• Journal of the Korea Institute of Building Construction
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• v.23 no.6
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• pp.663-671
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• 2023

This research experimentally evaluated the recyclability of four varieties of lignocellulosic fly ash(FA), a by-product from three power plants employing lignocellulosic biomass(Bio-SRF, wood pellets) as a fuel source. Comprehensive analyses were conducted on FA, encompassing both physical parameters (particle shape, size distribution, fineness, and density) and chemical properties(chemical composition and heavy metal content). Mortar test specimens, with FA mixing ratios ranging from 5 to 20%, were produced in compliance with KS L 5405 standards, and their flow and compressive strength were subsequently measured. The test results indicated that the four types of FA exhibited particle sizes approximately between 20~30㎛, densities around 2.3~2.5g/cm³, and a fineness range of 2,600~4,900cm²/g. The FA comprised approximately 50~90% of components such as SiO₂, Al₂O₃, Fe₂O₃, and CaO, displaying characteristics akin to type-II and type-III FA of KS L 5405 standards, albeit with differences in chlorine and SiO₂ content. From the mortar tests, it was observed that the compressive strength of the mortar ranged between 34~47MPa when the pellet combustion FA was mixed in proportions of 5~20%. FA, produced exclusively from the combustion of 100% lignocellulosic fuel, is assessed to possess high recyclability potential as a substitute for conventional admixtures.

• Journal of Power System Engineering
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• v.18 no.5
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• pp.35-41
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• 2014

The wood pellet, which is one of the woody biomass energy, has very high economic efficiency and combustion efficiency during their combustion. The existing pellet burner have many problems such as low combustion efficiency, flame stabilization, ash problem and ignition time etc. We developed cyclonic wood pellet burner aim to 20,000kcal/hr boiler and measured temperature profiles and exhaust gases in order to investigate the flame stability and optimum combustion condition at any air flow conditions. As results, we confirmed the reappearance and the isotropy of the experimental results in the burner. At the first air flow inlet condition of excess air ratio ${\alpha}=0.02$, second air flow $490{\ell}/min$ had the best combustion condition when pellet supplied 30g. This result means that we need much air supply only for the swirling of second air flow. So we tested various second air flux at first air excess air ratio ${\alpha}=0.7$ condition. At this condition, we could find out that we don't need much second air and total air flux compared to the former condition. We will continuously test this work of air flow distribution, and swirl effect of first air flow, and ash elimination.

• Journal of the Korean Wood Science and Technology
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• v.51 no.5
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• pp.381-391
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• 2023

Densification is a technique used to improve biomass quality in wood pellet manufacturing and torrefaction treatment. In this study, the effects of torrefaction on the quality of Calliandra wood pellets were investigated, and pellets of Calliandra wood (Calliandra calothyrsus) and bark were evaluated. The study was conducted using a completely randomized design with two treatment factors, namely torrefaction temperature (250℃ and 300℃) and torrefaction duration (30, 45, and 60 min). The results showed that the interaction between temperature and torrefaction duration significantly affected the compressive strength, proximate value, and calorific value of the torrefied Calliandra wood pellets. An increase in the temperature and torrefaction duration decreased the compressive strength, moisture content, volatile matter content, and ash content of the torrefied Calliandra wood pellets. Conversely, the calorific value of Calliandra wood pellets increased with increasing temperature and torrefaction duration. The best-quality Calliandra wood pellets were produced at a torrefaction temperature and duration of 300℃ and 60 min, respectively. In terms of important quality parameters, ash content of 0.90% and calorific value of 6,303.80 cal/g were observed, which complied with the quality standards of Indonesian National Standard 8675:2018 and Deutsche Industrie Norm 51731.

• Applied Chemistry for Engineering
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• v.23 no.4
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• pp.399-404
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• 2012

The objective of this study was to investigate the efficient pretreatment method for bioethanol production from rice hull. Ammonia and sodium hydroxide as an alkaline solution and dilute sulfuric acid as an acidic solution were used in a batch reactor under high-temperature and high-pressure conditions. The highest enzymatic saccharification efficiency of 82.8% and ash removal rate of 94.7% were obtained in the dilute sulfuric acid treated sample after the sodium hydroxide solution treatment. The enzymatic saccharification efficiencies and ash removals of pretreated rice hull samples have very similar variation tendency. This means that the maximum obstructive factor for the enzymatic saccharification of rice hull is the ash (silicate) content in biomass. The findings suggest that the combined sodium hydroxide-dilute sulfuric acid treatment system under high-temperature and high-pressure conditions is a promising pretreatment method to enhance the enzymatic saccharification of the silica-rich biomass.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.712-718
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• 2019

A combustible producer gas composed of H₂, CO and CH₄ could be obtained by the thermal-chemical conversion of biomass. However, a large amount of particulate matters including tar generated causes the mal-function of turbines and engines or the fouling of pipelines. In this study, a wet scrubber using the soybean oil and bag filter were installed, and the removal efficiency was investigated. Hydrate limestone and wood char base activated carbon were pre-coated on the filter medium to prevent clogging of open pores. The removal efficiencies by the bag filter were 86 and 80% for the hydrated limestone and activated carbon coating, respectively. Overall, the collection when using a series of oil scrubbers and bag filters were 88%, while 83% for the filter coating material.

• Journal of Environmental Impact Assessment
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• v.9 no.2
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• pp.109-117
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• 2000

The dynamics of physico-chemical factors and biomass of epilithic attached algae was determined by bimonthly sampling in the Kyechon and Yudongchon situated in the upper part of Som River from March 1998 to February 1999. Among environmental factors, average of $NH_4$, $NO_3$, SRP and SRSi concentration ranged $8.9{\sim}86.6{\mu}g$ N/l, $663.9{\sim}2,018.1{\mu}g$ N/l, $0{\sim}15.0{\mu}g$ P/l and 1.6~2.6 mg Si/l, respectively. The contents of chlorophyll-a and organic matter per unit area, which ranged from 21.1 to 231.8 $mg/m^2$ and ranged from 5.2 to 52.6 $g/m^2$, respectively, showed very high in the spatial and temporal variations. Both were high in February and May and low in March seasonally. The fluctuation of epilithic biomass related the concentration of $NH_4$, SRP and current velocity. In relationship between biomass and current velocity, >200 and 100~200 mg chl-a/$m^2$ corresponded to <0.2 and <0.8 m/s, respectively. The evaluation of water quality with chl-a and organic matter of periphyton resulted on over eutrophic condition. Periphytic algae in a small stream were more effective as indicator of water quality than planktonic algae. More researches on periphytic algae in relation to water quality evaluation are needed.

• Korean Journal of Environmental Agriculture
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• v.38 no.4
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• pp.245-253
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• 2019

BACKGROUND: Weathering of bottom ash (BA) might induce change of its surface texture and pH and affect physical and chemical properties of soil associated with greenhouse gas emission, when it is applied to the arable soil. This study was conducted to determine effect of weathering of BA in mitigating emission of greenhouse gases from upland soil. METHODS AND RESULTS: In a field experiment, methane (CH₄), carbon dioxide (CO₂), and nitrous oxide (N₂O) emitted from the soil was periodically monitored using closed chamber. Three month-weathered BA and non-weathered BA were applied to an upland soil at the rates of 0, 200 Mg ha^-1. Maize (Zea mays L.) was grown from July 1_st to Oct 8_th in 2018. Both BAs did not affect cumulative CH₄ emission. Cumulative CO₂ emission were 23.1, 19.8, and 18.8 Mg/ha/100days and cumulative N₂O emission were 35.8, 20.9, and 17.7 kg/ha/100days for the control, non-weathered BA, and weathered BA, respectively. Weathering of BA did not decrease emission of greenhouse gases significantly, compared to the weathered BA in this study. In addition, both BAs did not decrease biomass yields of maize. CONCLUSION: BA might be a good soil amendment to mitigate emissions of CO₂ and N₂O from arable soil without adverse effect on crop productivity.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.1
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• pp.27-32
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• 2003

To understand the chemical structure of sewer sludge in comparison with commercial compost and charcoal used as a soil improver, it was carried out to analyse their ash contents and metal ions, and to elucidate the chemical structure of their residuals after a sequential treatment of alcohol-benzene(1:2) extraction in Soxhlet, 3% HCl reflux and 79% H₂SO₄ hydrolysis, using CHNS analyzer and solid C-13 NMR spectrometer. The results obtained were as follows: 1. Ash content of sludge was about 46% that is higher than those of compost (17%) and charcoal (4%). 2. The residual of sludge after a sequential treatment of HCl and H₂SO₄ hydrolyses had high ash content about 23%, too. 3. The sludge seems to be suitable to the soil improver because the content of heavy metal ions in sludge was near the compost and below the organic fertilizer standard. 4. Elemental composition of sludge residual after HCl-H₂SO₄ hydrolyes was C/sub 56/H/sub 91/O/sub 12/N₂S = (C/sub 6/H/sub 10/O/sub 5/)/sub 7/(C/sub 6/H₄)/sub 7/C₂H/sub 43/O₂N₂S, similar to C/sub 103/H/sub 122/O/sub 33/N/sub 6/S = (C/sub 6/H/sub 10/O/sub 5/)/sub 6/(C/sub 6/H₄)/sub 10/C/sub 7/H/sub 22/O₃N/sub 6/S of compost. 5. The sludge residual had proved to have both considerable aliphatic and aromatic groups, but the compost residual to have mainly aliphatic groups and the charcoal to have mainly aromatic groups, through the peak analysis of solid C-13 NMR charts. 6. So, the sewer sludge is proved to have a considerable amount of aromaticity like in woody biomass containing lignin.

• Journal of the Korean Wood Science and Technology
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• v.44 no.3
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• pp.360-369
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• 2016

In this study, sequential leaching and wet torrefaction were performed to improve the fuel characteristics of empty fruit bunch (EFB). Leaching was carried out at $25{\sim}90^{\circ}C$ for 5~30 min. The highest ash removal efficiency of 55.99% was achieved when leaching was performed at $90^{\circ}C$ for 10 min. The ash removal efficiency was dependent more on leaching temperature than time. Wet torrefaction was carried out at $180{\sim}200^{\circ}C$ for 5~40 min, following the leaching. Most of the inorganic compounds were removed at removal efficiencies of 41.05~63.58% during sequential leaching and wet torrefaction, while silica remained in the biomass. Chloride, calcium, magnesium, and phosphorus showed more than 80% removal efficiencies. The calorific value of EFB increased to 7.96% (4730 kcal/kg) in comparison to the raw material (4390 kcal/kg) when wet torrefaction was performed at $200^{\circ}C$ for 40 min following leaching.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.3
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• pp.55-61
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• 2018

This study evaluated if the selected samples meets the Solid Refuse Fuel quality criteria in Korea. Biomass and plastic wastes generated in D City were mixed in diverse ratio. When the biomass content was about 40%, the moisture content was close to the SRF criteria and was measured to be 9.8%. The ash contents were analyzed up to 4.19%, and the lower calorific values based on Steuer, Dulong Equation and Bomb Calorimeter were at least 4,851, 4,181 and 3,847 kcal/kg, respectively. As a result of the elemental analysis, sulfur and chloride content were measured up to 0.05%. Those values satisfied the SRF criteria. Also, heavy metals(Hg, Cd, Pb, As) were analyzed to be below the SRF criteria. This makes it possible to use efficiently the wood byproducts abandoned in the woods, and the physical properties of wood being weak to moisture can be supplemented with plastics. Consequently, if plastic and biomass were well mixed and made into SRF, it would overcome the problem of shortening the life span of incineration facilities due to the high temperature of plastic wastes in the incinerator.