• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2007년도 춘계학술발표논문집
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• pp.39-41
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• 2007

자동차의 연소과정 후 발생되는 NOx를 제거하기 위하여 재생유(Bia-diesel)를 환원제로 사용하였으며, $Ag/Al_{2}O_{3}$ 를 배출가스 후처리 촉매로 사용하였다. 그에 따른 물리적 특성을 조사하고 bio-diesel 환원제의 질소산화물 제거 성능 실험을 수행하였다. 그 결과 $Ag/Al_{2}O_{3}$ 촉매계에서 최적의 Ag 담지량은 2wt% 인 것으로 나타나고, 산처리된 $Ag/Al_{2}O_{3}$ 촉매가 반응 온도$300^{\circ}C$ 에서 가장 높은 NOx 제거 전화율을 나타낸다.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.567-577
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• 2019

Due to the depletion of fossil fuels and environmental pollution, demand for alternative energy is gradually increasing. Among the various methods, a method to convert biomass into alternative fuel has been proposed. The bio-fuel obtained from biomass through pyrolysis process is called pyrolysis oil (PO) or bio-oil. Because PO is difficult to use directly in conventional engines due to its poor fuel properties, various methods have been proposed to upgrade pyrolysis-oil. The simplest approach is to mix it with conventional fossil fuels. However, due to their different polarity of PO and fossil fuel, direct mixing is impossible. To resolve this problem, emulsification of two fuels with a proper surfactant was proposed, but it costs additional time and cost. Alternatively, the use of alcohol fuels as an organic solvent significantly improve the fuel properties such as fuel stability, calorific value and viscosity. In this study, blends of diesel, n-butanol, and coffee ground pyrolysis oil (CGPO) which is one of the promising PO, was applied to diesel generator. Combustion and emissions characteristics of blended fuels were investigated under the entire load range. Experimental results show that ignition delay is similar to that of diesel at high load. Although, hydrocarbon and carbon monoxide emissions are comparable to diesel, significant reduction of nitrogen oxides and particulate matter emissions were observed.

• 공업화학
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• 제24권5호
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• pp.530-536
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• 2013

경유의 윤활성향상제로 사용하기 위하여 식물유 기반 다이머산 유도체를 합성하여 윤활성능을 평가하였다. 다이머산 유도체의 합성은 2단계의 반응을 거쳐 합성하였는데, 1단계 반응으로 폐식물유(다크오일)를 가수분해반응을 통하여 합성한 지방산을 사용하여 고온에서 디엘스-알더 반응을 행하여 다이머산을 합성하였다. 2단계 반응으로 합성한 다이머산을 사용하여 메탄올과 에스테르화 반응을 행하여 다이머산 유도체를 합성하였다. 합성한 다이머산 유도체는 1 wt% 범위 내에서 초저유황 경유에 잘 용해되었으며 일정량(120 ppm)을 초저유황 경유에 첨가하여 HFRR 시험법으로 마모흔을 측정하여 윤활성능을 평가하였다. 그 결과, 첨가 전 초저유황 경유의 마모흔의 직경이 $552{\mu}m$에서 첨가 후 $300{\sim}05{\mu}m$으로 현저히 작아져 초저유황 경유의 윤활성능을 향상하는 것으로 확인되었다. 한편, 식물유의 종류에 따른 마모흔의 차이는 크지 않아 다이머산 유도체의 알킬기의 구조에 따른 윤활성능의 차이는 크게 나타나지 않았으나, 카르복실산 그룹을 함유하는 다이머산 유도체가 함유하지 않은 유도체보다 윤활성능이 우수하였다.

• 한국분무공학회지
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• 제16권1호
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• pp.44-50
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• 2011

An object of this study is to understand the correlation of injection characteristics and injector dimensions according to biodiesel mixture. The Injection characteristics of different types of common-rail injectors are the number of nozzle holes (5~8), jet cone angle ($146^{\circ}{\sim}153^{\circ}$), hydraulic flow rate (830~900 ml/min) injection quantity and response time. Prior to characteristic experiment, the reference injector has been selected in 6 candidates injectors under the investigation of injected quantity according to the biodiesel mixture so that injector type can be determined. The injector is used for the characteristic experiment which varied the various operating conditions including pressure 23 MPa, 80 MPa, 160 MPa, changing in injection duration 0.16 ms~1.2 ms and even mixture ratio. The result shows that the nozzle hole number and cone angle influence the injection quantity much more than nozzle hole diameter at low injection pressure and the nozzle hole diameter at high injection pressure, post injection duration.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.579-584
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• 2007

대두유로부터 생산된 바이오디젤과 바이오디젤 혼합 연료유를 대상으로 지방산메틸에스터 함량과 화학적 분석을 통해 산화 특성과 오일의 수명 예측 연구를 수행하였다. 바이오디젤, 경유, BD5, BD20은 산화가 진행될수록 산가(Acid number), 동점도(Kinematic Viscosity) 및 밀도(Density)는 증가하였다. 산가 측정결과의 활용에 의해 임의의 온도조건에서 정확한 사용수명을 예측하기 위하여 화학속도론에 의거하여 각각의 연료에 대한 사용수명식을 도출하였다. 도출된 사용수명식으로부터 바이오디젤이 가장 빠르게 산화가 진행되었고 바이오디젤 혼합량이 증가할수록 사용수명이 단축되는 것을 확인할 수 있었다.

• 한국정밀공학회지
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• 제28권2호
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• pp.154-167
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• 2011

Recently, microalgae have been focused on potential biomass for bio-diesel and biorefinery process. The aim of this paper is to review the biorefinery process including biodesel using microalgae as a microreactor. The state-of-the-art of biodiesel and biorefinery research such as extraction and reaction process as well as byproducts utilization is described. In addition, we suggest possibility for develop bioactive substances and their industrial products from byproducts of microalgae massively obtained after bio-diesel extraction.

• 신재생에너지
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• 제3권2호
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• pp.17-23
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• 2007

대두유로부터 생산된 바이오디젤과 바이오디젤 혼합 연료유를 대상으로 지방산메틸에스터 함량과 화학적 분석을 통해 산화 특성과 오일의 수명 예측 연구를 수행하였다. 바이오디젤, 경유, BD5, BD20은 산화가 진행될수록 산가(Acid number), 동점도(Kinematic Viscosity) 및 밀도(Density)는 증가하였다. 산가 측정결과의 활용에 의해 임의의 온도조건에서 정확한 사용수명을 예측하기 위하여 화학속도론에 의거하여 각각의 연료에 대한 사용수명식을 도출하였다. 도출된 사용수명식으로부터 바이오디젤이 가장 빠르게 산화가 진행되었고 바이오디젤 혼합량이 증가할수록 사용수명이 단축되는 것을 확인할 수 있었다.

• 한국자원식물학회:학술대회논문집
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• 한국자원식물학회 2020년도 추계국제학술대회
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• pp.58-58
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• 2020

Xanthoceras sorbifolium Bunge (yellowhorn) is a woody tree in the soapberry family, Sapindaceae, native to northern China. This species has been identified as a major woody bioenergy plant for bio-diesel production because of high oil content in seed. But the flowers do not bear fruit well while the many flowers blooming. This study was performed to regenerate in vitro plantlet using adventitious shoot formation. To establish the protocol of plant regeneration, adventitious shoots formation rate in the culture of cotyledon of immature zygotic embryos was 68.6% in 1/2 MS medium with 0.5 mg l-1 BA and 3% sucrose (w/v). In the culture of cotyledons of mature zygotic embryos, induction of adventitious shoots was needed to contain high sucrose in pre-culture medium and the frequency of shoot induction was 64.4%. Multiple shoots were induced in 0.5 mg l-1 TDZ, and rooting of shoot was induced 4.0 mg l-1 IBA. Flow cytometry analysis revealed that all the regenerated plantlets were diploid.

• 한국자동차공학회논문집
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• 제22권5호
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• pp.59-65
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• 2014

Diesel engines have the superior combustion efficiency and fuel economy that they are widely used for industry, heavyduty vehicles, etc. However, its exhaust emissions have become the major concerns due to their environmental impacts. Moreover, the depletion of fossil fuels is the main issue. Therefore, it is important to look for alternative sources of energy. Bio-diesel is one of the ideal energy which has proved to be ecofriendly for more than fossil fuels. The experimental tests analysed the engine performance and emission characteristics of a diesel engine using diesel and biodiesel blended of BD25, BD45 and BD65, in order to study the use of clean fuel to meet the increasingly stringent emission regulations. The engine performance was examined by using engine dynamometer while an exhaust gas analyzer was used to examine the emission characteristics. The effect of biodiesel on engine performance were lower to diesel through comparing their HP and torque but fuel consumption was slightly increased because of biodiesel has lower heating value and higher density than diesel. However, due to the better lubricity, the brake thermal efficiency of biodiesel was higher than diesel. The emission characteristics were strongly affected by the blending ratio of diesel and biodiesel. The results showed that the smoke opacity, hydrocarbons (HC) and carbon monoxide (CO) emissions decreased while the nitrogen oxides (NOX) slightly increased.

• 한국환경독성학회:학술대회논문집
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• 한국환경독성학회 2003년도 춘계학술대회
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• pp.195-195
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• 2003

It is well known that diesel exhaust particulate matter contains mutagenic PAHs, such as benzo[${\alpha}$]pyrene, benz[${\alpha}$]anthracene, chrysene, etc. Therefore it is suspected that these chemicals act on estrogen receptor and reveal endocrine-disrupting effects. Recent attention has focused on causative chemicals of endocrine-disrupting effects. We examined the estrogenic activity of respirable diesel exhaust particulate matter derived from diesel powered vehicle. PM2.5 diesel exhaust of vehicle was collected using a high volume sampler equipped with a cascade impactor. Diesel exhaust samples were fractionated according to EPA methods. The presence of estrogenic and antiestrogenic chemicals in PM 2.5 diesel exhaust was determined using E-screen assay. To quantitatively assess the estrogenic and antiestrogenic activities in diesel exhaust particulate matter, estradiol equivalent concentration (bio-EEQ) was calculated by comparing the concentration response curve of the sample with those of the estrogen calibration curve. Weak estrogenic activities and strong antiestrogenic activities were detected in the crude extract and moderately polar fractions. Higher antiestrogenic potency was observed with higher EROD activities in aliphatic and aromatic compounds fraction. In conclusion, estrogenic/antiestrogenic-like activities were present in diesel exhaust particulate matter. However, the health consequences of this observation was unknown, the presence of these activities may contribute to and exacerbate adverse health effect evoked by diesel exhaust particulate matter.