• 제목/요약/키워드: Bio-kinetic Coefficient

검색결과 9건 처리시간 0.031초

판지공장 폐수 중 난분해성 유기물질이 동력학적 계수 및 생분해에 미치는 영향 (Effect of Recalcitrant Organics on Bio-kinetic Coeffcient and Biodegradable in Box-mill Wastewater)

  • 조용덕;이상화
    • 상하수도학회지
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    • 제20권3호
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    • pp.329-338
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    • 2006
  • The research aims to provide the basic data for practical applications by correlating the bio-kinetic coefficients with the load of recalcitrant organic matter in box-mill wastewater. The activated sludge process was employed to a Wastewater disposal plant in an industrial setting, increase of consequently leading to the organic load. The parameter values derived by Monod-kinetic analysis were as follows:specific substrate removal rate $K_{max}=0.17day^{-1}$, half saturation constants $K_s=60.37mg/l$, decay coefficient $K_d=0.142day^{-1}$, microbial yield coefficient y = 0.388mg/mg, and max specific growth rate ${\mu}_{max}=0.006day^{-1}$. In view of biodegradability, the $TCOD_{Mn}/TBOD_5$ ratios of inflow and outflow were 1.07 and 1.41, and the $SCOD_{Mn}/SBOD_5$ ratios of inflow and outflow were 1.10 and 1.50, respectively. The higher $TCOD_{Mn}/TBOD_5$ ratio of outflow indicated that metabolites of a microorganism have accumulated in the cells.

Lab-based Simulation of Carton Clamp Truck Handling - Frictional Characteristics between Corrugated Packages

  • Park, Jong Min;Choi, Sang Il;Kim, Jong Soon;Jung, Hyun Mo
    • 한국포장학회지
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    • 제25권3호
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    • pp.131-137
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    • 2019
  • Carton clamps, one of forklift attachments, allow users to quickly handle shipping units such as unitized loads, large shipping cases, or crates without the requirement of pallets. As the use of palletless handling by clamp trucks increases, so does the need for simulation research on clamp truck handling. The frictional characteristics for various contact conditions of corrugated paperboards and their constituent boards were analyzed to obtain the data needed in the computer simulation for the handling of carton clamp truck. The overall mean of static-frictional coefficients between selected corrugated paperboards was 0.38 (±0.01), which was 1.3~1.6 times greater than 0.23~0.29 of the frictional coefficients between boards. The overall mean of static-frictional coefficients between the corrugated paperboards and the rubber contact pad was 0.82 (±0.02), which was about 1.1 to 2.8 times greater than 0.29~0.78 of the static-frictional coefficient between the linerboard and the rubber contact pad. The overall mean of kinetic-frictional coefficients between the corrugated paperboards was 0.35 (±0.01), and 0.76 (±0.02) between the corrugated paperboards and the rubber contact pad.

Adsorption Characteristics and Kinetic Models of Ammonium Nitrogen using Biochar from Rice Hull in Sandy Loam Soil

  • Choi, Yong-Su;Kim, Sung-Chul;Shin, Joung-Du
    • 한국토양비료학회지
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    • 제48권5호
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    • pp.413-420
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    • 2015
  • Objective of this study was to investigate adsorption characteristics and kinetic models of $NH_4-N$ to biochar produced from rice hull in respective to mitigation of greenhouse gases. $NH_4-N$ concentration was analyzed by UV Spectrophotometer. For the experiment, the soil texture used in this study was sandy loam soil, and application rates of chemical fertilizer and pig compost were $420-200-370kgha^{-1}$ (N-P-K) and $5,500kgha^{-1}$ as recommended amount after soil test for corn cultivation. Biochar treatments were 0.2-5% to soil weight. Its adsorption characteristic was investigated with application of Langmuir isotherm, and pseudo-first order kinetic model and pseudo-second order kinetic model were used as kinetic models. Adsorption amount and removal rates of $NH_4-N$ were $39.3mg^{-1}$ and 28.0% in 0.2% biochar treatment, respectively. The sorption of $NH_4-N$ to biochar was fitted well by Langmiur model because it was observed that dimensionless constant ($R_L$) was 0.48. The maximum adsorption amount ($q_m$) and binding strength constant (b) were calculated as $4.1mgg^{-1}$ and $0.01Lmg^{-1}$ in Langmuir isotherm, respectively. The pseudo-second order kinetic model was more appropriate than pseudo-first order kinetic model for high correlation coefficient ($r^2$) of pseudo-second order kinetic model. Therefore, biochar produced from rice hull could reduce $N_2O$ by adsorbing $NH_4-N$ to biochar cooperated in sandy loam soil.

산소이용률을 이용한 생물학적 동력학 계수 추정 (The Estimation of Bio-kinetic Parameters using Respirometric Analysis)

  • 정연규;김한수;유성인
    • 대한환경공학회지
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    • 제22권1호
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    • pp.11-19
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    • 2000
  • 생물학적 폐수처리장의 효율을 정확하게 예측하기 위해서는 생물학적 동력학 계수와 화학양론적 계수를 반드시 추정하여야만 한다. 본 연구에서는 생물학적 동력학 계수를 추정하는 실험적 방법과 그 이론적 배경이 논의되었다. 또한 생물학적 동력학 계수 추정을 위해 신소이용률(Oxygen Uptake Rate, OUR)을 이용한 회분식 실험을 실시하였다. 호기성 상태에서 종속영양미생물과 독립영양미생물의 생물학적 동력학 계수를 추정하기 위한 간단한 방법이 기술되어 있다. 생물학적 동력학 계수 추정시 해석상의 부정확성 때문에 COD와 VSS농도를 이용하지 않고 산소이용률을 미생물 성장 자료로 변환하여 사용하였다. 종속영양미생물의 최대비성장율, 생산계수, 반속도상수, 사멸율을 산소이용률을 사용하여 추정하였다. 또한 독립영양미생물의 최대비성장율은 $NO_3{^-}$ 농도의 증가율로부터 추정하였다. 본 연구의 목적은 회분식 반응조에서 산소이용률을 이용해 종속영양미생물과 독립영양미생물의 생물학적 동력학 계수를 정확하고 간편하게 추정하는데 있다. 이러한 산소이용률을 이용한 생물학적 동력학 계수 추정 방법이 복잡한 활성슬러지 모델링에 도움을 줄 것으로 판단된다.

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무산소 활성오니공정을 이용한 판지공장 폐수처리의 동력학적 해석 및 설계분석 (Bio-kinetic and Design Analysis for Box-mill Wastewater Treatment Using Anoxic Activated Sludge Process)

  • 조용덕;이상화;김영일
    • 대한환경공학회지
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    • 제28권10호
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    • pp.1090-1097
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    • 2006
  • 판지공장 인쇄폐수에 무산소 활성오니공정을 적용한 결과 $TCOD_{Mn}=90{\sim}94%$, $Color=58{\sim}81%$의 높은 제거효율을 얻었다. 산업현장 판지공장 폐수에 대한 무산소 활성오니공정의 설계분석을 위하여 Monod식에 의한 동력학적계수를 추정한 결과 $K_{max}$(최대 기질제거속도)=0.52 $day^{-1}$, $K_s$(반포화 기질농도)=314 mg/L, $K_d$(내생호흡계수)=0.274 $day^{-1}$, y(미생물의 합성계수)=0.908 mg/mg, ${\mu}_{max}$(최대 비생장속도)=0.472 $day^{-1}$로 산출되었다. 설계분석을 위한 부하인자의 값은 F/M비=$0.043{\sim}0.07$ kg-$TCOD_{Mn}$/kg-SS-day, BOD 용적부하=$0.18{\sim}0.3$ kg-$TCOD_{Mn}/m^3-day$, ${\theta}_x$(미생물 체류시간)=$=6.8{\sim}26.4$ day로 현장 검증되었다. 이러한 부하인자의 값을 미생물의 성장 동력학과 연계시켜 볼 때 F/M비는 ${\theta}_x$에 반비례하고, 단위측면에서 F/M비는 ${\mu}_{max}$와 같아야 하나 F/M비와 ${\mu}_{max}$는 상당한 차이가 있음을 알 수 있었다. 따라서 미생물의 성장 동력학을 이용한 무산소 활성오니공정을 설계하고자 할 때에는 충분한 안전율이 요구되는 것으로 사료되었다.

다공성 여재를 이용한 고정생물막 반응기 특성에 관한 연구 (The study on Fixed Bio-reactor Characteristics Using Porous Media)

  • 이영신;김동민;정상철;백명석
    • 한국환경보건학회지
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    • 제22권1호
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    • pp.99-106
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    • 1996
  • The purpose of this study is to observe a specific removal efficiency of synthethetic wastewater which is managed by upflow submerged type at porous media which was sinteringed on a comparative low temperature 600$\circ$C, was annexed slag and humus soil with main material kaolinite. Observing removal efficiency quality of each media, a mixed media of kaolinite and humus soil by gravity percent 60, 40% respectively showed the most excellent removal utility, and applied predictive models for suspended culture kinetics without consideration diffusion limitation, and when analyzed kinetic which had been processed by this study the removal efficiency accompanied by carbon, nitrogen, phosphorous volumetric loading rate variation standed for a comparative large change rate 61~71%, it means the selection of the most proper load factor had a great effect on the highly removal efficiency, yield coefficient(Y) and specific microbial attach equation showed 1.53 mgVSS/mgCOD, $m_p=10039.4\times ((S_0)/(6.75+S_0))$ repectively.

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호기성 입상화 슬러지를 이용한 SBR 운전의 동력학적 해석 및 설계분석 (Bio-kinetic and Design Analysis of a Sequencing Batch Reactor by Aerobic Granular Sludge)

  • 최성우
    • 대한환경공학회지
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    • 제33권4호
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    • pp.275-280
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    • 2011
  • 고분자 응집제를 이용하여 짧은 시간에 형성된 입상형태의 슬러지를 연속회분식 장치에 주입하여 미생물의 호기성 입상화의 특성을 향상시키고, 제조한 입상화 슬러지를 하수에 적용하여 유기물제거에 대한 운전인자를 도출하였다. 유입하수 COD 63~72 mg/L에 대한 유기물 제거속도 계수 k는 $10.161d^{-1}$로 일반적 활성슬러지 공법의 k값 $5{\sim}8d^{-1}$보다 효과적으로 나타났으며, 산소이용에 대한 a', b' 값은 각각 0.87 mg $O_2/mg$ $COD_r$, 0.11 mg $O_2/mg$ MLVSS d이었다. 슬러지 합성계수와 자산 화계수는 각각 0.45 mg VSS/mg $COD_r$과 0.05 mg VSS/mg MLVSS d로 일반적 활성슬러지 공법에 비해, 자산화 계수는 비교적 적은 값으로 나타나므로 미생물의 사멸율은 낮은 것을 알 수 있었다.

어닐링 온도에 따른 무배향 PLA 필름의 등온결정화 거동과 표면물성에 관한 연구 (Study on Isothermal Crystallization Behavior and Surface Properties of Non-Oriented PLA Film with Annealing Temperature)

  • 김지혜;김문선;김병우
    • Korean Chemical Engineering Research
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    • 제49권5호
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    • pp.611-616
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    • 2011
  • 본 연구에서는 무배향 PLA 필름의 어닐링(annealing) 단계를 통하여 온도별 PLA 필름의 avrami 결정화 속도식을 도출하고 결정화 속도상수(k)를 비교함으로써 최적화된 어닐링 온도를 제안하였다. 120, 130, $140^{\circ}C$ 온도에서 결정화된 필름의 결정화 속도상수(k)는 각각 1.64, 1.68, 1.26이었다. 필름표면에 대한 어닐링은 필름의 표면조도와 동마찰계수에 영향을 주는데 80, 110, 120, 130, $140^{\circ}C$의 온도조건에서 표면조도(Ra)는 각각 0.006, 0.009, 0.015, 0.027, 0.029 ${\mu}m$로 높아졌고 동마찰계수(${\mu}_k$)는 0.45, 0.43, 0.33, 0.31, 0.27로 낮아졌다. 탈크를 1, 3, 5 wt%씩 첨가하는 경우 PLA 필름의 결정화 속도상수(k)는 0.58, 0.46, 0.39로 낮아졌다.

적용 기법에 따른 강우침식인자 산정 결과의 시공간적 불확실성 (Spatiotemporal Uncertainty of Rainfall Erosivity Factor Estimated Using Different Methodologies)

  • 황세운;김동현;신상민;유승환
    • 한국농공학회논문집
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    • 제58권6호
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    • pp.55-69
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    • 2016
  • RUSLE (Revised Universal Soil Loss Equation) is the empirical formular widely used to estimate rates of soil erosion caused by rainfall and associated overland flow. Among the factors considered in RUSLE, rainfall erosivity factor (R factor) is the major one derived by rainfall intensity and characteristics of rainfall event. There has been developed various methods to estimate R factor, such as energy based methods considering physical schemes of soil erosion and simple methods using the empirical relationship between soil erosion and annual total rainfall. This study is aimed to quantitatively evaluate the variation among the R factors estimated using different methods for South Korea. Station based observation (minutely rainfall data) were collected for 72 stations to investigate the characteristics of rainfall events over the country and similarity and differentness of R factors calculated by each method were compared in various ways. As results use of simple methods generally provided greater R factors comparing to those for energy based methods by 76 % on average and also overestimated the range of factors using different equations. The variation coefficient of annual R factors was calculated as 0.27 on average and the results significantly varied by the stations. Additionally the study demonstrated the rank of methods that would provide exclusive results comparing to others for each station. As it is difficult to find universal way to estimate R factors for specific regions, the efforts to validate and integrate various methods are required to improve the applicability and accuracy of soil erosion estimation.