• Title/Summary/Keyword: Binary mixture

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A Comparative Study on the Characteristics of Binary Oxidized Carbon Nanofluids Based DI Water and Ethanol (물-에탄올 기반 이성분 산화탄소나노유체의 특성 비교 연구)

  • Park, Sung-Seek;Kim, Nam-Jin
    • Journal of the Korean Solar Energy Society
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    • v.32 no.6
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    • pp.85-92
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    • 2012
  • A nanofluid is a fluid containing suspended solid particles, with sizes on the order of nanometers. Normally, nanofluids have higher thermal conductivitiest han their base fluids. Therefore, we measured the thermal conductivity and viscosity of oxidized carbon nanofluids based the mixture of distilled water and ethanol (ethanol concentration is 0.2) oxidized carbon nanofluids were made by ultrasonic dispersing oxidized multi-walled carbon nanotubes in the mixture of distilled water and ethanol at the rates of 0.001~ 0.1 vol%. The thermal conductivity and viscosity of oxidized carbon nanofluids were measured by using transient hot-wire method and rotational digital viscometer, respectively. And all of experiments were carried out at the same temperature conditions($10^{\circ}C$, $25^{\circ}C$ and $70^{\circ}C$). As a result, when volume fraction of nanofluids is 0.1 vol%, thermal conductivity was improved 13.6% ($10^{\circ}C$), 15.1% ($25^{\circ}C$), and 17.0% ($70^{\circ}C$), and its viscosity was increased by 36.0% ($10^{\circ}C$), 32.9% ($25^{\circ}C$) and 19.5% ($70^{\circ}C$) than the base fluids.

Hydrodynamic Characteristics of Fine Powders in the Conical Powder-Particle Fluidized Beds (원추형 분립유동층에서 미세 분체의 수력학적 특성)

  • Lee Dong Hyun;Shin Moon Kwon;Kim Eun Mi;Son Seong Yong;Park Byung Sub;Han Gui Young;Yoon Ki June
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.310-313
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    • 2005
  • The conical fluidizing system of a binary mixture of Geldart C powders and Geldart A particles was defined as the conical powder-particle fluidized bed. We used a cold conical powder-particle fluidized bed model having a 0.104m-I.D. and 0.6m-high with an apex angle of $10^{\circ}$ for fluidization of a binary powder-particle mixture of 50 $vol\%$ fine carbon black powders (HI-900L, Korea Carbon Black Co.) and coarse alumina particles $(90{\mu}m)$ under different superficial gas velocities (0-0.1 m/s). The differential bed pressure drop increases with increasing gas velocity, and it goes from zero to a maximum value with increasing or decreasing gas velocity. In the conical fluidized beds of fine powders, demarcation velocities of the partial fluidization, full fluidization, partial defluidization was not observed.

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Measurement of Flash Points for n-hexanol+n-butyric acid and n-butanol+propionic acid by Seta-flash Closed Cup Method (Seta-flash 밀폐식 방법에 의한 n-hexanol+n-butyric acid 계와 n-butanol+propionic acid 계의 인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Society of Safety
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    • v.29 no.6
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    • pp.76-80
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    • 2014
  • The flash point is one of the most important physical properties used to determine the fire hazard of flammable liquid mixture and defined as the lowest temperature at which a liquid produces sufficient vapor to form a combustible mixture with air. The main purpose of this paper is to measure and predict the flash point of binary flammable miscible mixtures. The flash points for n-hexanol+n-butyric acid and n-butanol+propionic acid, were measured by using Seta-flash closed cup method. The experimentally derived data were correlated with the binary interaction parameters of the van Laar and NRTL equations through the optimization method. The flash points estimated by these correlations were compared with those calculated by the method based on Raoult's law. The optimization method were found to be better than the method based on the Raoult's law.

Observation on the Ignition Delay Time of Cool and Thermal Flame of n-heptane/alcohol Blended Fuel at Low Temperature Combustion Regime (저온연소조건에서 n-heptane/alcohol 혼합연료의 냉염과 열염에 대한 착화지연 관찰)

  • Song, Jaehyeok;Kang, Kijoong;Ryu, Seunghyup;Choi, Gyungmin;Kim, Duckjool
    • Journal of the Korean Society of Combustion
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    • v.18 no.4
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    • pp.12-20
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    • 2013
  • The ignition delay time is an important factor to understand the combustion characteristics of internal combustion engine. In this study, ignition delay times of cool and thermal flame were observed separately in homogeneous charge compression ignition(HCCI) engine. This study presents numerical investigation of ignition delay time of n-heptane and alcohol(ethanol and n-butanol) binary fuel. The $O_2$ concentration in the mixture was set 9-10% to simulate high exhaust gas recirculation(EGR) rate condition. The numerical study on the ignition delay time was performed using CHEMKIN codes with various blending ratios and EGR rates. The results revealed that the ignition delay time increased with increasing the alcohol fraction in the mixture due to a decrease of oxidation of n-heptane at the low temperature. From the numerical analysis, ethanol needed more radical and higher temperature than n-butanol for oxidation. In addition, thermal ignition delay time is sharply increasing with decreasing $O_2$ fraction, but cool flame ignition delay time changes negligibly for both binary fuels. Also, in high temperature regime, the ignition delay time showed similar tendency with both blends regardless of blending ratio and EGR rate.

Separation of 20(R&S) Prosapogenin Isomers of Ginsenoside-$Rg_2$ and -$Rg_3$ from Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography (인삼 사포닌에서 Ginsenoside-$Rg_2$와 -$Rg_3$의 이성질체인 20(R&S) Prosapogenin들의 역상 고속 액체 크로마토그래피에 의한 분리)

  • Jeong, Seung-Il;Kim, Cheon-Suk;Lee, Yong-Gu;Lee, Ho-Sup;Kim, Il-Kwang
    • Analytical Science and Technology
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    • v.11 no.5
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    • pp.404-408
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    • 1998
  • Using a reversed-phase high performance liquid chromatography, the separation of 20(S)-, 20(R)-prosapogenin stereo-isomers of ginsenoside-$Rg_2$ and of ginsenoside-$Rg_3$ in ginseng saponins has been carried out with binary solvent system. The optimum conditions for the isomer separation are as following: Nova-$Pak^{(R)}C_{18}$ (Waters, $3.9{\times}150mm$) column, $CH_3CN/CH_3CN$ (100:8, v/v) binary solvent system and the flow rate was 1.7 mL/min. The stereoisomers were separated with change of the mixture ratio of the solvent system, the solvent elution by gradient program, and then detected at 203 nm of UV detector. The simultaneous separation of mixture that were the $Rg_2$, $Rg_3$ isomers was easily performed in nonpolar solvent for $Rg_2$, polar solvent for $Rg_3$ at the same optimum conditions.

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Combustion Modeling of Nano/Micro Aluminum Particle Mixture (나노-마이크로 알루미늄 혼합 입자의 공기와의 연소 모델링)

  • Yoon, Shi-Kyung;Shin, Jun-Su;Sung, Hong-Gye
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.6
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    • pp.15-25
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    • 2011
  • One dimensional combustion modeling of aluminum combustion behavior is proposed. Combustion model is assumed that region consists as follows ; preheat, reaction, post reaction region. Flame speed as a function of particle size, equivalence ratio for unitary particles and fraction ratio of micro to nano particle size for binary particles were investigated for lean burn condition at 1 atm. Results were compared with experimental data. For unitary particles, flame speed increase as particle size decreases, but opposite trend with equivalence ratio. For binary particles, flame speed increases proportionally as nano particle fraction increases. For flame structure, separated or overlapping flames are observed, depending on the fraction of nano sized particles.

A Study on the Operating Characteristics and System Modelling of Closed Loop Type Thermosyphon (루프형태의 밀폐형 Thermosyphon의 작동특성과 시스템 모델링에 관한 연구)

  • Kang, M.C.;Kang, Y.H.;Lee, D.G.
    • Journal of the Korean Solar Energy Society
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    • v.22 no.2
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    • pp.39-47
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    • 2002
  • The thermosyphon SDHWS and the loop type thermosyphon systems are widely used for domestic hot water system. The loop type thermosyphon is a circulation device for transferring the heat produced at the evaporator to the condenser area in the loop. In this study, the operating characteristics of various working fluids being used have been identified. The working fluids employed in the study were ethanol. water, and a binary mixture of ethanol and water. The volume of working fluid used in this study were 30%, 40%, 50%, 60% and 70% of evaporator volume. It is observed that, in the thermosyphon with low volume of working fluid, such as 30% or 40%, the fluid was dried out. The flow pattern and mechanism of the heat transfer were identified through this study. Flow patterns of the binary mixture working fluid were also investigated, and the patterns were recorded in the camera. The system parameters were calculated using the thermal performance data. Modelling of the system was carried out using PSTAR method and TRNSYS program.

Condensation Heat Transfer Coefficients of Binary Refrigerant Mixtures on Enhanced Tubes (열전달 촉진관에서 2원 혼합냉매의 외부 응축열전달계수)

  • 김경기;서강태;채순남;정동수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.2
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    • pp.161-167
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    • 2002
  • In this study, external condensation heat transfer coefficients (HTCs) of two non-azeotropic refrigerant mixtures of HFC32/HFC134a and HF0134a/HCF0123 at various compositions were measured on both low fin and Turbo-C enhanced tubes of 19.0 mm outside diameter All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3- 8 K. Test results showed that HTCs of the tested mixtures on the enhanced tubes were much lower than the ideal values calculated by the mass fraction weighting of the pure compo- nents'HTCs. Also the reduction of HTCs due to the diffusion vapor film was much larger than that of a plain tube. Unlike HTCs of pure fluids, HTCs of the mixtures measured on enhanced tubes increased as the wall subcooling increased, which was due to the sudden break up of the vapor diffusion film with an increase in wall subcooling. Finally, heat transfer enhancement ratios for mixtures were found to be much lower than those of pure fluids.

Cast-Shadow Elimination of Vehicle Objects Using Backpropagation Neural Network (신경망을 이용한 차량 객체의 그림자 제거)

  • Jeong, Sung-Hwan;Lee, Jun-Whoan
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.7 no.1
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    • pp.32-41
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    • 2008
  • The moving object tracking in vision based observation using video uses difference method between GMM(Gaussian Mixture Model) based background and present image. In the case of racking object using binary image made by threshold, the object is merged not by object information but by Cast-Shadow. This paper proposed the method that eliminates Cast-Shadow using backpropagation Neural Network. The neural network is trained by abstracting feature value form training image of object range in 10-movies and Cast-Shadow range. The method eliminating Cast-Shadow is based on the method distinguishing shadow from binary image, its Performance is better(16.2%, 38.2%, 28.1%, 22.3%, 44.4%) than existing Cast-Shadow elimination algorithm(SNP, SP, DNM1, DNM2, CNCC).

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Significant Liquid Structure of Binary Mixture, $C_6H_6-C_2H_4Cl_2$ (이성분 액체 혼합물의 통계열역학적 연구)

  • Ahn, Woon-Sun;Pak, Hyung-Suk;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.9 no.4
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    • pp.215-221
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    • 1965
  • The significant liquid structure theory is extended to binary mixture, benzene-ethylenechloride system. The partition function, applicable throughout the temperature range in which Raoult's law is satisfied is derived. The thermodynamic quantities such as total and partial pressures, molar volumes and mixing entropies are calculated from the partition function at the temperatures $293.15^{\circ},\;323.14^{\circ}\;and\;357.15^{\circ}K.$ The theoretical values, thus calculated, are found to agree with the experimental data in the literatures.

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