• Journal of the Korea Concrete Institute
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• v.28 no.6
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• pp.723-731
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• 2016

In pretensioned concrete members, a certain bond length from the end of the member is required to secure the effective prestress in the strands, which is defined as the transfer length. However, due to the complex bond mechanism between strands and concrete, most transfer length models based on the deterministic approach have uncertainties and do not provide accurate estimations. Therefore, in this study, Adaptive Neuro-Fuzzy Inference System (ANFIS), a Neuro-Fuzzy System, is introduced to reduce the uncertainties and to estimate the transfer length more accurately in pretensioned concrete member. A total of 253 transfer length test results have been collected from literatures to train ANFIS, and the trained ANFIS algorithm estimated the transfer length very accurately. In addition, a design equation was proposed to calculate the transfer length based on parametric studies and dimensional analyses. Consequently, the proposed equation provided accurate results on the transfer length which are comparable to the ANFIS analysis results.

• Journal of the Korean Chemical Society
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• v.32 no.3
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• pp.260-266
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• 1988

The rate constants for the nucleophilic addition reactions of thioglycolic acid and cysteine to ${\beta},\;{\beta}$-dichlorostyrene derivatives(p-H, p-Cl, $p-CH_3,\;and\;p-OCH_3$) were photochemically determined at various pH and a rate equation which can be applied over a wide pH range was obtained. On the bases of rate equation, general base catalysis and substituent effect, the plausible addition reaction mechanism was proposed: Above pH 9.0, the reaction was initiated by the addition of sulfide anion, and in the range of pH 7.0 to 9.0, the neutral molecules and it's anions attacked to the double bond, competitively. However, below pH 7.0, only the neutral molecules of thioglycolic acid or cysteine added to the carbon-carbon double bond.

• Journal of the Korean Society of Safety
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• v.5 no.2
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• pp.17-23
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• 1990

This study was performed by experiments with ASTM's apparatus for determination of autoignition temperature to obtain autoignition characteristics of 1-Heptene, 2-Heptene and 3-Heptene, respectively. As results, minimum autoignition temperatures (MAIT) of 1-Heptene, 2-Heptene and 3-Heptene were 246$^{\circ}C$, 248$^{\circ}C$ and 254$^{\circ}C$, respectively and each dropping volume of these temperatures was 0.25$m\ell$, 0.20$m\ell$ and 0.20$m\ell$. Instantaneous ignition temperatures measured at each dropping volume of Heptene were 371$^{\circ}C$, 357$^{\circ}C$ and 342$^{\circ}C$, respectively. Relation ignition delay time with ignition temperature at minimum autoignition temperature agreed well with Semenov's equation, and the values of apparent activation energy from this equation were 47Kca1/mo1 for 1-Heptene, 35Kca1/mo1 for 2-Heptene and 29Kca1/mo1 for 3-Heptene. It was found that the values of apparent activation energy decreased as the position of double bond changed from end to center in C-C chain.

• Bulletin of the Korean Chemical Society
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• v.6 no.4
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• pp.191-196
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• 1985

The MNDO was found to be the most reliable semi-empirical SCF-MO method for the studies of $S_N2$ reactions involving anion and neutral molecule. The results of our MNDO calculations on the $S_N2$ reactions of $CH_3X$ + $Y^-$ → $CH_3Y$ + X- where X = H, F, Cl, CN, $CH_3$, and Y = F, $CH_3$ showed that the order of the leaving group ability is the reverse of the order of proton affinities. It was also found that there is no symbiosis involved in the SN2 transition state and the departure of the leaving group is relatively late in contrast to the early bond formation of the nucleophile. The Marcus equation was found to apply to the MNDO barriers and energy changes.

• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.156-162
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• 1975

Rates of reactions of methanesulfonyl chloride with various substituted anilines have been measured in methanol. Substituent effects in aniline are found to be linearly correlated with pKa(Bronsted relation with ${\beta}$ = 0.84) and ${\rho}$(Hammett equation with ${\rho}$ = -2.46) respectively. The results are interpreted in terms of degree of bond-formation at the transition state, which was found to have progressed relatively further. The rates for o-methylaniline deviated from the Bronsted plot established by meta and para substituted anilines because of a steric effect of ortho position in aniline. Activation parameters, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ have also been determined. The enthalpy of activation showed a regular variation in that electron donating substituents in the p-substituted aniline decrease ${\Delta}H^{\neq}$ and increase the negative value of ${\Delta}S^{\neq}$.

• Bulletin of the Korean Chemical Society
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• v.21 no.7
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• pp.720-726
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• 2000

The analytic gradient method for the equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) energy has been extended to employ a reduced molecular orbital (MO) space. Not only the innermost core MOs but also some of the outermost virtua l MOs can be dropped in the reduced MO space, and a substantial amount of computation time can be reduced without deteriorating the results. In order to study the magnitudes and trends of the effects of the dropped MOs, the geometries and vibrational properties of the ground and excited states of BF, CO, CN, N2, AlCl, SiS, P2, BCl, AIF, CS, SiO, PN and GeSe are calculated with different sizes of molecular orbital space. The 6-31 G* and the aug-cc-pVTZ basis sets are employed for all molecules except GeSc for which the 6-311 G* and the TZV+f basis sets are used. It is shown that the magnitudes of the drop-MO effects are about $0.005\AA$ in bond lengths and about 1% on harmonic frequencies and IR intensities provided that the dropped MOs correspond to (1s), (1s,2s,2p), an (1s,2s,2p,3s,3p) atomic orbitals of the first, the second, and the third row atoms, respectively. The geometries and vibrational properties of the first and the second excited states of HCN and HNC are calculated by using a drastically reduced virtual MO space as well as with the well defined frozen core MO space. The results suggest the possibility of using a very smalI MO space for qualitative study of valence excited states.

• Journal of the Korean Chemical Society
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• v.26 no.6
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• pp.407-413
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• 1982

The rate constants of the nucleophilic addition of cysteine to 3,4-methylenedioxyphenylmethylene malononitrile were determined by UV Spectrophotometry and a rate equation which can be applied over wide pH range was obtained. On the basis of rate equation, it may be concluded that the rate constants were dependent upon only the concentration of hydroxide ion above pH 9.0, however, below pH 6.0, the reaction were initiated by the addition of neutral cysteine molecule to carbon-carbon double bond and at pH 7.0~9.0, the addition of a neutral cysteine molecule and it's anion occurred competitively.

• Journal of the Korean Applied Science and Technology
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• v.9 no.2
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• pp.119-126
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• 1992

The kinetics of the hydrolysis of indolylacrylophenone derivatives(IA) was investigated by ultraviolet spectrophotometry in 30% dioxane-$H_2O$ at 25$^{\circ}C$ Rate equations were obtained over a wide pH range. On the basis of rate equation, general base catalysis and Hammett's plot, the mechanism of hydrolysis to the (IA) were proposed: Below pH 3.0, the hydrolysis of (IA) was proportional to hydronium ion concentration, between pH 4.0${\sim}$9.0 neutral water molecule and hydroxide ion were added to carbon-carbon double bond and over pH 10.0 hydrolysis of (IA) was proportional to hydroxide ion concentration.

• Journal of the Korean Society of Clothing and Textiles
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• v.40 no.6
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• pp.1010-1024
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• 2016

This study identifies the influence of on/off-line acquaintances' recommendation messages on fashion product attitude and purchase intention on the online purchase of fashion products in two-sided word of mouth situations as well as compares the difference in influence according to bond-base with equidistance. This study was conducted for one month on university students in their 20s who were believed to be active in smartphone use. Out of the collected 174 copies of the questionnaire, 162 copies were used for analysis. The questionnaire was classified into online and offline recommendation messages of an acquaintance. We present two-sided fashion product reviews made similar to the type found in an actual shopping mall web-site. As for analysis, confirmatory factory analysis, structural equation modeling, and multi-group analysis were conducted using AMOS 19.0. The analysis results are as follows. First, on/off-line acquaintances' recommendation messages had significant influences on product attitude in the situation where two-sided reviews on fashion products were presented; however, those messages did not influence purchase intention. Recommendation messages positively increased product attitude and enhanced purchase intention if acquaintances' recommendation messages were mediated between on/off-line acquaintances' recommendation messages and purchase intention. Consequently, a mediating effect on product attitude was revealed. Second, there was no difference between online acquaintances and offline acquaintances in terms of the influence of acquaintances' recommendation messages on product attitude and purchase intention, in the situation where two-sided reviews were presented on online fashion products. Therefore, no control effect according to the type of acquaintance was confirmed.

• Journal of the Korea Concrete Institute
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• v.15 no.1
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• pp.102-109
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• 2003

The grouted splice steeve has been applied widely due to its superior construction efficiency, such as the unnecessity of post concrete and the large allowable limit to the arrangement of reinforcing bars. However, studies on grout-filled splice steeve still have not been sufficiently peformed. The purpose of this study is to investigate the confining effect of mortar grouted splice sleeve on reinforcing bar, known to strengthen the bond capacity between grout mortar and reinforcing bar. To accomplish this objective, totally 6 full-sized specimens were made and tested under monotonic loading. Each specimens were equipped with strain gauges at the 12 location of sleeve and reinforcing bar. The experimental variables adopted in this study are embedment length and size of reinforcing bars. Following conclusions are obtained; 1) Under ultimate strength condition, the confining pressure of grouted splice sleeve calculated from measured tangential and axial strain of the sleeve is over $200{\sim}300kgf/{cm}^2$ at any location of sleeve and improved with reduction in embedment length of reinforcing bar. 2) Untrauer and Henry's equation which describe bond strength of mortar as a function of its compressive strength and confining pressure, predicted the measured bond capacity of this test within the 5% limits.