• Korean Journal of Food Science and Technology
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• v.36 no.3
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• pp.398-402
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• 2004

Safrolechitosan (SaCs) and eugenolchitosan (EuCs) were synthesized and characterized to increase water solubility and functionality of chitosan. Product impurities were removed by Soxhlet apparatus using methanol to obtain final product with high purity. Using Ubbelohde viscometer, molecular weights of chitosan, EuCs, and SaCs were determined as $1.2{\times}10^{5}\;Da,\;7.8{\times}10^{5},\;and\;7.5{\times}10^{5}\;Da,\;respectively$. IR spectrum of SaCs revealed chemical shift of amide II band ($1,553cm^{-1}$) of chitosan grafted by safrole caused by generation of covalent bond between primary amino of chitosan and double bond of safrole. Due to graft reaction of safrole onto chitosan, vinyl bands ($1,611\;and\;1,442cm^{-1}$) of safrole disappeared. In graft reaction of eugenol onto chitosan, shift of amide II band ($1,553cm^{-1}$) and disappearance of vinyl band were observed. On $^{1}H-NMR$ spectrum of EuCs, $H_{2}C=CH-$ peak in eugenol (monomer) disappeared, whereas $-H_{2}C-CH_{2}-$ peak appeared. Above results indicate safrole and eugenol were successfully grafted onto chitosan.

• Polymer(Korea)
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• v.30 no.3
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• pp.271-278
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• 2006

In order to investigate the structure and dynamics of atatic poly (vinyl alcohol) (PVA)/water system, laser light scattering experiment has been done in the semi-dilute concentration regime at $25^{\circ}C$. The scattering intensity I(q) can be analyzed with the fractal equation of $I(q){\sim}q^{-m}$ instead of Onstein-Zernike type equation. The fractal dimensionality m was found to be constant after reaching the plateau value of $m=2.6{\pm}0.3$ above C=3wt%. The time correlation function of dynamic light scattering has always two different modes such as fast mode and slow one. The cooperative diffusion of fast mode showed concentration independence contrary 4o the reptation theory's concentration dependent exponent of 3/4. The slow mode can be interpreted as the motion of large scale heterogeneities and its strong concentration dependence is apparent with a large negative exponent of -3.0. It is considered that the stereo-regular arrangement with four successive meso units of -OH plays as a key role in forming such heterogeneity.

• Polymer(Korea)
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• v.33 no.5
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• pp.501-508
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• 2009

The thermal degradation experiment of sodium salt of poly (${\gamma}$-glutamic acid) (PGGNa) has been carried out in both its solid phase and solution phase at the range of $57{\sim}120^{\circ}C$ and their molecular weight decreasing effect was analyzed as a function of time by means of viscometry and light scattering. Based on the solid phase degradation results, it was supposed that the bond scission rate in a polymer chain kept constant and that the bond scission was occurred on a randomly located position in a polymer chain. For the degradation in solution phase, it was also found that all data at various temperatures were dropped on a single master curve when the reduced time $t/t^*$ was used in the plot of the reciprocal intrinsic viscosity (or molecular weight). This degradation curve in solution phase could be expressed as the sum of a single exponential and a linear equation and especially, the single exponential character appeared only at the beginning stage. The activation energy was measured as $107{\sim}115$ kJ/mol in this study and agreed with the literature values.

• Journal of the Korean Chemical Society
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• v.25 no.2
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• pp.110-118
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• 1981

Kinetics and mechanism for the reaction of substituted phenacyl bromides with substituted pyridines have been determined at 25, 35 and $45^{\circ}C$ in methanol and dimethylformamide by the conductivity method. The rate constants for the reaction of various pyridines with phenacyl bromide shown that electron-donating substituents in the pyridine increase the rate, while electron-attracting one decrease in both solvents. The effect of substituents in substrate, the rate being increased by electron-attracting substituents. This is as expected for nucleophilic attack of amines on the carbon atom. Isokinetic and $Br{\psi}nsted$ linear relationship were shown in the reaction of phenacyl bromide with pyridines in both solvent in which isokinetic temperature were obtained 614, $202^{\circ}K$ and ${\beta}$ values were 0.29, 0.36 in methanol and dimethylformamide respectively. In the case of the reaction of substituted phenacyl bromide with pyridines, isokinetic temperature decreases with increasing electron-attracting ability of the substituents in the phenacyl bromide, while the ${\beta}$ values were reverse. From the above results, it can be inferred that N…C bond formation decreases progressively from p-chloro- to p-methoxyphenacyl bromide and the bond formation predominates in DMF than methanol. The ${\rho}$ values of Hammett equation of the reaction of phenacyl bromide with substituted pyridines are negative in both solvent, but its value was larger negative in DMF than methanol and the ${\rho}$ value of that of substitutted substrates with pyridine was 0.3, the low value is ascribed to direct $S_N2$ attack of the nitrogen atom in pyridine ring at the methylene carbon.

• Informatization Policy
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• v.26 no.2
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• pp.46-61
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• 2019

This study constructs an integrated model for university students' smart phone cyber bullying and tests interaction effects between causal and control factors. Causal factors include low self-control, differential association with cyber bullying peers, and victimization experiences; and control factors include internet ethics, perceived certainty of formal punishment, and bond to parents. This study focuses on examining how internet ethics buffers the effect of causal factors in cyber bullying. Results show that both differential association with cyber bullying peers and victimization experiences have significant effects on cyber bullying. And among the control factors, internet ethics only has a negative direct effect on cyber bullying. In addition, it is found that there are significant interaction effects between two causal factors - differential association with cyber bullying peers and victimization experiences - and internet ethics. It is also shown that there is a significant interaction effect between victimization experience and bond to parents, but a perceived formal punishment has no significant control effect. It is revealed that internet ethics is a main control factor in buffering the effects of causal factors in cyber bullying.

• Journal of the East Asian Society of Dietary Life
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• v.23 no.4
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• pp.470-476
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• 2013

The property of deep frying oil is one of the important factors in fried food quality. The purpose of this study is to identify the quality of deep frying oil in continuous usages for 4 days by two types of fryers: traditional deep-fat fryer and modified oil-water fryer. After frying pork cutlets, the frying oil was kept not only for several physical analyses such as color, viscosity, and water content but also for the quality analyses of frying oil, such as free fatty acid, double bond changes and oxidative rancidity formation. The oil fried in a traditional deep-fat fryer was significantly increased in terms of physical values including moisture content, viscosity, and color, compared to those of the modified fryer, continuously for 4 days. The oil fried by a traditional deep-fat fryer exhibited a significant increase in its free fatty acid content compared to that fried by a modified oil-water fryer, while the iodine value was significantly decreased in the oil fried by a traditional deep-fat fryer when compared to control oil and oil fried by the modified oil-water fryer. In the peroxide value as an indicator of primary oxidation products, the oil fried by both fryers was significantly increased till the second day but decreased in value after the third day because of unstable hydroperoxide decomposition. The p-anicidine value is used as an indicator of secondary oxidation products, the oil fried in a traditional deep-fat fryer was significantly increased in value compared to that of a modified oil-water fryer.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.6
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• pp.707-714
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• 2015

In this paper, an experimental program has been conducted to investigate transfer length in high strength concrete members pretensioned through a seven-wire strand with FBG sensors. To measure transfer length, five members were fabricated, which had a length of 3 m and a cross-section of $150{\times}150mm$. It was measured that the concrete compressive strength was 58MPa at pretensioning. Test results indicated that more precise and reliable measurement on the transfer length was attained with FBG sensors than conventional gauges attached on concrete surface. Through comparing the measured transfer length and predictions, applicability of several transfer length models in literature was investigated. This paper can be useful for relevant research field such as investigation on the bond mechanism of a seven-wire strand in concrete members.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.23 no.2
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• pp.34-34
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• 1987

Friction welding has emerged as a reliable process for high-production commercial application with significant economic and technical advantages. But nondestructive test in friction weld was not clearly developed. Therefore the experimental verification is necessary in order to understand the characteristics of the pulse echo effects according to various change in welding conditions. This paper presents a new attempt to detect the bond strength of friction welds by ultrasonic. Instead of looking for a flaw or cracks at the interface, the new approach evaluates the coefficient by reflection which provides a single quantitative indicator involving the acoustic energy reflected at the interface. The objective of this study is to find the relationship between the reflection coefficients and the weld strength. Results of the bar-to-bar friction welding of aluminum to copper and stainless steel and such relationship investigation are presented and interpreted.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.23 no.2
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• pp.80-85
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• 1987

Friction welding has emerged as a reliable process for high-production commercial application with significant economic and technical advantages. But nondestructive test in friction weld was not clearly developed. Therefore the experimental verification is necessary in order to understand the characteristics of the pulse echo effects according to various change in welding conditions. This paper presents a new attempt to detect the bond strength of friction welds by ultrasonic. Instead of looking for a flaw or cracks at the interface, the new approach evaluates the coefficient by reflection which provides a single quantitative indicator involving the acoustic energy reflected at the interface. The objective of this study is to find the relationship between the reflection coefficients and the weld strength. Results of the bar-to-bar friction welding of aluminum to copper and stainless steel and such relationship investigation are presented and interpreted.

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.832-842
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• 1996

TAME synthesis was studied in a fixed bed reactor with 3 different types of exchanged resins i.e, Amberlyst-15, Amberlyst-15(wet) and Amberlyst XN-1010. Amberlyst-15 has highest activity, presumably due to the higher reaction participation of the inner active sites of gel shape microparticular resin structure. The optimum reaction conditions for TAME synthesis were found as follows ; reaction temperature of $135^{\circ}C$, molar ratio(MeOH/I.A.A) of 1.0~4.0 and W/F of 2.0~4.0 gr.-cat. hr/gr.-mole. The cross-linking bond of styrene divinyl benzene was observed at $2{\theta}=20$ in XRD pattern. The DSC analysis showed that the thermal stability was in order of Amberlyst-15>Amberlyst-15(wet)>Amberlyst XN-1010. The apparent activation energies of TAME synthesis reaction with Amberlyst-15, Amberlyst-15(wet) and Amberlyst XN-1010 were 12.36, 12.46 and 14.72 kcal/mole, respectively.