• Title/Summary/Keyword: Bentonite

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A Study on the Swelling Property of Bentonite Mat under Salt Water Condition (담수환경하에 노출된 일반 벤토나이트 매트재의 팽윤성능 평가)

  • 양승도;김영삼;유재강;오상근
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2002.05a
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    • pp.81-84
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    • 2002
  • Recently Bentonite mat is applied various structure : External waterproofing for underground structure, A reclaimed land, Artificial lake, Large-scaled civil structure, etc. With these various structure environment, water quality for application of Bentonite Mat affects watertightness. Specially spot with a large quantity of Chloride ion like salt water, degree of watertightness revelation is evaluated and applied. In this study, it is a main goal to investigate watertightness of Bentonite Mat with distilled water and salt water dissolved chloride ion Contents 0.88%. The result of this paper is as follows. 1) Water permeability coefficient of Bentonite Mat : distilled water(1.21$\times$10$^{-9}$cm/sec), salt water(3.12$\times$10$^{-7}$cm/sec). 2) Variation of thickness : distilled water(187%), salt water(108%). 3) Swelling ratio : distilled water(1500%), salt water(350%).

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Efficient Optimum Design of Reinforced Concrete Structures using the Mixed-Discrete Optimization Method

  • Kim, Jong-Ok
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.2
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    • pp.32-43
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    • 1997
  • Abstract A series of permeability tests was performed on the mixtures with specific mixing rates of sand and bentonite using modified rigid-wall permeameter. Sand-bentonite mixtures were permeated by organics, ethanol and TCE. Permeability of bentonite with several mixing rates had a tendency to decrease up to initial one pore volume and permeability was thereafter converged to a constant value. When sand-bentonite mixtures was permeated by water, permeability was decreased at the beginning but it was thereafter converged to a constant. Among several mixing rates, permeability was greatly decreased at 15% of mixing rate. When sand-bentonite mixtures with 15% mixing rate was permeated by ethanol, permeability was about 10 times larger value than permeability of water. Peameability was shown greater values when permeated by TCE (TrichloroEthylene) followed by ethanol. Suitable mixing rate of sand-bentonite for a liner of waste landfills was detected.

HDTMA-Bentonite로부터 페놀류 화합물의 경쟁탈착

  • 신원식;김영규;송동익
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.15-18
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    • 2001
  • Sorption/desorption studies were conducted to determine sorption/desorption characteristics of phenolic compounds (phenol and 4-chlorophenol) in organically modified natural bentonite. The cationic exchange capacity (CEC) of bentonite was exchanged with a cationic surfactant, hexadecyltrimethylammonium (HDTMA), to enhance the removal capacity of organic phenol contaminants dissolved in aqueous solution. This modification produces a change of the surface property of bentonite from hydrophilic to organophilic. The single-solute and bi-solute competitive adsorptions were performed In batch mode to investigate the removal of two toxic organic Phenols, chlorophenol and 4-chlorophenol on the HDTMA-bentonite. The adsorption affinity of the 4-chlorophenol was higher than phenol due to higher octanol:water partition coefficient (Kow). The single-solute and bi-solute competitive desorptions were also performed investigate the competitive desorption of the phenolic compounds from HDTMA-bentonite. Freundlich model was used to analyze the single-solute adsorption/desorption results, while the IAST model predicted the hi-solute adsorption/desorption equilibria. The IAST model well predicted hi-solute competitive adsorption/desorption behaviors.

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Improvement of Adsorbability of Methylene Blue on Bentonite Treated with Electrolyte Solution (Bentonite의 전각질수용액 처리에 의한 Methylene Blue 흡착성 개선)

  • 신병식;김면섭
    • Journal of the Korean Ceramic Society
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    • v.11 no.2
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    • pp.11-16
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    • 1974
  • Korean Yung-il bentonite was treated with potassium chloride, zinc chloride, calcium chloride, ferric chloride, or chromic chloride solutions respectively varying their concentration, treating temperature and treating time. The adsorbabilities of methylene blue on these pretreated bentonite were investigated. In the case of treatment with potassium chloride solution, the improvement of the adsorbahility of methylene blue on the products was observed, and in the best result the adsorbability was 1.6 times better than that on the original bentonite. With zinc chloride solution, the optimum adsorbability was a value of 1.7 times better than that on the original bentonite. With ferric chloride, chromic chloride or calcium chloride solution, slight improvement of the adsorbability was observed.

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A Study on Fatty Acid Profiles of Eggs in Older Laying Hens fed Diets Supplemented with Bentonite (벤토나이트를 산란노계 사료에 첨가시 계란의 지방산조성에 관한 연구)

  • Choi, In Hag
    • Journal of Environmental Science International
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    • v.27 no.5
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    • pp.341-344
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    • 2018
  • This study was conducted to determine the effects of dietary bentonite supplementation on the fatty acid profiles of eggs in older laying hens. A total of 90 Hy-line Brown layers, 74 weeks of age, were confined in 6 wire cages and then assigned randomly to two groups to receive one of the two diets (3 replicates of 15 older layers each) containing 0 and 0.2% bentonite for 4 weeks. After the 4-week feeding trial, no remarkable differences in individual fatty acid, saturated fatty acid (SFA), unsaturated fatty acid (UFA), and mono unsaturated fatty acid (MUFA) levels were found. However, linoleic acid, docosahexaenoic acid, and poly unsaturated fatty acid (PUFA) and UFA/SFA ratio were influenced by 0.2% bentonite. In conclusion, supplementation with 0.2% bentonite improved the profiles of PUFA more than those of SFA, UFA, and MUFA inthe eggs of the older laying hens.

복합오염물질제거를 위한 현장반응층 이용에 관한 연구

  • 조현희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.168-171
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    • 2003
  • This research was conducted to assess the performance of the mixed reactive materials with sand, iron filings, and HDTMA-bentonite for trichloroethylene (TCE) and chromate removal under controlled groundwater flow conditions. TCE and chromate removal rates with the mixtures of iron filing/HDTMA-bentonite were highest among four columns due to reduction by iron filings and sorption by HDTMA-bentonite. The greater capacity of the mixed iron filing/HDTMA-bentonite compared HDTMA-bentonite was due to an enhanced chromate reduction in addition to chromate sorption. The presence of chromate caused greater inhibition of TCE removal in the column with iron filings, while the presence of TCE caused less inhibition of TCE. Also, nitrate caused the decrease in TCE removal relative to chloride. Nitrate ions may also significantly affect TCE reduction rates by competing for electrons with the chlorinated compounds. The anion and co-existed contaminants competing effects should be considered when designed permeable reactive barriers (PRBs) composed of zero valent iron for field applications to remediate TCE and chromate.

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The Purification Characteristics of Reactive Soil-Bentonite Landfill Liner (혼합반응 차수재의 오염정화특성)

  • 김학문
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.4
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    • pp.398-403
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    • 2003
  • The purpose of this paper is to investigate purification characteristic of soil-bentonite landfill liner and to develop a desirable liner system. In order to clarify the purification characteristics, high pressure column tests using soil-bentonite, reactive soil-bentonite and reactive bentomat were carried out in the presence of water and leachate. The test results indicated that the significant amount of NH$_3$-N, Pb and Cu was removed through the reactive soil-bentonite liner system.

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Numerical Simulations of the Moisture Movement in Unsaturated Bentonite Under a Thermal Gradient

  • Park, J.W.;K. Chang;Kim, C.L.
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.62-72
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    • 2001
  • The one-dimensional finite element program was developed to analyze the coupled behavior of heat, moisture, and air transfer in unsaturated porous media. By using this program, the simulation results were compared with those from the laboratory infiltration tests under isothermal condition and temperature gradient condition, respectively. The discrepancy of water uptake was found in the upper region of a bentonite sample under isothermal condition between numerical simulation and laboratory experiment. This indicated that air pressure was built up in the bentonite sample which could retard the infiltration velocity of liquid. In order to consider the swelling phenomena of compacted bentonite which cause the discrepancy of the distribution of water content and temperature, swelling and shrinkage factors were incorporated into the finite element formulation. It was found that these factors could be effective to represent the moisture diffusivity and unsaturated hydraulic conductivity due to volume change of bentonite sample.

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Hydraulic Conductivity of Bentonite-Sand Mixture for a Potential Backfill Material for a High-level Radioactive Waste Repository

  • Cho, Won-Jin;Lee, Jae-Owan;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.32 no.5
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    • pp.495-503
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    • 2000
  • The hydraulic conductivities in the bentonite-sand mixtures with high density were measured, and the effects of sand content and dry density on the hydraulic conductivity were investigated. The hydraulic conductivities of the bentonite-sand mixtures with a dry density of 1.6 Mg/㎥ and 1.8 Mg/㎥ are less than 10$^{-11}$ m/s when the sand content is not higher than 70 wt%. However at the sand content of 90 wt%, the hydraulic conductivity increases rapidly At the same dry density, the logarithm of hydraulic conductivity increases linearly with increasing sand content. The hydraulic conductivity of the bentonite-sand mixture can be explained by the concept of effective clay dry density, and using this concept, the hydraulic conductivities for the mixtures with various sand contents and dry densities can be estimated.

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Effect of Bentonite Type on Thermal Conductivity in a HLW Repository

  • Lee, Gi-Jun;Yoon, Seok;Cho, Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.3
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    • pp.331-338
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    • 2021
  • Extensive studies have been conducted on thermal conductivity of bentonite buffer materials, as it affects the safety performance of barriers engineered to contain high-level radioactive waste. Bentonite is composed of several minerals, and studies have shown that the difference in the thermal conductivity of bentonites is due to the variation in their mineral composition. However, the specific reasons contributing to the difference, especially with regard to the thermal conductivity of bentonites with similar mineral composition, have not been elucidated. Therefore, in this study, bentonites with significantly different thermal conductivities, but of similar mineral compositions, are investigated. Most bentonites contain more than 60% of montmorillonite. Therefore, it is believed that the exchangeable cations of montmorillonite could affect the thermal conductivity of bentonites. The effect of bentonite type was comparatively analyzed and was verified through the effective medium model for thermal conductivity. Our results show that Ca-type bentonites have a higher thermal conductivity than Na-type bentonites.