• 제목/요약/키워드: Bi2223

검색결과 401건 처리시간 0.045초

Bi계 세라믹에서 초전도체 특성에 미치는 도우핑 원소의 영향 (Effect of Doping Elements on Superconducting Characteristics in Bi-system Ceramics)

  • 양승호;박용필;김용주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.198-203
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    • 2000
  • This paper investigated the effects of doping elements on the Bi-Sr-Ca-Cu-O ceramics. The doping elements can be classified into four groups depending on their superconducting characteristics in the Bi-Sr-Ca-Cu-O structure. The first group of doping elements(Co, Fe, Ni and Zn) substitute into the copper site and can reduce the critical temperatures of the 2223 and 2212 phases. The second group of doping elements(Y and La) substitute into the Ca site and cause the disappearance of the 2223 phase and increase the critical temperatures in the 2212 phase. The third group of doping elements(P and K) have a tendency to decompose the superconducting phase and reduce the optimal sintering temperature. The fourth group of doping elements(B, Si, Sn and Ba) almost unaffected the superconductivity of the 2223 and 2212 phase.

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Bi-Sr-Ca-Cu-O 세라믹의 도우핑 특성 (Deping characteristics of the Bi-Sr-Ca-Cu-O ceramics)

  • 박용필;김영천;황석영
    • E2M - 전기 전자와 첨단 소재
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    • 제9권1호
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    • pp.1-8
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    • 1996
  • We investigated the effects of doping elements on the Bi-Sr-Ca-Cu-O ceramics. The doping elements can be classified into four groups depending on their supeconducting characteristics in the Bi-Sr-Ca-Cu-O structure. The first group of doping elements(Co, Fe, Ni and Zn) substitute into the copper site and can reduce the critical temperatures of the 2223 and 2212 phases. The second group of doping elements(Y and La) substitute into the Ca site and cause the disappearance of the 2223 phase and increase the critical temperatures in the 2212 phase. The third group of doping elements(P and K) have a tendency to decompose the superconducting phase and reduce the optimal sintering temperature. The fourth group of doping elements(B, Si, Sn and Ba) almost unaffected the superconductivity of the 2223 and 2212 phase.

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고온초전도 BSCCO 2223상 형성시 나타나는 여러 가지 이차상들이 선재의 임계전류에 미치는 영향(토요일)

  • 박성창;김철진;유재무;고재웅;김영국
    • 한국결정학회:학술대회논문집
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    • 한국결정학회 2003년도 춘계학술연구발표회
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    • pp.24-24
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    • 2003
  • 고온초전도 BSCCO 2223 ((Bi, Pb)₂Sr₂Ca₂Cu₃O/sub x/) 선재의 특성을 향상시키기 위해서는 반복적인 인발 및 압연과정을 통한 texturing향상, BSCCO 2223입자의 배향성 증대, 피복재내 초전도체의 충진율(밀도)향상, 이차상의 부피분율 감소등이 이루어져야 한다. 최적 열처리 조건을 통하여 열처리 시에 형성되는 이차상인 (Bi,Pb)₂Sr₂CuO/sub y/ (2201, amorphous phase)를 조절하면서, (Ca,Sr)₂CuO₃ (2/1 AEC), (Ca,Sr)/sub 14/Cu/sub 24/O/sub 41/ (14/24 AEC)와 같은 이차상들의 부피분율 및 크기를 감소시켜야만 한다. 본 실험에서는 BSCCO 2223 선재의 특성을 향상시킬수 있는 최적의 열처리 조건 확립 및 기계적 공정시 나타나는 여러 가지 문제점을 개선하여 높은 임계전류를 가지는 선재의 특성을 분석하고자 하였다. 최종적으로 제조된 선재는 2223상 결정이 피복재(Ag)와 평행하게 길게 성장하며, AEC상의 크기와 부피분율이 감소할수록 더 높은 임계전류특성을 나타내었다(I/sub c/~70A, J/sub c/~42,000 A/㎠). 또한 이 선재에서 나타나는 여러 가지 이차상들을 분석하기 위하여 XRD, SEM, EDS 분석을 행하였다.

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단결정 형성을 위한 열역학 분석 (Analysis of Thermodynamics for Single Crystal Formation)

  • 천민우;양승호;박용필
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 학술대회 및 기술세미나 논문집 디스플레이 광소자
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    • pp.70-73
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    • 2006
  • High quality $Bi_2Sr_2Ca_nCu_{n+1}O_x$ superconducting thin films fabricated by using the evaporation method at various substrate temperatures, $T_{sub}$, and ozone gas pressures, $pO_3$. The correlation diagrams of the $Bi_2Sr_2Ca_nCu_{n+1}O_x$ phases with $T_{sub}$ and $pO_3$ are established in the 2212 arid 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 as well as Bi2212 phases come out as stable phases depending on $T_{sub}$ and $pO_3$. From these results, the thermodynamic evaluation of ${\Delta}H$ and ${\Delta}S$, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase, was performed.

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Investigation of $I_c$ Degradation Behavior in Bent Bi-2223 Tapes under Pressurized Liquid Nitrogen using a $\rho-shaped$ Sample Holder

  • Shin Hyung-Seop;Dizon John Ryan C.;Choi Ho-Yeon;Ha Dong-Woo;Oh Sang-Soo
    • 한국초전도ㆍ저온공학회논문지
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    • 제7권4호
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    • pp.4-9
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    • 2005
  • The degradation behavior of the critical current $(I_c)$ of Bi-2223 superconducting tapes under pressurized liquid nitrogen were investigated using a newly developed p-shaped sample holder which gives a series of bending strains to a sample. Three kinds of commercially available multi-filamentary Bi-2223 superconducting tapes were used. At atmospheric pressure, the Ie degradation behavior depended on the manufacturing process undergone by each tape. The tapes externally reinforced or densified by over pressure showed better bending strain tolerance than the Ag alloy-sheathed Bi-2223 tape. But these tapes showed a significant $I_c$ degradation when pressurized to 1 MPa in liquid nitrogen. For all samples, after depressurization to atmospheric pressure from 1 MPa, the Ie was completely recovered to its initial values at atmospheric pressure. When the samples were subjected to a thermal cycle wherein the tape was warmed up to room temperature after being depressurized from 1 MPa, it was found that the larger degradation of $I_c$ occurred at the regions where significant ballooning occurred, such as $0\%\;and\;0.2\%$. However, an improved ballooning damage tolerance was observed in the highly-densified tape.

액체질소로 냉각된 Bi-2223 선재의 퀜치 전파 특성에 관한 연구 (A Study on the Quench Propagation Properties of Bi-2223 Wire cooled in Liquid Nitrogen)

  • 윤경용;배덕권;안민철;강형구;이찬주;윤용수;이상진;고태국
    • 한국초전도ㆍ저온공학회논문지
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    • 제7권1호
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    • pp.32-36
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    • 2005
  • With the successful commercialization of Bi-2223 powder-in-tube wire , various attempts in the R & D of the high-Tc superconducting (HTS) magnets for high magnetic field applications are being implemented actively. Operating temperature of HTS magnet has to be maintained at the designed level but the magnetic energy and mechanical disturbance can cause unstable operational temperature of HTS magnet. Especially the generated heat energy of inner HTS winding Is apt to be accumulated . so the normal region appears in HTS winding. This paper deals with the quenching characteristics of three kinds of selected Bi-2223 wires : the High Current Density Wire (HC-A) and the High Strength Wire (HS-A) made by AMSC and HTS wire(HW-I) made by Innost The Innost wire has the highest minimum quench energy (MQE). The High Current Density Wire has the highest normal zone Propagation velocity (NZPV).

고온초전도선재 제초기술과 개발 동향 (Manufacturing technology and R&D status of high temperature superconducting wire)

  • 오상수;하동우;하홍수;박찬;송규정;고락길;권영길;류강식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.67-73
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    • 2002
  • The development of high performance HTS wire is a key factor for various electrical applications of coils and cables. The purpose of this paper is to review and consider the main manufacturing technologies of HTS wire and its current status. A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. According to this, long Bi-2223 wires having Ic of 130 A were recently produced and their mass production has been underway in US. The current status performance of Bi-2223 wire is supposed to be used in power transmission cable because of its lower self-field property. Y-123 second generation conductor is extensively being developed throughout the world and many fabrication processes are competed with each other. 30 m-long Y-123 wire with Ic of 0.8 MA/$\textrm{cm}^2$ was recently fabricated using IBAD and PLD techniques in Japan. This result offers promise of scalable processing of practical multi-layer coated conductor.

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초전도자석 충전용 고온초전도전원장치의 특성해석 (Analysis of the Operational Characteristic of a High-Tc Superconducting Power Supply for Charging of the Superconducting Magnet)

  • 윤용수;김호민;안민철;배덕권;고태국
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제51권4호
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    • pp.159-164
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    • 2002
  • This paper presents the design and fabrication of a high-Tc superconducting (HTS) power supply for charging of the HTS magnet load, and its characteristics have been analyzed through experiments. HTS power supply consists of two heaters, an electromagnet, a Bi-2223 solenoid and a Bi-2223 pancake magnet load. In this experiment, 331 mH electromagnet and 0.8 A dc heater current were used, and 8.5 sec and 17 sec were used for pumping period. Mechanism of the superconducting switch is used for heater-trigger. In order to measure the pumping-current with respect to the magnet flux changes, hall sensor was installed at the center of the Bi-2223 pancake load. The experimental observations have been compared with the theoretical predictions. In this experiment, the pumping-current has reached about 1.2 A. In computer simulation, the maximum pumping-current of the system has been predicted to be about 2.7 A.

The effect of mechanical working on processing the Bi-2223/Ag tapes using PIT method

  • Oh, S.S.;Ha, D.W.;Kim, S.C.;Bae, S.W.;Kwon, Y.K.;Ryu, K.S.;Ha, H.S.
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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    • pp.276-279
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    • 2000
  • When high temperature superconducting tapes is fabricated using the PIT (Powder In Tube) method, the length of HTS tapes is increased more than 500 ${\sim}$ 1,000 times of initial powder packed billet. On mechanical processing, heterogeneous properties between the ceramic superconducting core and Ag/Ag alloy sheath occur the non-uniformity deformation as like sausaging that deteriorate the critical current properties of HTS tapes. In this study, we investigated the workability of Bi-2223/Ag/Ag alloy sheath tapes fabricated by the PIT method involving a number of different mechanical processes, multi drawing and rolling. In order to obtain the high critical current density and high uniformity of Bi-2223/Ag sheath tapes, the influences of powder packing density, drawing die angle and rolling parameters were studied. We found that the roll diameter is an important variable in the rolling process, as critical current of tapes rolled using 250 mm rolls was higher than that using 150 mm rolls.

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자장방향이 적층 Bi-2223도체의 자화손실에 미치는 영향 (Effect of Field Orientation on Magnetization Loss in a Stacked Bi-2223 Conductor)

  • 류경우;김현준
    • 한국전기전자재료학회논문지
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    • 제16권1호
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    • pp.77-82
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    • 2003
  • The ac loss is an important issue in the design of high-Tc superconducting power devices such as transformers and cables. In these devices many Bi-2223 tapes are closely stacked together and exposed to alternating magnetic fields that can have different orientations with respect to a tape. In such arrangement the magnetization loss is influenced by the screening current induced in adjacent tapes and thus different from that in a single tape. This stacking effect was experimentally investigated by measuring the magnetization loss in a stack, which consists of a number of tapes. First the magnetization loss in the single tape was measured in order to confirm the reliability of the loss data measured in the stack. The results for the single tape coincide well will the loss characteristics described in other previous works. For the stack In parallel and longitudinal magnetic fields the measured loss is Independent of both the number of tapes and stacking type. The longitudinal magnetization loss Is well explained rather by the slab model for decoupled filaments. For the tall stack in perpendicular field the measured loss at low fields is greatly decreased, compared to the loss of the single tape. However the loss at high fields is unaffected. These loss behaviors in the tall stack are well described by the slab model for full coupling.