• Korean Journal of Soil Science and Fertilizer
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• v.41 no.3
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• pp.228-234
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• 2008

The purpose of this study was to predict environmental distribution of anthracene, benzene, benzo[a]pyrene, 1-methylphenanthrene and phenanthrene in a four phase biopile system - air, water, soil and non aqueous phase liquid (NAPL) phase using level I fugacity model. Soil samples used for this study were collected from three sites in the United Kingdom which were historically contaminated with petroleum hydrocarbons. The level I fugacities (f) for the five contaminants were markedly different, however, the fugacities of each contaminant in three soil samples did not show significant difference. NAPL and soil were the dominant phases for all five contaminants. Results of this study indicated that difference in percentage of organic carbon strongly influenced the partitioning behavior of the cntaminants. The presence of benzene calls for an urgent need for risk-based management of air and water phase. Whereas insignificant amount of chemicals leached in the water phase for other organic contaminants showing greatly reduced potential of groundwater contamination. Furthermore, this study helped us to confirm the association of risk critical contaminants with the residual saturation in treated soils. They also can be used to emphasize the importance of accounting for the partitioning behavior of both NAPL and soil phases in the process of the risk assessment of the sites contaminated with petroleum hydrocarbons.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.363-367
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• 2003

Batch experiments were performed to determine optimum conditions for biopile. The batch experiments results showed that 12.5 to 17.9% of moisture content was effective to biodegradation of petroleum hydrocarbon regardless of soil texture. Total heterotrophic bacteria populations in the inoculum-treated soil were greater than of the control and nutrient-amended soil in the early stage, but the populations in the inoculum and nutrient-amended soil were not different significantly from those in the latter stage regardless of soil texture. The same trend was observed for petroleum hydrocarbon degrading bacteria populations. The results of the biodegradation capacity experiments showed that there was a decline in the TPH concentrations during the experiments and no significant difference on the biodegradation was observed by treatment in silt soil. Changes of n-C17/pristane and n-C18/phytane ratios in all treated soil were significantly more than those of control. This is a strong indication of biodegradation. The TPH removal rate was calculated at 60% in all treated soil.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.3
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• pp.415-424
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• 2011

This research was conducted to verified the effectiveness of a sintered porous media coated with organic matter as nutrient source and microorganisms as decomposer effective in TPH decomposition for a closed-typed biopole system. The organic matter content in the sintered porous media which was developed with bentonite increased with increasing dilution ratio of pig slurry and the sintered porous media as well as decrease in the particle size of sintered porous media. The decomposition rate of TPH was significantly increased with increasing aeration than that under atmospheric condition. Also the sintered porous media containing organic matter and microorganisms proved that the decomposition was enhanced with addition of nutrients sources in addition to aeration periodically.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.297-300
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• 2004

The various microbial tests were performed to determine bioremediation agent capacity for eight strains isolated from the oil contaminated regions. Two tests for isolated strains were conducted such as cell hydrophobicity and emulsifying activity. The biodegradation of SHM (saturated hydrocarbon mixture) and AHM (aromatic hydrocarbon mixture) with the strains also was carried out. The strains having higher cell hydrophobicity and emulsifying activity degraded petroleum oil effectively. The degradation capacity for SHM was represented more than 90% in YS-7 and WLH-1 of isolated strains, and KH3-2 were capable of degrading AHM. Especially, WLH-1 as yeast was shown more than two or three times in the degradation capacity of automobile engine lubricants and the biomonitoring results of contaminated soil for residual oil degrading test showed that the hydrocarbon biodegradation was increased in the second treatment by this strain.

• Journal of Soil and Groundwater Environment
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• v.15 no.1
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• pp.19-28
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• 2010

Considering six screen matrix to select an optimum remediation method for the Kunsan military base contaminated with petroleum oil, the following order was obtained: landfarming > biopile > soil washing > thermal desorption = incineration. When the landfarming method was applied for the remediation of 2,250 $m^3$ soil contaminated with petroleum oil ranging from 500 to 2,404 mg/kg as TPH, contamination level decreased below target concentration 450 mg/kg after 20~42 days depending on the initial contamination. From the evaluation of case studies of landfarming, it is suggested that ratty-truss or single-arch structure is suitable in the landfarming plant for the treatment of large-scale contaminated soil requiring long period of remediation. But, vinyl-house structure is suitable in the landfarming plant for the treatment of small-scale contaminated soil requiring short period of remediation. Therefore vinyl-house structure is recommended in the remediation of contaminated soil less than 5,000 $m^3$ requiring within 1 year of remediation period but ratty-truss or single-arch structure is recommended for the remediation of contaminated soil more than 5,000 $m^3$.