• Geophysics and Geophysical Exploration
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• v.16 no.1
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• pp.36-44
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• 2013

We conducted the airborne magnetic and radiometric survey for the characterization of the black shale related and pyrometamorphic uranium deposits distributed in Geumsan area. For the successful characterization of the uranium deposits, the general geological and structural geological features were investigated based on the lithological and linear feature analysis to individual magnetic and radiometric data as the first step. Lithological analysis from the magnetic reduction to the pole and downward continuation map revealed that prominent positive anomalies caused by black and dark gray slate member were clearly recognized as magnetic sources. These results indicate that magnetic survey, even though it is not a direct method for the detection of uranium, can be a useful tool in uranium detection. By the linear feature analysis based on 2nd vertical derivative and curvature map, two linearments corresponded the gray hornfels and black slate member were extracted and in succession, the additional uranium potential zone was inferred. Final discrimination whether uranium-rich or not was confirmed by radiometric and uranium anomaly map. From these analysis, we finally concluded that uranium deposit originated by pyrometamorphic process was confined near the intrusive area only. On the contrary, it was found that black shale related uranium deposit is distributed and extended through out the entire survey area with south-west to north-east direction. In addition, from the linear feature analysis based on radiometric total anomaly map, the typical discontinuous characteristics were recognized in areas where uranium-contained linearments cross the faults. From the above discussion, we concluded that airborne magnetic and radiometric survey are complementary to each other. So it is preferable to carry out simultaneously for the efficient data processing and fruitful interpretation.

• Explosives and Blasting
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• v.16 no.2
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• pp.23-33
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• 1998

This study has been carried out to design the standards of rock bolts which are recommended to be used for supporting material in Seong Ju tunnel, Under recently planned to construct. Due to the weak bedding rocks along the Tunnel, NATM supporting method is assumed to be applied and the design and calculation for rock bolts which are important material for this supporting method. Though the study, the results obtained are as follows. 1) The rocks defined s coarse sandstone, fine sandstone, medium sandstone, sandy shale and silty shale are normal rocks in strength, and black shale, greywacke and conglomerate are weak rocks in strength. 2) When the length of 3∼4meters of rock bolts are used, the distances of bolts are supposed to be 1.3∼1.8m in sandstone and 1.3∼2.0m in shale and for greywacke the distance should be 1.5m.

• Nuclear Engineering and Technology
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• v.12 no.2
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• pp.106-110
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• 1980

The radio-equilibrium conditions of uranium and thorium in the Okcheon black shales and monazites have been studied. As the results. a radiometric method based on the measurements of gamma ray activity has been suggested for the simple analysis of many samples in the process of the prospecting and the grading of uranium and thorium minerals.

• Economic and Environmental Geology
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• v.12 no.4
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• pp.207-221
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• 1979

The studied area occupies the southern part of Haenam peninsula located in the southwestern corner of Korea. The stratigraphic sequences of the area are grouped into following three units in ascending order. (1) Late Cretaceous sedimentary rocks of Uhangri Formation which consist of the alternative beds of black shales and tuffaceous sediments, Hwangsan acidic fine grained tuffs and Jindo rhyolite flows. (2) Late Cretaceous biotite granite and acidic porphyries which intruded the Late Cretaceous sedimentary rocks. (3) Tertiary(?) pitchstone. The study purposes to delineate any of geochemical aspects on the deposition of the sequences, the average amounts of organic materials and the effect to the maturation of hydrocarbonization which has been occured by the intrusives. Sixty nine black shale samples were collected from Uhangri Formation in the northern and southern coasts of the peninsula. Organic carbons, total extracted organic matters and hydrocarbons were mainly determined by the Soxhlet extraction method, together with C-H-N elemental analyses. Based on the field and laboratory studies, the following interpretations have been obtained. (1) The paleohydrostatic condition of the sedimentation which took place was relatively calm and stable to delineate a lacustrine environment. (2) The amounts of organic material were more or less constant throughout the period of the deposition of the sediments. (3) The degree of hydrocarbonization of the Uhangri Formation in the northern coast was taken place higher than that in the southern coast due to the differences of thermal effect by the biotite granite which is assumed to be as a heat source in the area. Among the northern coast, some black shales in Uhangri and Mogsam areas which had been under the most moderate temperature environment snow symptomatic oily material, whereas, those in Sinseongri area do not, which were presumably to be intensive thermal alteration by the later acidic porphyries.

• Economic and Environmental Geology
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• v.42 no.1
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• pp.27-53
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• 2009

A 30-m-thick Middle Ordovician Jigunsan Shale exposed along the southern limb of the Backunsan (Baekunsan) Syncline, Taebacksan (Taebaeksan) basin, has been simply considered as a transgressive shale sequence onlapped the underlying Maggol platform carbonates. Results of this study, however, suggest that majority of the Jigunsan Shale be interpreted as a regressive shale sequence downlapped onto a thin (ca. 240 cm) marine stratigraphic unit consisting of organic-rich (>3 wt.% of TOC) black shales in the lower Jigunsan Shale, which was accumulated at the time of maximum regional transgression. Detailed stratigraphic analysis in conjunction with XRD, XRF, and ICP-MS as well as Rock-Eval pyrolysis allows the thin marine stratigraphic unit in the Jigunsan Shale to define a condensed section that was deposited in a distinctive euxinic zone formed due to expansion of pycnocline during the early highstand phase. As well, a number of stratigraphic horizons of distinctive character that may have sequence stratigraphic or environmental significance, such as transgressive surface, maximum flooding surface, maximum sediment starvation surface, and downlap surface, are identified in the lower Jigunsan Shale. In the future, these stratigraphic horizons will provide very useful information to make a coherent regional stratigraphic correlation of the Middle Ordovician strata and to develop a comprehensive understanding on stratigraphic response to tectonic evolution as well as basin history of the Taebacksan Basin.

• Economic and Environmental Geology
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• v.30 no.5
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• pp.417-431
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• 1997

Characteristics of sedimentary rocks and enrichment of toxic elements in shale and coal from the Chungnam coal field were investigated based upon geochemistry of major, trace and rare earth elements. Shale and coal of the area are interbedded along the Traissic to the Jurassic Daedong Supergroup, which can be subdivided into grey shale, black shale and coal. The coal had been mined, however all the mines are abandonded due to the economic problems. The shale and coal are characterized by relatively low contents of $SiO_2$, and $Al_2O_3$ and high levels of loss-on-ignition (LOI), CaO and $Na_2O$ in comparison with the North American Shale Composite (NASC). Light rare earth elements (La, Ce, Yb and Lu) are highly enriched with the coal. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in shale and coal range from 30.0 to 351.8 and from 4.2 to 106.8, which have partly negative correlations against $SiO_2/Al_2O_3$ (1.24 to 6.06), respectively. Those are suggested that controls of mineral compositions in shale and coal can be due to substitution and migration of those elements by diagenesis and metamorphism. Shale and coal of the area may be deposited in terrestrial basin deduced from high C/S (39 to 895) and variable composition of organic carbon (0.39 to 18.40 wt.%) and low contents of reduced sulfur (0.01 to 0.05 wt.%). These shale and coal were originated from the high grade metamorphic and/or igneous rocks, and the rare earth elements of those rocks are slightly influenced with diagenesis and metamorphism on the basis of $Al_2O_3$ versus La, La against Ce, Zr versus Yb, the ratios of La/Ce (0.38 to 0.85) and Th/U (3.6 to 14.6). Characteristics of trace and rare earth elements as Co/Th (0.07 to 0.86), La/Sc (0.31 to 11.05), Se/Th (0.28 to 1.06), V/Ni (1.14 to 3.97), Cr/V (1.4 to 28.3), Ni/Co (2.12 to 8.00) and Zr/Hf (22.6~45.1) in the shale and coal argue for inefficient mixing of the simple source lithologies during sedimentation. These rocks also show much variation in $La_N/Yb_N$ (1.36 to 21.68), Th/Yb (3.5 to 20.0) and La/Th (0.31 to 7.89), and their origin is explained by derivation from a mixture of mainly acidic igneous and metamorphic rocks. Average concentrations in the shale and coal are As=7.2 and 7.5, Ba=913 and 974, Cr=500 and 145, Cu=20 and 26, Ni=38 and 35, Pb=30 and 36, and Zn=77 and 92 ppm, respectively, which are similar to those in the NASC. Average enrichment indices for major elements in the shale (0.79) and coal (0.77) are lower than those in the NASC. In addition, average enrichment index for rare earth elements in coal (2.39) is enriched rather than the shale (1.55). On the basis of the NASC, concentrations of minor and/or environmental toxic elements in the shale and coal were depleted of all the elements examined, excepting Cr, Pb, Rb and Th. Average enrichment indices of trace and/or potentially toxic elements (As, Cr, Cu, Ni, Pb, U and Zn) are 1.23 to 1.24 for shale and 1.06 to 1.22 for coal, respectively.

• Economic and Environmental Geology
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• v.9 no.3
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• pp.157-163
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• 1976

In this study, the oil bearing rock-sequence, U-hand-ri Formation (D.S. Lee et al., 1976), was subdivided into three members; the lower, the intermediate and the upper. The lower consists mainly of reddish purple tuff and sandy calcareous shales, the intermediate of an alternation of tuffs, sandstons, calcareous black shales, cherts and limestone and the upper of coarse grained variegated tuff and agglomerate. Oily matter was found from the black shales of the intermediate. Ten samples of black shales from drilled cores, 8 samples of black shales from different outcrops of the member, and 1 sample of grease-like seeping oil from black shales at U-hang-ri coast were chemically analyized. Among them, 9 samples contain remarkable amount of organic carbon (0.96~1.60%) and E.O.M. extract (0.176~0.718%), and mostly the bituminous material is saturated hydrocarbons as well as shown in infared spectroscopic analyses. The elemental analyses of MAE extracts and asphaltenes of some of thoese samples indicate that the transformation of organic material to crude oil is highly progressed. The authors suggest that the seeping oil and oily tinges in black shale layers are the products of natural cracking related with the igneous activities in the area nearby.

• Journal of The Korean Society of Agricultural Engineers
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• v.54 no.5
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• pp.43-47
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• 2012

A evaluation for the strength of rock includes a lot of uncertainty due to existence of discontinuity surface and weakness plain in the rock mass, so essential test results and other data for the resonable strength analysis are absolutely insufficient. Therefore, a analytical technique to reduce such uncertainty can be required. A probabilistic analysis technique has mainly to make up for the uncertainty to investigate the strength of rock mass. Recently, a artificial neural networks, as a more newly analysis method to solve several problems in the existing analysis methodology, trends to apply to study on the rock strength. In this study the unconfined compressive strength from basic physical property values of sedimentary rock, black shale and red shale, distributed in Daegu metropolitan area is estimated, using the artificial neural networks. And the applicability of the analysis method is investigated. From the results, it is confirmed that the unconfined compressive strength of the sedimentary rock can be easily and efficiently predicted by the analysis technique with the artificial neural networks.

• Journal of Korean Society of Forest Science
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• v.108 no.2
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• pp.216-223
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• 2019

This study was conducted to measure the changes in the geological and soil properties following slow-moving landslide events in Yangbuk-myun and Gyungju-si, Gyeongsangbuk-do, South Korea. The geological characteristics of the study site comprised black shale in the Gyeongsang nodal group formed in the Cretaceous period and quartz feldspar carcinoma in the east side with conglomerate in the Yeonil group formed in the Quaternary period. The study site exhibited the geologic characteristics of a slow-moving landslide with severely weathered rocks. The maximum collapsing depth of the slow-moving landslide was 12.0 m with colluvial deposits. The strike and joint aspects in the slope areas of the slow-moving landslides were $N46^{\circ}E$ in lower slope and $N62^{\circ}E$ in upper slope, respectively. Soil hardness of ${\leq}20cm$ deep was not measured because of the completely disturbed soil resulting from soil creeping. Soil from 25 to 90 cm deep was 1.4-4.7 times softer in the slow-moving landslide areas than in the undisturbed or natural forests. Soil bulk density was $1.24-1.29g/cm^3$ in land creep areas. Soil bulk in both areas was 1.6 times denser than that in the natural forest. The soil pore space was 51.5-53.3% in the land creep areas. The values are 1.3-1.4 times lower than those within the natural forest. Black shale areas showed the lowest coefficient of permeability (8.75 E-06 cm/s) and mesopore ratio (pF 2.7: 9.8%) compared with those resulting from other study areas.

• Economic and Environmental Geology
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• v.30 no.2
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• pp.105-116
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• 1997

This study is for extent of polluted area by acid mine drainage from the Daeseong coal mine, Keumsan. Black shales of the Changri Formation containing the Daeseong coal mine are geochemically similar to those from the North America as well as Europe. Comparing with geochemical compositions and relative ratios, coal bearing and non-coal bearing soils are similar to the stream sediments influenced and not influnced by the acid mine drainage, respectively. These characteristics suggest that acidification of the soils and of the stream sediments are related to the the coal bearing black shale. Soil waters beneath the coal bearing soil have low pH and high cation contents than those beneath non-coal bearing soil, suggestive of extractions of cations with increasing oxidizations within the soils. Surface waters show that those influenced by the acid mine drainage are low pH, and have high $SO_4{^{2-}}$, $Mg^{2+}$, $Fe^{2+}$, Mn and slightly lower DO, suggesting that heavy pollutions have been progressed in these area. Geochemical comparisons between the polluted surface water and adjacent black shales suggest that pollutions of the surface water are related to the black shales.