• Journal of Powder Materials
• /
• v.30 no.6
• /
• pp.509-515
• /
• 2023

Lead-free perovskite ceramics, which have excellent energy storage capabilities, are attracting attention owing to their high power density and rapid charge-discharge speed. Given that the energy-storage properties of perovskite ceramic capacitors are significantly improved by doping with various elements, modifying their chemical compositions is a fundamental strategy. This study investigated the effect of Zn doping on the microstructure and energy storage performance of potassium sodium niobate (KNN)-based ceramics. Two types of powders and their corresponding ceramics with compositions of (1-x)(K,Na)NbO₃-xBi(Ni_2/3Ta_1/3)O₃ (KNN-BNT) and (1-x)(K,Na)NbO₃-xBi(Ni_1/3Zn_1/3Ta_1/3)O₃ (KNN-BNZT) were prepared via solid-state reactions. The results indicate that Zn doping retards grain growth, resulting in smaller grain sizes in Zn-doped KNN-BNZT than in KNN-BNT ceramics. Moreover, the Zn-doped KNN-BNZT ceramics exhibited superior energy storage density and efficiency across all x values. Notably, 0.9KNN-0.1BNZT ceramics demonstrate an energy storage density and efficiency of 0.24 J/cm³ and 96%, respectively. These ceramics also exhibited excellent temperature and frequency stability. This study provides valuable insights into the design of KNN-based ceramic capacitors with enhanced energy storage capabilities through doping strategies.

• Korean Journal of Materials Research
• /
• v.31 no.10
• /
• pp.562-568
• /
• 2021

(Bi_1/2Na_1/2)TiO₃ (BNT)-based ceramics are considered promising candidates for actuator application owing to their excellent electromechanical strain properties However, to obtain large strain properties, there remain several issues such as thermal stability and high operating fields. Therefore, this study investigates a reduction of operating field in (0.98-x)Bi_1/2Na_1/2TiO₃-0.02 BiAlO₃-xSrTiO₃ (BNT-2BA-100xST, x = 0.20, 0.21, 0.22, 0.23, and 0.24) via analyses of the microstructure, crystal structure, dielectric, polarization, ferroelectric and electromechanical strain properties. The average grain size of BNT-${\underline{2}}$BA-100xST ceramics decreases with increasing ST content. Results of polarization and electromechanical strain properties indicate that a ferroelectric to relaxor state transition is induced by ST modification. As a consequence, a large electromechanical strain of 592 pm/V is obtained at a relatively low electric field of 4 kV/mm in 22 mol% ST-modified BNT-2BA ceramics. We believe that the materials synthesized in this study are promising candidates for actuator applications.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2003.10a
• /
• pp.119-122
• /
• 2003

This report describes the procedure of detailed design and structural test for the composite flexure which is a part of the hingeless hub system. First, stacking sequence design for composite flexure was done, and structural analysis by using NASTRAN was made to verify structural stability and safety. Using FPS installed at KIMM, composite flexure was laid up and cured using a autoclave. Before rotor ground test, the basic structural tests such as a bench test, tensile strength test and shear strength test, for flexure, were accomplished. Through replacing existing metal hub part with new fabricated composite flexure, improvement of aeroelastic stability and weight reduction were achieved. This result will be applied to composite rotor system design fur helicopter.

• The Pure and Applied Mathematics
• /
• v.23 no.3
• /
• pp.237-246
• /
• 2016

Ebadian et al. proved the Hyers-Ulam stability of bimultipliers and Jordan bimultipliers in C*-ternary algebras by using the fixed point method. Under the conditions in the main theorems for bimultipliers, we can show that the related mappings must be zero. Moreover, there are some mathematical errors in the statements and the proofs of the results. In this paper, we correct the statements and the proofs of the results, and prove the corrected theorems by using the direct method.

• Proceedings of the SAREK Conference
• /
• 2006.06a
• /
• pp.1144-1149
• /
• 2006

Electric power is generated by Seeback Effect if there is thermal difference in pettier module. Peltier module is composed by alumina, Bi-Te semiconductor and insulation (or air). If load is increased in pettier module, the alumina of module will be destroyed. One of the preventing method of module destruction is using damper between module and heat source. But the electric Power is dropped because of decrease of thermal difference, if thermal conductivity of damper was tourer than other thermoelectric materials. We design, Polymer Pad for enhancing thermoelectric porter. As the result of these experiment, Polymer Pad is more superior than the Rubber in the stability and thermal conduction.

• Journal of the Korean Electrochemical Society
• /
• v.3 no.4
• /
• pp.204-210
• /
• 2000

The control of dissolved aluminum concentration in the hot dip zinc galvanizing bath is greatly important in producing galvannealed steel sheets. The purpose of present study is to provide basic data for measurement of the aluminum concentration in site in hot dip zinc bath at the temperature of $460^{\circ}C\~500^{\circ}C$ using $CaF_2$ solid electrolyte sensor with three kinds of reference electrode. Good workability and stability of the sensor were confirmed with the $Bi+BiF_3$ reference electrode from the emf measurement. In order to measure the aluminum concentration in Zn-Al bath, the galvanic cell of fluorine ion was constructed with $CaF_2$ solid electrolyte as follows; $$(-)W|Zn-Al,\;AlF_3|CaF_2|Bi,BiF_3|W(+)$$. The emf measurement was made at the temperature of $460\pm10^{\circ}C$ in the Zn-Al bath. The following correlationship between aluminum concentration and emf was obtained by the least square regression analysis; $$E/mV=56.795log[\%Al]+1881.7\;R=0.9704$$,$$0.026wt\%{\leq}[\%Al]{\leq}0.984wt\%$$

• Korean Journal of Materials Research
• /
• v.22 no.1
• /
• pp.1-7
• /
• 2012

Thin film electrode consisting purely of porous anodic tin oxide with well-defined nano-channeled structure was fabricated for the first time and its electrochemical properties were investigated for application to an anode in a rechargeable lithium battery. To prepare the thin film electrode, first, a bi-layer of porous anodic tin oxides with well-defined nano-channels and discrete nano-channels with lots of lateral micro-cracks was prepared by pulsed and continuous anodization processes, respectively. Subsequent to the Cu coating on the layer, well-defined nano-channeled tin oxide was mechanically separated from the specimen, leading to an electrode comprised of porous tin oxide and a Cu current collector. The porous tin oxide nearly maintained its initial nano-structured character in spite of there being a series of fabrication steps. The resulting tin oxide film electrode reacted reversibly with lithium as an anode in a rechargeable lithium battery. Moreover, the tin oxide showed far more enhanced cycling stability than that of powders obtained from anodic tin oxides, strongly indicating that this thin film electrode is mechanically more stable against cycling-induced internal stress. In spite of the enhanced cycling stability, however, the reduction in the initial irreversible capacity and additional improvement of cycling stability are still needed to allow for practical use.

• Structural Engineering and Mechanics
• /
• v.70 no.1
• /
• pp.113-123
• /
• 2019

In the classical stability investigation of rectangular plates the classical thin plate theory (CPT) is often employed, so omitting the transverse shear deformation effect. It seems quite clear that this procedure is not totally appropriate for the investigation of moderately thick plates, so that in the following the first shear deformation theory proposed by Meksi et al. (2015), that permits to consider the transverse shear deformation influences, is used for the stability investigation of simply supported isotropic rectangular plates subjected to uni-axial and bi-axial compression loading. The obtained results are compared with those of CPT and, for rectangular plates under uniaxial compression, a novel direct formula, similar to the conventional Bryan's expression, is found for the Euler stability stress. The accuracy of the present model is also ascertained by comparing it, with model proposed by Piscopo (2010).

• Journal of the Korean Society of Manufacturing Technology Engineers
• /
• v.20 no.4
• /
• pp.412-418
• /
• 2011

Reliability-based Topology optimization(RBTO) is to get an optimal design satisfying uncertainties of design variables. Although RBTO based on homogenization and density distribution method has been done, RBTO based on BESO has not been reported yet. This study presents a reliability-based topology optimization(RBTO) using bi-directional evolutionary structural optimization(BESO). Topology optimization is formulated as volume minimization problem with probabilistic displacement constraint. Young's modulus, external load and thickness are considered as uncertain variables. In order to compute reliability index, four methods, i.e., RIA, PMA, SLSV and ADL(adaptive-loop), are used. Reliability-based topology optimization design process is conducted to obtain optimal topology satisfying allowable displacement and target reliability index with the above four methods, and then each result is compared with respect to numerical stability and computing time. The results of this study show that the RBTO based on BESO using the four methods can effectively be applied for topology optimization. And it was confirmed that DLSV and ADL had better numerical efficiency than SLSV. ADL and SLSV had better time cost than DLSV. Consequently, ADL method showed the best time efficiency and good numerical stability.

• Journal of Pharmaceutical Investigation
• /
• v.37 no.2
• /
• pp.79-84
• /
• 2007

This study was aimed to establish analytical method of Bi to develop a guideline of the bioequivalence test of tripotassium dicitrato bismuthate (TDB). For this purpose, a simple, specific and sensitive inductively coupled plasma-mass spectrometry (ICP/MS) method were developed and validated in human plasma. Various concentrations of bismuth standard solution (0-25ng/mL) were prepared with distilled water and human blank plasma. To 10mL of the volumetric flasks, 2mL of blank plasma was added with 8ml of distilled water. Bi standard solution was added to prepare the calibration samples and injected into ICP-MS. The plasma samples obtained from volunteers given 3 tablets of bismuth (total 900mg as TDB) were analyzed as described above. As a result, the coefficients of variation were <20% in quantitation limit (0.2 ng/mL) and <15% at the rest of concentrations. The stability test by repeated freezing-thawing cycles showed that the samples were stable only for 24hr. The stability tested for samples with a short-term period of storage at room temperature and pre-treatment prior to the analysis showed very stable over 24hr. In 8 healthy Korean subjects received Denol tablets at the dose of 900mg bismuth, AUC, $C_{max},\;T_{max}$ and half-life $(t_{1/2})$ were determined to be $198.33{\pm}173.78 ng{\cdot}hr/mL,\;64.48{\pm}27.06 ng/mL,\;0.52{\pm}0.21 hr,\;and\;5.15{\pm}2.67 hr$, respectively, from the plasma bismuth concentration-time curves. In conclusion, the method was suitable for the determination of bismuth in human plasma samples and could be applied to bioequivalence test of bismuth tablet.