability to lower friction due to an increased spatial length of the fatty acid. Both the spatial length of the hydrocarbon chain and the number of lubricating chains may be of importance for the paper-to-paper friction caused by wood extractives. A hydrophilic head-graup in the wood extractive and an ordered molecular layer of lubricating molecules seems also to be prerequisites for efficient lubrication. A chemical weak boundary layer between the paper sheets was suggested to cause the low friction when long chain saturated fatty acids were deposited on paper.

• Analytical Science and Technology
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• v.6 no.1
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• pp.39-45
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• 1993

We have examined Raman spectra of cis-peptide model complex, diketopiperazine in water and $D_2O$ with 320 nm through 218 nm excitation. Our study examines assignment of the resonance enhanced amide vibrations and characterizes their enhancement mechanism. Three resonance enhaned cis-peptide marker bands were observed in aqueous solution at 1676, 1533 and $806cm^{-1}$, which were assigned to the cis-amide I, II and S band, respectively. The $1533cm^{-1}$ amide II band, which is almost pure C-N stretching, was most dominant in water and shifted to $1520cm^{-1}$ upon N-deuteration. This band will be probably a potential probe band for cis-peptide moieties in proteins. The excitation profile data and an Albrecht A-term fit indicated that the cis-peptide vibrations derive their intensities from the 188 nm cis-peptide ${\pi}-{\pi}^*$ electronic transition. We Propose that the geometry of cis-peptide ${\pi}^*$ excited state is C-N bond displacement relative to that of electronic ground state.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3333-3340
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• 2010

A three dimensional pharmacophore model was generated for the molecules which are responsible for anti-inflammatory activities targeting Interleukin-2 inducible tyrosine kinase (Itk). 16 structurally diverse molecules were selected as training set to generate the hypotheses using Discovery Studio v2.1. The best hypothesis, Hypo1, comprises two hydrogen bond acceptor (HBA), one hydrophobic aromatic (HA), one ring aromatic (RA) and shows high cost difference (63.71), high correlation coefficient (0.97) as well as low RMS deviation (0.81). Hypo1 has been further validated toward a test set, decoy set and Fischer's randomization method. Furthermore, Hypo1 was used to screen NCI and Maybridge databases. Finally, 2 hit molecules were identified as potential leads against Itk, which may be useful for future drug development.

• Asian Journal of Atmospheric Environment
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• v.2 no.1
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• pp.34-46
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• 2008

Emissions inputs for use in air quality modeling of Korea were generated with the emissions inventory data from the National Institute of Environmental Research (NIER), maintained under the Clean Air Policy Support System (CAPSS) database. Source Classification Codes (SCC) in the Korea emissions inventory were adapted to use with the U.S. EPA's Sparse Matrix Operator Kernel Emissions (SMOKE) by finding the best-matching SMOKE default SCCs for the chemical speciation and temporal allocation. A set of 19 surrogate spatial allocation factors for South Korea were developed utilizing the Multi-scale Integrated Modeling System (MIMS) Spatial Allocator and Korean GIS databases. The mobile and area source emissions data, after temporal allocation, show typical sinusoidal diurnal variations with high peaks during daytime, while point source emissions show weak diurnal variations. The model-ready emissions are speciated for the carbon bond version 4 (CB-4) chemical mechanism. Volatile organic carbon (VOC) emissions from painting related industries in area source category significantly contribute to TOL (Toluene) and XYL (Xylene) emissions. ETH (Ethylene) emissions are largely contributed from point industrial incineration facilities and various mobile sources. On the other hand, a large portion of OLE (Olefin) emissions are speciated from mobile sources in addition to those contributed by the polypropylene industry in point source. It was found that FORM (Formaldehyde) is mostly emitted from petroleum industry and heavy duty diesel vehicles. Chemical speciation of PM2.5 emissions shows that PEC (primary fine elemental carbon) and POA (primary fine organic aerosol) are the most abundant species from diesel and gasoline vehicles. To reduce uncertainties in processing the Korea emission inventory due to the mapping of Korean SCCs to those of U.S., it would be practical to develop and use domestic source profiles for the top 10 SCCs for area and point sources and top 5 SCCs for on-road mobile sources when VOC emissions from the sources are more than 90% of the total.