• Title/Summary/Keyword: Blue and white emission

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Effects of hydration structure on the femtosecond white light-induced phase transition to crystalline silicon nanocrystal having ultrabright narrowed luminescence

  • Choi, Kyong-Hoon;Wang, Kang-Kyun;Ha, Jeong-Hyon;Kim, Yong-Rok
    • Rapid Communication in Photoscience
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    • v.4 no.3
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    • pp.54-58
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    • 2015
  • Under the condition of femtosecond impulsive nonlinear optical irradiation, the bright and narrowed blue emission of silicon nanocrystal was observed. This synthetic method produced very small (~ 4 nm) oxide-capped silicon nanocrystal having probably ultra small emitting core (~ 1 nm) inferred from luminescence. By controlling the stirring condition, very high efficiencies of luminescence ( 4 fold higher) were obtained compared with the other conventional femtosecond laser fragmentation methods, which was attributed to the differences in hydration shell structure during the femtosecond laser induced irreversible phase transition reaction. When we properly adjusted the irradiation times of the white light continuum and stirring condition, very homogeneous luminescent silicon nanocrystal bands having relatively sharp lineshape were obtained, which can be attributable to the luminescent core site isolated and free from the surface defects.

Synthesis of Lu3Al5O12:Ce3+ Nano Phosphor by Coprecipitation Method, and Their Optical Properties (공침법을 이용한 Lu3Al5O12:Ce3+ 나노 형광체 합성과 광학적 특성 분석)

  • Kang, Taewook;Kang, Hyeonwoo;Kim, Jongsu;Kim, Gwangchul
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.4
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    • pp.51-56
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    • 2019
  • LuAG:Ce(Lu3Al5O12:Ce3+) nano phosphor were synthesized by applying the coprecipitation method. It is used to increase the color rendering of phosphor ceramic plate for high power LEDs and laser lighting. Internal quantum efficiency and absorption of LuAG:Ce nano phosphor are 51.5 % and 64.4 %, respectively, which is higher than the previously studied nano phosphors. The maximum absorption wavelength of this phosphor is 450 nm blue light, and the emission wavelength is 510 nm. The emission wavelength shifted to longer wavelength when the concentration of Ce increased in the heat treatment of the reducing atmosphere. Thermal quenching of LuAG nano phosphor was 70 % at 200 ℃, it was explained by their significant quenching of all raman scattering modes, implying the restriction of electron-phonon couplings caused by their defects.

POLARIZATION OF $H_{\alpha}$ WINGS RAMAN-SCATTERED IN SYMBIOTIC STARS (공생별에서의 $H_{\alpha}$날개의 편광연구)

  • BAK JIH-YONG;LEE HEE-WON
    • Publications of The Korean Astronomical Society
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    • v.15 no.spc1
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    • pp.147-151
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    • 2000
  • Symbiotic stars, believed to be binary systems of a mass-losing giant and a white dwarf with an emission nebula, are known to exhibit very broad wings around Hex that extend to $\~10^3km\;s^{-1}$. The wing formation mechanism is not a settled matter and recently Lee (2000) proposed that Raman scattering of Ly$\beta$ by neutral hydrogen is responsible for the broad H$\alpha$ wings. In this model, it is predicted that. the Hex wings will be polarized depending on the geometric and kinematic distribution of the scatterers relative to the UV emission region. In this paper, we investigate the polarization of Hex wings in symbiotic stars. Noting that many symbiotic stars possess bipolar nebular morphology, we assume that the distribution of neutral scatterers follows the similar pattern with a receding velocity of several tens of km $s^{-1}$ that mimics the expansion of the neutral envelope of the nebula. It is found that the red wing is more strongly polarized than the blue and main part and that the polarization direction is along the equatorial plane. We obtain a typical degree of polarization $\~10$ percent, however, it varies depending on the detailed distribution of H I scatterers We conclude that spectropolarimetry will provide very important information on the origin of the Hex wings.

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Resonant inelastic X-ray scattering of tantalum double perovskite structures

  • Oh, Ju Hyun;Kim, Jung Ho;Jeong, Jung Hyun;Chang, Seo Hyoung
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1225-1229
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    • 2018
  • In this paper, we investigated the electronic structures and defect states of $SrLaMgTaO_6$ (SLMTO) double perovskite structures by using resonant inelastic x-ray scattering. Recently, $Eu^{3+}$ doped SLMTO red phosphors have been vigorously investigated due to their higher red emission efficiency compared to commercial white light emitting diodes (W-LED). However, a comprehensive understanding on the electronic structures and defect states of host SLMTO compounds, which are specifically related to the W-LED and photoluminescence (PL), is far from complete. Here, we found that the PL spectra of SLMTO powder compounds sintered at a higher temperature, $1400^{\circ}C$, were weaker in the blue emission regions (at around 400 nm) and became enhanced in near infrared (NIR) regions compared to those sintered at $1200^{\circ}C$. To elucidate the difference of the PL spectra, we performed resonant inelastic x-ray spectroscopy (RIXS) at Ta L-edge. Our RIXS result implies that the microscopic origin of different PL spectra is not relevant to the Ta-related defects and oxygen vacancies.

Analysis of Charcoal from Quercus phillyraeoides (졸가시나무 탄화물 분석)

  • Shin, Soo-Jeong;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.3
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    • pp.181-186
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    • 2013
  • In this work, charcoal making characteristics of Quercus phyllyaeoides (which has been known as one of best raw materials for charcoals) was investigated. Charcoal from Quercus phyllyaeoides had more than 85% of fixed carbon, which is 5~25% higher fixed carbon content than other charcoals. Also specific gravity of this charcoal was more than 1.0, which is quite higher than other black charcoals (average of commercial products: 0.52) or white charcoals (average of commercial products: 0.73). Methylene blue adsorption, pH, and adsorption of water vapour was lower than other commercial charcoals. Carolic value of this charcoal was similar to other commercial products. Far infrared ray's emission from this charcoal was higher than others. Application of charcoal from Quercus phyllyaeoides should be consider the characteristics of this product.

Synthesis and photoluminescence of Ca3Si3O8F2: Ce4+, Eu3+, Tb3+ phosphor

  • Suresh, K.;PoornachandraRao, Nannapaneni V.;Murthy, K.V.R.
    • Advances in materials Research
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    • v.3 no.4
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    • pp.227-232
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    • 2014
  • $Ce^{4+}$, $Eu^{3+}$, $Tb^{3+}$ co-doped $Ca_3Si_3O_8F_2$ phosphor was synthesized via solid state reaction method using $CaF_2$, $CaCO_3$ and $SiO_2$ as raw materials for the host and $Eu_2O_3$, $CeO_2$, and $Tb_4O_7$ as activators. The luminescent properties of the phosphor was analysed by spectrofluorophotometer at room temperature. The effect of excitation wavelengths on the luminescent properties of the phosphor i.e. under near-ultraviolet (nUV) and visible excitations was investigated. The emission peaks of $Ce^{4+}$, $Eu^{3+}$, $Tb^{3+}$ co-doped $Ca_3Si_3O_8F_2$ phosphor lays at 480(blue band), 550(green band) and 611nm (red band) under 380nm excitation wavelength, attributed to the $Ce^{4+}$ ion, $Tb^{3+}$ ion and $Eu^{3+}$ ions respectively. The results reveal that the phosphor emits white light upon nUV (380nm) / visible (465nm) illumination, and a red light upon 395nm / 535nm illumination. RE ions doped $Ca_3Si_3O_8F_2$ is a promising white light phosphor for LEDs. The emission colours can be seen using Commission international de l'eclairage (CIE) co-ordinates. A single host phosphor emitting different colours under different excitations indicates that it is a potential phosphor having applications in many fields.

Analysis of the spectral characteristics of white light-emitting diodes under various thermal environments

  • Jeong, Su-Seong;Ko, Jae-Hyeon
    • Journal of Information Display
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    • v.13 no.1
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    • pp.37-42
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    • 2012
  • An empirical functional form was suggested for the analysis of the emission spectrum of high-power light-emitting diode (LED) consisting of a sharp blue peak from the LED chips and a broad yellow peak from the phosphor layer. The peak positions, half widths, shape parameters, and amplitudes of these two peaks were reliably obtained as a function of the temperature, and the results were discussed qualitatively in relation with the junction temperature. The adoption of an inert liquid was found to have significantly reduced the LED temperature and the color shift of the emitted light. The phenomenological approach used in this study may be helpful in the simulation of the LED spectrum under various thermal conditions, and may thus be helpful in the improvement of the device performance.

Electrical and Optical Properties of Organic Light Emission Devices using Selective Doping in a Single Host (단일 호스트를 이용하여 선택적으로 도핑된 OLEDs의 전기 및 광학적 특성)

  • Seo, Yu-Seok;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.2
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    • pp.124-127
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    • 2010
  • We have fabricated organic white light emitting device by two colors from yellow fluorescence material (5,6,11,12)-Tetraphenylnaphthacene(Rubrene) and blue phosphorescent material (iridum-bis(4,6-difluorophenylpyridinato-N,C2)-picolinate(FIrpic). The threshold voltage is 5.3 V, and the brightness reaches 1000 cd/$m^2$ at 11 V, 14.5 mA/$m^2$. The color of the light corresponds to a CIE coordinate of (0.30, 0.38). The highest efficiency of the device can reach 9.5 cd/A or 5.5 lm/W at 6 V, 0.1 mA/$m^2$.

Preparation and Luminescence Properties of Spherical Sr4Al14O25:Eu2+ Phosphor Particles by a Liquid Synthesis (액상법을 이용한 구상의 Sr4Al14O25:Eu2+ 형광체의 합성 및 발광 특성)

  • Lee, Jeong;Choi, Sungho;Nahm, Sahn;Jung, Ha-Kyun
    • Korean Journal of Materials Research
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    • v.24 no.7
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    • pp.351-356
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    • 2014
  • A spherical $Sr_4Al_{14}O_{25}:Eu^{2+}$ phosphor for use in white-light-emitting diodes was synthesized using a liquid-state reaction with two precipitation stages. For the formation of phosphor from a precursor, the calcination temperature was $1,100^{\circ}C$. The particle morphology of the phosphor was changed by controlling the processing conditions. The synthesized phosphor particles were spherical with a narrow size-distribution and had mono-dispersity. Upon excitation at 395 nm, the phosphor exhibited an emission band centered at 497 nm, corresponding to the $4f^65d{\rightarrow}4f^7$ electronic transitions of $Eu^{2+}$. The critical quenching-concentration of $Eu^{2+}$ in the synthesized $Sr_4Al_{14}O_{25}:Eu^{2+}$ phosphor was 5 mol%. A phosphor-converted LED was fabricated by the combination of the optimized spherical phosphor and a near-UV 390 nm LED chip. When this pc-LED was operated under various forward-bias currents at room temperature, the pc-LED exhibited a bright blue-green emission band, and high color-stability against changes in input power. Accordingly, the prepared spherical phosphor appears to be an excellent candidate for white LED applications.

A Study on the Lighting Environment Standard for Museum Exhibition Halls, with a Focus on Color Temperature (박물관 전시 공간 조명 환경 기준 연구(I) - 색온도를 중심으로)

  • Lee, Sungeun;Roh, Hyunsook
    • Conservation Science in Museum
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    • v.18
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    • pp.65-76
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    • 2017
  • Following advances in technology and with the growing need for renewable energy, fluorescent and halogen lamps are being replaced by LED lighting in museum systems. This paper researched the setting of standards for the diverse lighting systems in addition to the LED lighting that are expected to be introduced in museums in the future. Contrary to previous belief, LEDs were shown to only barely emit in the ultraviolet region, but the visible rays were confirmed to produce discoloration depending on illuminance-hours. When the color change by LED lamps at the color temperature of 2800K, or warm white, was compared with 5500K, or white, the emission spectrum analysis confirmed that the blue spike increased at a higher color temperature and caused more discoloration. This suggests that in addition to illumination, color temperature should be considered by including the emission spectrum when museums set lighting environment standards.