• Title/Summary/Keyword: Bleaching

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Soda-Anthraquinone Pulping and Chlorine Dioxide Bleaching Properties from Moso Bamboo (Phyllostachys pubescens) (맹종죽(Phyllostachys pubescens)의 소다 안트라퀴논 펄핑 특성 및 이산화염소 표백 특성)

  • Lee, Kyu-seong;Song, Woo-Yong;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.13-19
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    • 2016
  • Moso Bamboo was investigated as the a raw material for pulp and paper industry. Soda-Anthraquinone (Soda-AQ) pulping, elemental chlorine free bleaching was applied. Yield of soda or soda-AQ pulp was 29.3-31.7% with Kappa number 33.0-22.8 with different cooking time or anthraquinone addition at 20% active alkali. In soda or soda-AQ pulping, 81-86% of xylan was removed, which was the main reason for lower pulp yield than hardwood species. Average fiber length of Moso Bamboo soda-AQ pulp was 1.36 mm with $15.5{\mu}m$ fiber width. Soda-AQ pulp from Moso Bamboo (P-3, lowest Kappa pulp) was bleached with 5.5-6.5% of chlorine dioxide charge as D0ED1 bleaching sequence. In 3-stages ECF bleaching, final brightness of 85.3% ISO was achieved with total chlorine dioxide 6.5%.

Pulp Bleaching Effect and Ionization Rate of Chlorine Dioxide by Additives and Various pH Conditions(I)-Ionization of ClO$_2$ and Formation of Chlorate in Pulp Bleaching- (pH와 첨가제에 의한 이산화염소의 분해율 및 펄프표백 효과(1)-표백 중에서 이산화염소의 분해와 Chlorate의 생성-)

  • ;Li Jun Wang
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.1-6
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    • 1998
  • Elementally Chlorine Free (ECF) bleaching will be superior than Totally Chlorine free (TCF) bleaching, not only because they have no significant difference in effluent toxicity, but also those pulps bleached by ECF have higher brightness, strength, yield, etc., over those by TCF. With this belief, this paper focused on the chemistry of chlorine dioxide decomposition and ionization, both in water solution and in pulp slurry. Special attention was paid to chlorate ion because there have been controversies as how it is formed and what its behavior to the end pH of pulp bleaching is. As a result, during ionization of chlorine dioxide with water, both chlorate and chlorite were found to increase with increasing pH, but during ionization with pulp, chlorite was found to increase with end pH while chlorate decreased with increasing end pH. In the case of ionization with water, the disproportion equation $2CIO_2 + OH^{-} \lightarrow H_2O + CIO_3^{-} + CIO_2^{-}$ was thought to become the main reaction with the increasing pH, while in the case of ionization with pulp, the reaction $HCIO + CIO_2^{-}\lightarow H^{+} + Cl^{-} + CIO_3^{-}$ was the main reaction contributing to the formation of chlorate. Based on this above opinion, the contrary results of chlorine dioxide ionization from different researchers were discussed and explained.

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Modeling Hydrogen Peroxide Bleaching Process to Predict Optical Properties of a Bleached CMP Pulp

  • Hatam Abouzar;Pourtahmasi Kambiz;Resalati Hossein;Lohrasebi A. Hossein
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.365-372
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    • 2006
  • In this paper, the possibility of statistical modeling from the pulp and peroxide bleaching condition variables to predict optical properties of a bleached chemimechanical pulp used in a newsprint paper machine at Mazandaran Wood and Paper Industries Company (MWPI) was studied. Due to the variations in the opacity and the brightness of the bleached pulp at MWPI and to tackle this problem, it was decided to study the possibility of modeling the bleaching process. To achieve this purpose, Multi-variate Regression Analysis was used for model building and it was found that there is a relationship between independent variables and pulp brightness as well as pulp opacity, consequently, two models were constructed. Then, model validation was carried out using new data set in the bleaching plant at MWPI to test model predictive ability and its performance.

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EoP Bleaching of Mixed Office Wastepaper (MOW의 산소-알칼리 첨가 과산화수소 표백)

  • Kim, Seung-Ho;Lee, Hyung;Baek, Ki-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.3
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    • pp.46-52
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    • 2002
  • To produce the raw material used for printing and writing paper or high quality tissue, MOWs that were consisted of white ledger, colored ledger and old newspaper were bleached with EoP and EoPY(FAS) method, the EoP bleaching process gave the improvement in brightness and a high color removal efficiency. Especially, MOW B(initial brightness: 59.1% ISO) that contained much old newspaper showed the higher bleaching efficiency than those of MOW A(initial brightness: 68.3%). After EoPY(FAS) bleaching, MOW's brightness was increased from 68.3% ISO to 84.3∼84.0% ISO, and from 59.1% ISO to 78.7∼79.2% ISO, respectively. Also the tensile and burst index of bleached pulps decreased by 10∼30%. The tear index slightly decreased or halted at the same range as unbleached pulps.

Studies on the Bleaching of Rice-Straw chemical Pulp(I) (볏짚화학펄프의 표백에 관한 연구)

  • 강진하;박성종
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.3
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    • pp.65-74
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    • 2000
  • This study was carried out to acquire basic data necessary for the use of rice-straw chemical pulp. It investigated the proper bleaching conditions when rice-straw chemical pulps(alkaline sulfite-Na2S2O4 pulp) were bleached with the various kinds of bleaching agents. And physical properties of bleached pulps were tested. The results of this study were as follows; 1, The proper conditions of chlorine sequence were determined to be 4% concentration of chlorine 25$^{\circ}C$ of reaction temperature and 50 minutes of reaction time. 2. For calcium hypochlorite sequence the proper conditions of chemical concentration reac-tion temperature and reaction time were 3% 25$^{\circ}C$ and 20 minutes respectively. 3. For chlorine dioxide sequence the proper conditions were 1% concentration of chlorine dioxide 70$^{\circ}C$ of reaction temperature and 2hr. of reaction time. 4. The proper conditions of hydrogen peroxide sequence were 1.5% concentration of hydro-gen peroxide 70$^{\circ}C$ of reaction temperature and 1hr. of reaction time respectively. 5. When the rice-straw chemical pulp were bleached with four kinds of bleaching agents methioned above in the proper conditions respectively brightnesses were the order of chlorine dioxide calcium hypochlorite, chlorine, hydrogen peroxide. And strengthes of pulps bleached with chlorine dioxide and hydrogen peroxide were higher than those of pulps bleached with other bleaching agents.

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THE COMPARISON OF MICROLEAKAGE ON INTRACORONAL RESTORATION AFTER NON-VITAL BLEACHING (실활치 표백술 후 치관내 수복물의 미세누출에 관한 비교)

  • Jung, Jae-Eun;Lee, Hee-Joo;Hur, Bock
    • Restorative Dentistry and Endodontics
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    • v.28 no.1
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    • pp.57-63
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    • 2003
  • The purpose of the present study were to evaluate microleakage of a fourth generation dentin-bonding agent following a walking bleaching treatment, to determine the effect of temporary postbleaching dressing with calcium hydroxide on microleakage and to investigate the effect of delayed intracoronal restoration on microleakage. The results of this study were as follows : 1. Bleached groups showed more microleakage than unbleached group 2. Immediately restored group following bleaching procedure showed the highest microleakage score. 3. One-week delayed restorations showed less microleakage but there were no statistically significant difference between group II and III. 4. Provisional dressing with calcium hydroxide had no influence on microleakage. It is necessary to know the time that has elapsed from the bleaching treatment to the restoration procedure to achieve optimal seal, as well as to reduce the risk of microleakage in adhesive restoration.

Comparative Analysis of Two Selective Bleaching Methods on Alpaca Fibers

  • Liu, Xin;Hurren, Christopher J.;Wang, Xungai
    • Fibers and Polymers
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    • v.4 no.3
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    • pp.124-128
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    • 2003
  • Dark brown Alpaca fiber was reduced in shade via selective bleaching with peroxide. Two selective oxidative bleaching methods were tested on alpaca top to assess their effectiveness for color removal and fiber quality properties. Color change, bundle strength, weight loss, fiber diameter, surface modification, dye-ability and dye wash fastness were assessed for both methods and compared with the original brown top. Bleach method 1 (BL-I) showed little surface modification, 5.8% weight loss and 2.4% strength loss. D1925 yellowness index was reduced to 74.3 from 83.1 and provided a good base for the dyeing of medium to deep shades. Bleach method 2 (BL-II) displayed considerable surface modification, 7.8% weight loss and 18% strength loss. BL-II also resulted in a mean diameter reduction of 1.9 micron during bleaching. Yellowness was reduced to 64.5 from 83.1 and provided a very good base for the dyeing of medium to deep shades. BL-I showed better exhaustion of the premetallised dye Lanaset Violet B than BL-II. Wash fastness for BL-II was 1 grey scale unit poorer than BL-I. BL-II showed far better color clarity at pale depths however the wash fastness of the finished product was not good enough to maintain the depth or clarity of the color. BL-I showed poorer clarity of color but exhibited better wash fastness results.

Application of Microorganism to Pulping and Bleaching Processes (펄프 및 표백공정(漂白工程)에서의 미생물응용(微生物應用))

  • Sakai, Koki
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.3
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    • pp.67-78
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    • 1992
  • The application of white-rot fungi to pulping and bleaching processes has been studied at the Wood Chemistry Laboratory in Kyushu University, cooperatively with the Biotechnology Laboratory of Kobe Steel, Ltd. Some successful results of the studies for a biomechanical pulping process, biobleaching of hardwood and softwood kraft pulp, as well as chlorine free biobleaching of oxygen-prebleached hardwood kraft pulp are dealt with. Biological treatment of the pulp bleaching effluent is also described.

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Effects of Surfactants on the Enzymatic Blaching of Kraft Pulp by Xylanase

  • Ryu, Keun-Garp;Kim, Young-Gon
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.94-96
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    • 1997
  • A xylanase was purified from a commercial crude xylanase, Pulpzyme HC, and used for the bleaching of kraft pulp in the absence or in the presence of nonionic surfactants, Tween 20, Tween 80, and Igepal C930. The purified xylanase has a molecular weight of 23,500 as determined by a reducing SDS-PAGE. Tween 20 was most effective to enhance the efficiency of the enzymatic bleaching of kraft pulp by xylanase.

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Effect of Various Bleaching Agents on Discolored Nonvital Teeth.

  • Park, Sun-Ah;Hwang, In-Nam;Oh, Won-Mann
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.591.1-591
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    • 2001
  • This study was performed to evaluate internal bleaching effect of various bleaching agent on discolored nonvital teeth. 40 Human teeth were intentionally discolored with erythrocytes of human blood and randomly divided into 4 groups: 10% carbamide peroxide gel (Opalescence, Ultradent, U.S.A.); 15% carbamide peroxide gel; sodium perborate (Duksan pure chemical Co., Korea) with distilled water; sodium perborate with 30% hydrogen peroxide (Duksan pure chemical Co., Korea).(omitted)

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