• Journal of the Korean Applied Science and Technology
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• v.27 no.3
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• pp.282-289
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• 2010

In preparation of silica aerogel-based hybrid coating materials, the combination of hydrophobic aerogel with organic polar binder material is shown to be very limited due to dissimilar surface property between two materials. Accordingly, the surface modification of the aerogel would be required to obtain compatibilized hybrid coating sols with homogeneous dispersion. In this study, the surface of silica aerogel particles was modified by using both surfactant adsorption and heat treatment methods. Four types of surfactants with different molecular weights and HLB values were used to examine the effect of chain length and hydrophilicity. The surface property of the modified aerogel was evaluated in terms of visible observation for aerogel dispersion in water, water contact angle measurement, and FT-IR analysis. In surface modification using surfactants, the effects of surfactant type and content, and mixing time as process parameter on the degree of hydrophilicity for the modified aerogel. In addition, the temperature condition in modification process via heat treatment was revealed to be significant factor to prepare aerogel with highly hydrophilic property.

• Textile Coloration and Finishing
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• v.35 no.3
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• pp.151-158
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• 2023

In this study, we investigated the durability properties of the recycled leather using shaving scrap with antioxidant. Recycled leather sheets were manufactured by mixing shaving scrap and NB latex as a binder. HALS(Hindered Amine Light Stabilizer) and UVA(UV absorbers) were used as antioxidant. Mechanical properties such as hardness, tensile strength, elongation, tear strength and abrasion resistance were measured. Light aging resistance was evaluated using UV lamp and the degree of discoloration of the recycled leather sheets using a gray scale. In addition, to evaluate heat aging and UV aging, the degree of discoloration of the recycled leather sheets over time was measured using colorimeter. Washing fastness was evaluated on the degree of dyeing of recycled leather sheets for six type of multi-fiber woven fabrics (Acetate, Cotton, Nylon-66, Polyester, Acryl, Wool). To determine whether hazardous substances were detected in recycled leather sheets, the contents of arylamine and Cr 6⁺ were evaluated. As a result, when used in combination with antioxidant, the heat aging and light aging of recycled leather were improved and hazardous substance were not detected.

• Journal of the Korea Concrete Institute
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• v.16 no.5 s.83
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• pp.621-626
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• 2004

The use of blast-furnace slag (BFS) in making not only normal concrete but also high-performance concrete has several advantages with respect to workability, long-term strength and durability. However, slag concrete tends to show more shrinkage than normal concrete, especially autogenous shrinkage. High autogenous shrinkage would result in severe cracking if they are not controlled properly. Therefore, in order to minimize the shrinkage stress and to ensure the service life of concrete structures, the autogenous shrinkage behavior of concrete containing BFS should be understood. In this study, small prisms made of concrete with water-binder (cement+BFS) ratio (W/B) ranging from 0.27 to 0.42 and BFS replacement level of $0\%$, $30\%$, and $50\%$, were prepared to measure the autogenous shrinkage. Based on the test results, thereafter, material constants in autogenous shrinkage prediction model were determined. In particular, an effective autogenous shrinkage defined as the shrinkage that contributes to the stress development was introduced. Moreover, an estimation formula of the 28-day effective autogenous shrinkage was proposed by considering various W/B's. Test results showed that autogenous shrinkage increased with replacement level of BFS at the same W/B. Interestingly, the increase of autogenous shrinkage is dependent on the W/B at the same content of BFS; the lower W/B, the smaller increasing rate. In concluding, it is necessary to use the combination of other mineral admixtures such as shrinkage reducing admixture or to perform sufficient moisture curing on the construction site in order to reduce the autogenous shrinkage of BFS concrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.3
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• pp.66-74
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• 2016

The aim of this research work is to investigate the mix proportion of multi-component cement incorporating ground granulated blast furnace(GGBFS), fly ash(FA) and silica fume(SF) as an addition to cement in ternary and quaternary combinations. The water-binder ratio was 0.45. In this study, 50% and 60% replacement ratios of mineral admixture to OPC was used, while series of combination of 20~40% GGBFS, 5~35% FA and 0~15% SF binder were used for fundamental characteristics tests. This study concern the GGBFS/FA ratio and SF contents of multi-component cement including the compressive strength, water absorptions, ultrasonic pulse velocity(UPV), drying shrinkage and X-ray diffraction(XRD) analysises. The results show that the addition of SF can reduce the water absorption and increase the compressive strength, UPV and drying shrinkage. These developments in the compressive strength, UPV and water absorption can be attributed to the fact that increase in the SF content tends basically to consume the calcium hydroxide crystals released from the hydration process leading to the formation of further CSH(calcium silicate hydrate). The strength, water absorption and UPV increases with an increase in GGBFS/FA ratios for a each SF contents. The relationship between GGBFS/FA ratios and compressive strength, water absorption, UPV is close to linear. It was found that the GGBFS/FA ratio and SF contents is the key factor governing the fundamental properties of multi-component cement.

• Journal of Conservation Science
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• v.29 no.1
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• pp.81-92
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• 2013

In the past, European material and method were applied to conservation of Buddhist mural paintings in Korea. At that time, there were inadequate to selection of materials in consideration of porosity and hydrophilicity, therefore insufficiency to assessing their suitability for materials. The treatment result of mural painting are dissatisfied with consolidation of painting layer using synthetic resin. Therefore, it has experimented on applying fixative for reinforcement of painting layer on Buddhist mural painting in order to establish the effects of conservation. In relationship of binder's viscosity, adhesion and penetrating depth, adhesion increased in high-viscosity specimen whereas it decreased in low-viscosity specimen. While the binder's penetrating depths show similar patterns, the surface's response and combination adjacent to painting layer have differences. Animal glue and methyl cellulose (MC) shows excellent performance in their reaction with soil and painting layer. It is estimated that the fixative penetrates deep into soil to produce a stable fixing effect. The viscosity of polyvinyl acetate resin (PVAc) and acrylic resins are low, and thus penetrates well into soil, but they adhere poorly to soil.

• Applied Chemistry for Engineering
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• v.7 no.6
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• pp.1132-1141
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• 1996

Heterogeneous cation exchange membrane(HCEM) was prepared with LLDPE(Linear Low Density Poly-ethylene) as binder, powdered cation exchange resins($diameter{\leq}149{\mu}m$) as ion-exchange material and glycerol as additive for electrodialysis and electrodeionization system. The weight ratio of (binder/ion exchange)/glycerol was (60%/40%)/5%, (55%/45%)/5%, (50%/50%)/5% and (40%/60%)/5%. The characterization of prepared HCEM was evaluated on mechanical, electrochemical, morphology and ion permeable properties. It was compared with commercial membrane. Electrochemical properties of HCEM of (50%/50% )/5% were very similar to value of IONPURE(commercial membrane), in which ion exchange capacity, ion transfer number and membrane resistance were to be 1.733meq/g, 0.96 and $16.08{\Omega}/cm^2$, respectively. Ion permeability of the membrane was better than that of IONPURE membrane. Compared with IONPURE membrane, the HCEM had a higher tensile strength and lower elongation and modulus, in which HCEM had tensile strength of $62.33kg/cm^2$, elongation of 87.42% and modulus of $658.53kg/cm^2$. The HCEM of (50%/50% )15% was optimum combination.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.400-406
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• 2023

In this study, the relationship between the material properties and air permeability characteristics was examined, an experimental method to analyze the air permeability characteristics was presented, and experimental results were derived. The effects of compressive strength and apparent density of hardened concrete on air permeability characteristics were evaluated experimentally. Focusing on the mix proportions used in nuclear power plant concrete structures, concrete test specimens were manufactured and air permeability characteristics were measured according to changes in binder, maximum aggregate size, and water-binder ratio. The apparent density was over 2,400 kg/m³ for the OPC mix and the FA-35 mix, and the air permeability for both mixes were low, in the range of 0.1-0.2 L/min. On the other hand, in the case of the combination of FA-40, FA-45, and FA-M, the apparent density was measured to be less than 2,400 kg/m³ and the air permeability was measured to be more than 0.3 L/min, experimentally verifying that the apparent density is an important factor in air permeability characteristics.

• Journal of the Korea Institute of Building Construction
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• v.15 no.6
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• pp.553-559
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• 2015

In this study, to suggest the application method of recycled fine aggregate, the non-cement mortar was prepared and studied with the binders of blast furnace slag, fly ash, and fly ash from combined heat power plant. As a basic experiment, a series of tests was conducted to determine the potions of the binders and types of activator. When the binder was consisted with 20% of fly ash and 40% of fly ash from combined heat power plant, the highest strength of the mortar was obtained, and as an activator, the combination of sodium hydroxide 2.5%, and calcium hydroxide 7.5% showed the highest strength of the mortar. Therefore, this study focuses on engineering properties of mortar contains fly ash from combined heat power plant and recycled fine aggregate according to replacement ratio of recycled fine aggregate based on the optimum mix from the basic experiment. As a result, the best replacement ratio of recycled fine aggregate is 75%.

• Journal of Environmental Health Sciences
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• v.29 no.1
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• pp.51-61
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• 2003

Pollution purification using titanium dioxide (TiO$_2$) photocatalyst has attracted a great deal of attention with increasing number of relent environmental problems. Currently, the application of TiO$_2$ photocatalyst has been focused on purification and treatment of waste water. However. the use of conventional TiO$_2$ powder photocatalyst results in disadvantage of stirring during the reaction and of separation after the reaction. And the usage of artificial UV lamp has made the cost of photocatalyst treatment system high. Consequently, we herein studied the pilot-scale design to aid in optimization of the energy-saving process for more through development and reactor design by solar light/UV lamp/ TiO$_2$system. In this study, we manufactured the TiO$_2$sol by sol-gel method. According to analysis by XRD, SEM and TEM, characterization of TiO$_2$ sol were nano-size (5-6 nm) and anatase type. Inorganic binder (SiO$_2$) was added to TiO$_2$ lot to be coated for support strongly, and support of ceramic bead was used to lower separation rate that of glass bead The influences were studied of various experimental parameters such as TiO$_2$ quantity, pH, flow rate. additives, pollutants concentration, climate condition and reflection plate by means of reaction time of the main chararteristics of the obtained materials. In water treatment system, variable realtor as solar light/ or UV lamp according to climate condition such as sunny and cloudy days treated the phenol and E-coli(Escherichia coli) effectively.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2002.11a
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• pp.87-91
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• 2002

This paper investigates the corrosion inhibition and the reduction of hydration heat properties of Ground Granulated Blast-Furnace Slag (GGBFS) added concrete. Since the massive civil structure is vulnerable to the thermal crack by hydration. adiabatic temperature rising tests were performed for water-binder ratios from 43.2% to 47.3%, while replacing 15% to 50% of cement with GGBFS of equal weight. Then, the corrosion protection performance was evaluated using cylindrical specimens embedded with steel reinforcement according to the combination of 3 W/B ratios and 2 levels of chloride ion quantity. The corrosion area of the embedded steel ban was determined using the high pressure steam curing method specified in KS F 2561. The test results showed that the replacement of GGBFS was effective in reducing the hydration heat. The corrosion area of the embedded steel ban decreased as the replacement of GGBFS increased. However, the corrosion area of the steel bar was proportional to the autoclave cycle and the chloride ion quantity. Among the tested specimens, compressive strength, reduction of hydration heat, and corrosion inhibition performance were excellent when 50% of cement was replaced with GGBFS of equal weight.