• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.55-62
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• 2006

A two-step fuel-rich/fuel-lean catalytic combustion seems to be one of the most effective methods to control simultaneously the NO generation and the hydrocarbon (HC) conversion from fuel-bound nitrogen. By controlling equivalent air ratio for maintaining fuel-rich and fuel-lean condition over each catalytic layer, space velocity, inlet temperature, and catalyst component, the HCand ammonia conversion efficiency higher than 95% could be achieved, with ammonia conversion to NO remaining below 5%. The experimental results wouldbe applied to the combustion of land fill gas and to gasified refuse-derived fuels as a method of minimizing NO generation.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.355-356
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• 2014

Catalytic steam reforming of tar produced from biomass gasification was conducted using several Ni-based catalysts. K and Mn were used as a promoter over $Ni/Ru/Al_2O_3$ catalyst. The pellet and monolith type catalysts were prepared and applied to lab and bench-scale biomass gasification system. The $Ni/Ru-K/Al_2O_3$ catalyst shown higher performance than $Ni/Ru-Mn/Al_2O_3$ catalyst at low temperature range.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.231-233
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• 2012

Circulating Fluidized Bed (CFB) is a technically and economically proven technology for boiler systems and large CFB coal boilers are making inroads into the domestic power boiler market. For biomass gasification, it is also considered as a very promising technology for commercial. Due to the lack of experiences of a large scale CFB gasifier, however, any large scale CFB gasifiers are hard to in Korea in spite of fast-growing demand of domestic market. In this study, a 3 $MW_{th}$ CFB gasifier was developed for biomass gasification. The CFB gasifier consists of interconnected fast and bubbling fluidized bed reactors including unique features for in-situ tar removal. Various numerical and experimental approaches will be presented such as basic modeling works, investigation of hydrodynamics with a cold model, computational particle fluid dynamics and experiments in the 3 MWth gasifier.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.19-20
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• 2013

The cofiring of renewable fuel in coal fired boilers is an attractive option to mitigate $CO_2$ emissions, since it is relatively low cost option for efficiently converting renewable fuel to electricity by adding biomass as partial substitute of coal. However, it would lead to reduce plant efficiency and flexibility in operation, and increase operation cost and capital cost associated with renewable fuels handling and firing equipment. The aim of this study is to investigate reduction of carbon dioxide at varying percentage of biomass in fuel blend to the boiler biomass, and estimate operation and capital cost. Wood pellet, PKS (palm kernel shell), EFB (empty fruit bunch) and sludge are considered as a renewable fuels for a cofiring with coal. Several approaches by the cofiring ratio are chosen from past plant demonstrations and commercial cofiring operation, and they are evaluated and discussed for CO2 reduction and cost estimation.

• Journal of the Korean Society of Combustion
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• v.15 no.1
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• pp.43-49
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• 2010

Co-combustion of syngas in an existing boiler can be one of the options for replacing conventional fossil fuel with alternative fuels such as waste and biomass. This study is aimed to investigate effects of syngas cocombustion on combustion characteristics and boiler efficiency. An experimental study was performed for a pilot-scale furnace with 4 oil burners. Tests were conducted with mixture-gas as a co-combustion fuel and heavy oil as a main fuel. The mixture-gas was composed of 15% CO, 7% $H_2$, 3% $CH_4$ and 75% $N_2$ for simulating syngas from air-blown gasification. And LHV of the mixture-gas was 890 kcal/$Nm^3$. Temperature distribution in the furnace and flue gas composition were measured for various heat replacement ratio by the mixture gas. Heat loss through the wall was also carried out through heat & mass balance calculation, in order to obtain informations related to boiler efficiency. Experimental results show that similar temperature distribution and flue gas composition can be obtained for the range of 0~20% heat replacement by syngas. NOx concentration is slightly decreased for higher heat replacement by the syngas because fuel NOx is decreased in the case. Meanwhile, heat loss is a bit decreased for higher heat replacement by the syngas, which implies that boiler efficiency can be a bit decreased when syngas co-combustion is applied to a boiler.

• Journal of Energy Engineering
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• v.19 no.4
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• pp.251-257
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• 2010

Korea have a plan to enforce the Renewable Portfolio Standard(RPS) in 2012 for climate change action and effective use of energy but because of lack of renewable energy resources and limits of technology development, it will be hard to fullfill a target for RPS obligation in domestic power generation sector and woodchip biomass cofiring with coal combustion is the one of the alternative methods of the goal. Woodchip biomass cofiring with coal combustion is easy to approach technical design and has competitiveness of $CO_2$ & renewble energy certificate benefit and also has much lower generation cost than any other renewable energy resources. Because of that reason, woodchip biomass cofiring with coal combustion should be needed to fullfill the goal for RPS obligation in domestic power generation sector with midlong-term direction.

• New & Renewable Energy
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• v.19 no.1
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• pp.1-11
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• 2023

A large amount of carbon monoxide (CO) is generated in circulating fluidized bed combustion, the process whereby a hot cyclone separates unburned fuel. However, calcium sulfate (CaSO₄), when combined with a high CO content, can cause fouling on the surface of the steam tube installed inside the integrated recycle heat exchangers (INTREX). In this study, CaSO₄ decomposition was investigated using 0.2-3.2 vol.% CO and 1-3 vol.% oxygen (O₂) at 850℃ for 20 min in a lab-scale fluidized bed reactor. The results show that CaSO₄ decomposes into CaS and CaO when CO gas is supplied, and SO₂ emissions increase from 135 ppm to 1021 ppm with increasing CO concentration. However, the O₂ supply delayed SO₂ emissions because the reaction between CO and O₂ is faster than that of CaSO₄; nevertheless, when supplied with CaCO₃, the intermediate product, SO₂ was significantly released, regardless of the CO and O₂ supply. In addition, agglomerated solids and yellow sulfur power were observed after solid recovery, and the reactor distributor was corroded. Consequently, a sufficient O₂ supply is important and can prevent fouling formation on the INTREX surface by suppressing CaSO₄ degradation.

• Journal of Korea Society of Waste Management
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• v.35 no.7
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• pp.640-646
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• 2018

Biomass-fired power plants produce electricity and heat by burning biomass in a boiler. However, one of the most serious problems faced by these plants is severe corrosion. In biomass boilers, corrosion comes from burnt fuels containing alkali, chlorine, and other corrosive substances, causing boiler tube failures, leakages, and shorter lifetimes. To mitigate the problem, various approaches implying the use of additives have been proposed; for example, ammonium sulfate is added to convert the alkali chlorides (mainly KCl) into the less corrosive alkali sulfates. Among these approaches, the high temperature corrosion prevention technology based on ammonium sulfate has few power plants being applied to domestic power plants. This study presents the results obtained during the co-combustion of wood chips and waste in a circulating fluidized bed boiler. The aim was to investigate the characteristics of pollution load in domestic biomass power plants with ammonium sulfate injection. By injecting the ammonium sulfate, the KCl content decreased from 68.9 to 5 ppm and the NOx were reduced by 18.5 ppm, but $SO_2$ and HCl were increased by 93.3 and 68 ppm, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.53-59
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• 2015

Combustion characteristics for co-firing of biomass (Walnut Shell) as blending fuel in coal fired boiler have investigated using thermogravimetric analyser (TGA) and drop tube reactor (DTR). The results show that devolatilization and char combustion for WS occurs at lower temperature than those of existing coals and has lower activation energy value, which is resulting in higher reactivity. When the WS is blended with coal, TGA results show linear profiles depending on blending ratio for each fuel. However, DTR results exist the non-additive phenomena for blending of WS. As blending ratio of WS increase, the UBC decrease at BBR 5%, but the UBC rather increase from BBR 10% due to oxygen deficiency formed from rapid combustion of WS. This paper propose that fuel lean condition by oxygen rich lead to higher blending ratio of biomass by solving the oxygen deficiency condition.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.1
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• pp.48-58
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• 2014

It is very important to investigate air pollutants emissions emitted from open burning in order to control nonpoint sources effectively. In this study, we utilized incineration simulator proposed by U.S EPA and investigated emissions of CO, OC/EC, from household waste and biomass burning to estimate pollutant emissions by illegal incineration of biomass wastes. Emission factor of OC was estimated as 17.1 g/kg for rice strew, 23.5 g/kg for barley, 10.3 g/kg for corn stover, 4.3 g/kg for unseasoned wood, respectively. In case of EC, it was calculated as 1.6 g/kg for rice strew, 4.3 g/kg for barley, 1.4 g/kg for corn stover, 0.6 g/kg for unseasoned wood, respectively. Most of the pollutants emissions were emitted at the stage 1 and 2. In the stage 3, the pollutants concentration decreased gradually. To estimate emissions and build inventory for biomass burning, we need to know accurate activity data. We, therefore, used activity data of both survey results of previous study and statistical data of National Statistical Office. However, we need to perform additional experiments in the future to obtain more accurate activity data for various cases.