• 제목/요약/키워드: Bimetallic oxoalkoxides

검색결과 1건 처리시간 0.017초

Synthesis and Characterization of Derivatives of Dibutyl Sn(IV)-Ti(IV)-μ-Oxoisopropoxide with Schiff Bases

  • Kumar, Rajesh;Sharma, H.K.
    • 대한화학회지
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    • 제56권1호
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    • pp.54-57
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    • 2012
  • New Schiff base derivatives of organoheterobimetallic-${\mu}$-oxoisopropoxide $[Bu_2SnO_2Ti_2(OPr^i)_6]$ have been synthesized by the thermal condensation ${\mu}$-oxoisopropoxide compound with Schiff bases in different molar ratios (1:1-1:4) yielded the compounds of the type $[Bu_2SnO_2Ti_2(OPr^i)_{6-n}(SB)_n]$ (where n is 1-4 and SB=Schiff base anion) respectively. The ${\mu}$-oxoisopropoxide derivatives have been characterized by elemental, spectral analysis (IR, $^1H$, $^{13}C$, $^{119}Sn$ NMR) and molecular weight measurement The studies reveal that the derivative compounds show monomeric nature. Further these are found less susceptible to hydrolysis as compared to parent compound and may prove excellent precursors for the mixed metal oxides.