• Title/Summary/Keyword: Blocking Layer

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Application of Limestone, Zeolite, and Crushed Concrete as Capping Material for Interrupting Heavy Metal Release from Marine Sediments and Reducing Sediment Oxygen Demand (해양퇴적물에서 중금속 용출 차단 및 퇴적물 산소 요구량 감소를 위한 석회석, 제올라이트 및 폐콘크리트의 피복 소재로서 적용)

  • Kang, Ku;Park, Seong-Jik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.4
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    • pp.31-38
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    • 2015
  • This study aims to assess the effectiveness of limestone, zeolite, and crushed concrete as capping material to block the release of heavy metals (As, Cu, Cr, Ni, and Pb) and reduce the sediment oxygen demand. The efficiency of limestone, zeolite, and crushed concrete was evaluated in a reactor in which a 1-cm thick layer of capping materials was placed on the sediments collected from Inchon north harbor. Dissolved oxygen concentration and heavy metal concentration in seawater above the uncapped sediments and capping material were monitored for 17 days. The sediment oxygen demand was in the following increasing order: crushed concrete ($288.37mg/m^2{\cdot}d$) < zeolite ($428.96mg/m^2{\cdot}d$) < limestone ($904.53mg/m^2{\cdot}d$) < uncapped ($981.34mg/m^2{\cdot}d$). The capping materials could reduce the sediment oxygen demand by blocking the release of biochemical matters consuming dissolved oxygen in seawater. It was also shown that zeolite and crushed concrete could effectively block the release of Cu, Ni, and Pb but those were not effective for the interruption of As and Cr release from marine contaminated sediments.

Optically transparent and electrically conductive indium-tin-oxide nanowires for transparent photodetectors

  • Kim, Hyunki;Park, Wanghee;Ban, Dongkyun;Kim, Hong-Sik;Patel, Malkeshkumar;Yadav, Pankaj;Kim, Joondong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.390.2-390.2
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    • 2016
  • Single crystalline indium-tin-oxide (ITO) nanowires (NWs) were grown by sputtering method. A thin Ni film of 5 nm was coated before ITO sputtering. Thermal treatment forms Ni nanoparticles, which act as templates to diffuse Ni into the sputtered ITO layer to grow single crystalline ITO NWs. Highly optical transparent photoelectric devices were realized by using a transparent metal-oxide semiconductor heterojunction by combining of p-type NiO and n-type ZnO. A functional template of ITO nanowires was applied to this transparent heterojunction device to enlarge the light-reactive surface. The ITO NWs/n-ZnO/p-NiO heterojunction device provided a significant high rectification ratio of 275 with a considerably low reverse saturation current of 0.2 nA. The optical transparency was about 80% for visible wavelengths, however showed an excellent blocking UV light. The nanostructured transparent heterojunction devices were applied for UV photodetectors to show ultra fast photoresponses with a rise time of 8.3 mS and a fall time of 20 ms, respectively. We suggest this transparent and super-performing UV responser can practically applied in transparent electronics and smart window applications.

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Analysis of Heavy Metal Concentration on Working Clothes for Waste Incinerating Workers (생활폐기물 소각장 작업복의 중금속 분석)

  • Park, Soon-Ja
    • The Korean Journal of Community Living Science
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    • v.18 no.1
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    • pp.39-53
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    • 2007
  • The purpose of this study was to determine the characteristics of an experimental protective clothing material with regard to comfort and isolation from the hazardous heavy metals produced in municipal waste incineration. An analysis was conducted on the total concentrations of heavy metals in some parts such as surface, middle layer, and interior for the treated fabric, and the untreated one, and working clothes. We conclude that the processed fabric with charcoal for working clothes showed the least exposure to heavy metals of the three. Working clothes worn by workers during waste incineration were much more contaminated than the untreated and treated materials. The material of working clothes could be chosen according to the function with regard to its original chemical characteristics, which are the proper results of the dyeing process. The processed fabric material has high degrees of moisture regain, thermal insulation, water vapor penetration, and antibacterial function; consequently, it is much more comfortable to wear. The fabric material proposed in this research contributed much more to blocking heavy metal concentrations (such as Cd, Pb, Cu, Cr, Zn, Mn) than did the fabric of working clothes at present. Consequently, we strongly suggest that the material of working clothes be upgraded by adopting the above-mentioned charcoal-processed fabric. Materials of working clothes must be improved to increase comfort and prevent harmful gas, flying dust, and heavy metals from permeating the fabrics.

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Effect on Efficiency of the OLED depending on Thickness Variation of EIL $Cs_2CO_3$ (전자 주입층 $Cs_2CO_3$ 두께 변화에 따른 OLED의 효율에 미치는 영향)

  • Han, Hyeon-Seok;Kim, Chang-Hoon;Kang, Yong-Gil;Kim, Gwi-Yeol;Kim, Tae-Wan;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1438-1439
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    • 2011
  • In this paper, we studied effects on the efficiency, according to thickness of the electron injection layer(EIL) for improving efficiency of Organic Light Emitting Diodes(OLEDs). For the first time, after confirming the optimum thickness of the EIL material $Cs_2CO_3$, we designed OLED devices having a structure of ITO/TPD/$Alq_3/Cs_2CO_3$/Al. And we manufactured devices applying for the optimum thickness of the material in the simulation with thermal evaporating method. And we investigated how the EIL material $Cs_2CO_3$ effects on efficiency of OLEDs in the EIL. As the result, because the EIL material $Cs_2CO_3$ reduces energy potential barrier of the EIL, it facilitated the electron transfer. And, as blocking the hole transfer contributes to an increased recombination, we confirmed that the efficiency of OLEDs increased. And compared to the device without using the EIL material, the device using thickness 1.0 nm of $Cs_2CO_3$ in the EIL shows the excellent efficiency. Therefore, we confirmed that the luminance and the external quantum efficiency increase about 600% and 500% respectively.

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Etching Characteristics of ZnO Thin Films Using Inductively Coupled Plasma of HBr/Ar/CHF3 Gas Mixtures (HBr/Ar/CHF3 혼합가스를 이용한 ZnO 박막의 유도결합 플라즈마 식각)

  • Kim, Moon-Keun;Ham, Young-Hyun;Kwon, Kwang-Ho;Lee, Hyun-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.915-918
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    • 2010
  • In this work, the etching characteristics of ZnO thin films were investigated using an inductively coupled plasma(ICP) of HBr/Ar/$CHF_3$ gas mixtures. The plasma characteristics were analyzed by a quadrupole mass spectrometer (QMS) and double langmuir probe (DLP). The surface reaction of the ZnO thin films was investigated using X-ray photoelectron spectroscopy (XPS). The etch rate of ZnO was measured as a function of the $CHF_3$ mixing ratio in the range of 0-15% in an HBr:Ar=5:2 plasma at a fixed gas pressure (6mTorr), input power (700 W), bias power (200 W) and total gas flow rate(50sccm). The etch rate of the ZnO films decreased with increasing $CHF_3$ fraction due to the etch-blocking polymer layer formation.

A study on the improvement in the efficiency of blue phosphorescent organic light-emitting diodes (청색 인광물질을 이용한 유기 발광 다이오드의 효율개선에 관한 연구)

  • Yang, Mi-Youn;Kim, Jun-Ho;Ha, Yun-Kung;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1070-1073
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    • 2004
  • In this study, Tri(1-phenylpyrazolato)iridium $(Ir(ppz)_3)$ was prepared for the pure blue phosphorescent dopant and various host materials were used for the appropriate energy alignment. Although the luminance was pure blue with the CIE coordinates of x = 0.158, y = 0.139, device efficiencies didn't improve yet. Instead of finding the proper host materials, the alteration of structure of OLEDs affected the improvement of electrical and optical characteristics of the devices. It was worthy that insertion the exciton formation zone with the host material between the emitting zone and the exciton blocking layer. The device with a structure of ITO/NPB/Ir(ppz)3 doped in CBP/CBP for the exciton formation zone/BCP/Liq/Al was fabricated and the characteristics were observed compared with the devices without the exciton formation zone. When CBP was used for the exciton formation zone, the device efficiency reached to over 0.25 cd/A. While the device used CBP only for the host showed the luminous efficiency of under 0.11 cd/A

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Unequal Error Protection and Error Concealment Schemes for the Transmission of H.263 Video over Mobile Channels

  • Hong, Won-Gi;Ko, Sung-Jea
    • Journal of IKEEE
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    • v.2 no.2 s.3
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    • pp.285-293
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    • 1998
  • This paper presents unequal error protection and error concealment techniques far robust H.263 video transmission over mobile channels. The proposed error protection scheme has three major features. First, it has the capability of preventing the loss of synchronization information in H.263 video stream as much as possible that the H.263 decoder can resynchronize at the next decoding point, if errors are occurred. Secondly, it employs an unequal error protection scheme to support variable coding rates using rate compatible punctured convolutional (RCPC) codes, dividing the encoded stream into two classes. Finally, a macroblock-interleaving scheme is employed in order to minimize the corruption of consecutive macroblocks due to burst errors, which can make a proper condition for error concealment. In addition, to minimize the spatial error propagations due to the variable length codes, a fast resynchronization scheme at the group of block layer is developed for recovering subsequent error-free macroblocks following the damaged macroblock. futhermore, error concealment techniques based on both side match criterion and overlapped block motion compensation (OBMC) are employed at the source decoder so that it can not only recover the lost macroblock more accurately, but also reduce blocking artifacts. Experimental results show that the proposed scheme can be an effective error protection scheme since proper video quality can be maintained under various channel bit error rates.

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High Performance Electrode of Polymer Electrolyte Membrane Fuel Cells Prepared by Direct Screen Printing Process (직접 스크린 프린팅법으로 제조된 고분자 전해질 연료전지의 고성능 전극)

  • 임재욱;최대규;류호진
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.1
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    • pp.65-69
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    • 2004
  • Screen printing it one of the most popular methods for the fabrication of catalytic layer in electrode of polymer electrolyte membrane fuel cells (PEMFCs) due to its convenience and adaptability. This paper suggests an improved screen-printing method, which is rather simple suppressing the swelling trouble without additive process and competitive with very low Pt loading in comparison with the previous methods. Particularly, the gasket unified MEA made better performances than the other especially at high current area due to blocking effect on the gas leakage during the operation. These methods give us more simplified and faster fabrication chances.

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The Fabrication and Characteristics of p-channel SONOS Charge-Trap Flash Memory (p채널 SONOS 전하트랩 플래시메모리의 제작 및 특성)

  • Kim, Byung-Cheul;Kim, Joo-Yeon
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.604-607
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    • 2008
  • In this study, p-channel silicon-oxide-nitride-oxide-silicon (SONOS) transistors are fabricated and characterized as an unit cell for NAND flash memory. The SONOS transistors are fabricated by $0.13{\mu}m$ low power standard logic process technology. The thicknesses of gate insulators are $20{\AA}$ for the tunnel oxide, $14{\AA}$ for the nitride layer, and $49{\AA}$ for the blocking oxide. The fabricated SONGS transistors show low programming voltage, fast erase speed, and relatively good retention and endurance.

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Impedance Spectroscopy Studies on Corrosion Inhibition Behavior of Synthesized N,N’-bis(2,4-dihydroxyhydroxybenzaldehyde)-1,3-Propandiimine for API-5L-X65 Steel in HCl Solution

  • Danaee, I.;Bahramipanah, N.;Moradi, S.;Nikmanesh, S.
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.153-160
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    • 2016
  • The inhibition ability of N,N-bis(2,4-dihydroxyhydroxybenzaldehyde)-1,3-Propandiimine (DHBP) as a schiff base against the corrosion of API-5L-X65 steel in 1 M HCl solution was evaluated by electrochemical impedance spectroscopy, potentiodynamic polarization and scanning electron microscopy. Electrochemical impedance studies indicated that DHBP inhibited corrosion by blocking the active corrosion sites. The inhibition efficiency increased with increasing inhibitor concentrations. EIS data was analysed to equivalent circuit model and showed that the charge transfer resistance of steel increased with increasing inhibitor concentration whilst the double layer capacitance decreased. The adsorption of this compound obeyed the Langmuir adsorption isotherm. Gibbs free energy of adsorption was calculated and indicated that adsorption occurred through physical and spontaneous process. The corrosion inhibition mechanism was studied by potential of zero charge. Polarization studies indicated that DHBP retards both the cathodic and anodic reactions through adsorption on steel surface. Scanning electron microscopy was used to study the steel surface with and without inhibitor.