• 제목/요약/키워드: Bench-scale reactor

검색결과 77건 처리시간 0.022초

내부순환반응기의 Scale-up에 따른 동력학적 특성의 변화 (Dynamic Behavior of an Internal Loop Reactor during Scale-up)

  • 최윤찬;박영식
    • 한국환경과학회지
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    • 제6권1호
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    • pp.25-31
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    • 1997
  • The variations of gas hold-up, overall volumetric oxygen mass transfer coefficients and liquid circulation velocity in an internal loop reactor were investigated to manifest scale-up effect. The relationship between superficial gas velocity and gas hold-up were found as Ugr = 0.045 $\varepsilon$r in the pilot-scale and Ugr = 0.056 $\varepsilon$r in the bench-scale reactor. The overall volumetric oxygen mass tractsfer coefficient, KLa was slightly increased in the pilot-scale than in the bench-scale reactor. Flow regime was changed from the bubble flow to the churn-turbulent flow when the superficial gas velocity reached to 3.5 - 4 cm/sec in the pilot-scale.

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KIER 액화 기술 개발 현황 (KIER Liquefaction R & D's status)

  • 양정일;양정훈;이호태;천동현;김학주;정헌
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.110.1-110.1
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    • 2010
  • A bench scale slurry bubble column reactor (SBCR) with active-Fe based catalyst was developed for the Fischer-Tropsch synthesis (FTS) reaction. Considering the highly exothermic reaction heat generated in the bench scale SBCR, an effective cooling system was devised consisting of a U-type dip tube submerged in the reactor. Also, the physical and chemical properties of the catalyst were controlled so as to achieve high activity for the CO conversion and liquid oil ($C_{5+}$) production. Firstly, the FTS performance of the FeCuK/$SiO_2$ catalyst in the SBCR under reaction conditions of $265^{\circ}C$, 2.5 MPa, and $H_2/CO=1$ was investigated. The CO conversion and liquid oil ($C_{5+}$) productivity in the reaction were 88.6% and 0.226 $g/g_{cat}-h$, respectively, corresponding to a liquid oil ($C_{5+}$) production rate of 0.03 bbl/day. To investigate the FTS reaction behavior in the bench scale SBCR, the effects of the space velocity and superficial velocity of the synthesis gas and reaction temperature were also studied. The liquid oil production rate increased upto 0.057 bbl/day with increasing space velocity from 2.61 to 3.92 $SL/h-g_{Fe}$ and it was confirmed that the SBCR bench system developed in this research precisely simulated the FTS reaction behavior reported in the small scale slurry reactor.

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실험실 수준의 반응조 온도가 양돈폐수중 질소, 인의 처리에 미치는 영향 (Effect of Temperature on Treatment of Nitrogen and Phosphorus of Pig Wastewater in Bench Scale Reactor)

  • 박석환
    • 한국환경보건학회지
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    • 제21권1호
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    • pp.86-92
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    • 1995
  • This study was performed to evaluate the effect of temperature on operating parameters for reactor in pig wastewater treatment using sequencing batch reactor method which is one of the biological treatment methods. Study was accomplished by experimental apparatus of bench scale, and the degradation rate coefficient and temperature correction factor were derived. The followings are the conclusions that were derived from this study. 1. In the characteristics of pig wastewater, concentrations of TKN and T-P were very high as 590 mg/l and 40 mg/l, respectively. 2. Removal efficiency of BOD and $COD_{Mn}$ as organic compound indicators were the highest mark as 97% at 25$\circ$C. 3. When temperature was incresed from 10$\circ$C to 25$\circ$C, removal efficiencies of TKN and T-P were proportionally increased. Especially, the former was greatly effected by temperature of reactor. 4. In experiment of bench scale, the degradation rate coefficients were increased as temperature increased, but decreased at the temperature range of 25~35$\circ$C. Temperature adjustment coefficients for $COD_{Mn}$, BOD, TKN and T-P were 1.1460, 1.1356, 1.1140 and 1.0565, respectively.

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SBR 및 MBR 복합공정을 적용한 Bench-scale Shipboard STP에서의 미생물 우점종에 관한 연구 (A Study on Microorganism Dominant Species in Bench-scale Shipboard STP Using Combined SBR and MBR Process)

  • 최영익;신대열;사나 만수르;권민지;정진희;정병길
    • 한국환경기술학회지
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    • 제19권6호
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    • pp.550-555
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    • 2018
  • 국제 해사기구 (IMO)에서 MARPOL 73/78은 조문과 여섯 개의 부속서로 구성되어 있다. Annex IV는 선박의 하수를 규제한다. 2012년 제 64회 결의안에서 선박에서 배출되는 하수 중 영양염류를 제거하도록 규제하였다. 2014년 해양수산부의 지원으로 영양염류를 제거 할 수 있는 대용량 폐수처리 장치를 개발하였다. Sequence Batch Reactor (SBR)와 Membrane Bio Reactor (MBR)를 결합한 새로운 공정이 개발되었다. 현존하는 SBR 공정의 사이클에서는 침전을 제외하고 통기 및 교반만을 사용하였고, 상기 막은 처리 된 물을 배출 시키는데 사용하였다. 본 연구에서는 MACROGEN 사의 NGS 분석 기술을 이용하여 Bench 규모 폐수처리 설비를 이용한 하수처리장 원수를 처리하기 위한 최적 운전조건에서 폭기조 내 미생물의 우점종을 분석하였다. 그 결과 Bacteroidetes는 호기성 박테리아의 27.1 %를 차지했으며 Gammaproteobacteria는 혐기성 박테리아의 16.8 %를 차지하였다. Operational taxonomic unit ratio에 Others 항목이 차지하는 비율도 상당하다고 볼 수 있는데 기존의 오수처리를 위해 필요했던 미생물 외에 아직 NCBI (National center for Biotechnology Information)에 등록되지 않은 미생물일 가능성이 있어 추후 연구가 필요하다고 판단된다.

Bench-scale 고압반응기 내의 미세액적분사에 따른 $SF_6$ 하이드레이트 형성 거동 연구 (Study on $SF_6$ hydrate Formation and Dissociation Behavior inside of Bench-scale High Pressure Reactor)

  • 문동현;이재정;신형준;이주동;이강우
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.687-690
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    • 2009
  • 본 연구에서는 가스 하이드레이트 형성과정에서 발생할 수 있는 유도지체시간을 줄이고 전체 가스 저장량과 반응 속도의 향상을 위하여 이류체 분사 방식을 이용하여 물분자의 액적을 최소화하는 실험을 통하여, 미세액적 분사에 따른 하이드레이트 형성 시간을 확인하였으며, 반응기 내부의 온도 변화를 확인하여 반응기 내부의 하이드레이트 형성 거동을 확인하고 이를 통하여 상용화를 위한 반응기 설계의 기초 자료로 활용하고자 하였다.

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연속회분식반응조를 이용한 생물학적인 인 제거 연구 (Biological Phosphorus Removal using the Sequencing Batch Reactor Process)

  • 양형재;신응배;정윤철;최훈근
    • 한국물환경학회지
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    • 제16권4호
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    • pp.533-539
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    • 2000
  • A bench-scale reactor using SBR process was experimented with an synthetic wastewater. The main purpose of this investigation was to evaluate applicability in the field and process removal efficiencies in terms of BOD and T-P and its corresponding kinetic parameters. Removal rate of phosphorus was 77% in terms of total phosphorus. Effluent concentrations were $9.8mg/{\ell}$ BOD and $1.1mg/{\ell}$ T-P. Effluent quality was maintained consistently stable by controlling decant volume and operating cycles. The efficiency for phosphorus removal was increased due to decrease in BOD-SS loading value in the range of $0.25{\leq}$aeration time ratio${\leq}0.52$.

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SI 열화학싸이클 황산분해공정의 Bench-scale 상압 실험 (Bench-scale Test of Sulfuric Acid Decomposition Process in SI Thermochemical Cycle at Ambient Pressure)

  • 전동근;이기용;김홍곤;김창수
    • 한국수소및신에너지학회논문집
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    • 제22권2호
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    • pp.139-151
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    • 2011
  • The sulfur-iodine (SI) thermochemical water splitting cycle is one of promising hydrogen production methods from water using high-temperature heat generated from a high temperature gas-cooled nuclear reactor (HTGR). The SI cycle consists of three main units, such as Bunsen reaction, HI decomposition, and $H_2SO_4$ decomposition. The feasibility of continuous operation of a series of subunits for $H_2SO_4$ decomposition was investigated with a bench-scale facility working at ambient pressure. It showed stable and reproducible $H_2SO_4$ decomposition by steadily producing $SO_2$ and $O_2$ corresponding to a capacity of 1 mol/h $H_2$ for 24 hrs.

염수 전기분해와 연계한 이산화탄소의 전환 공정 연구 (A Study on a Process for Conversion of Carbon Dioxide through Saline Water Electrolysis)

  • 이동욱;이지현;이정현;곽노상;이수진;심재구
    • Korean Chemical Engineering Research
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    • 제55권1호
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    • pp.86-92
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    • 2017
  • 석탄 화력발전 연소 배가스에 포함된 이산화탄소를 염수의 전기분해를 통해 얻어진 가성소다와 반응시켜 중탄산나트륨, 염소, 수소 등을 생산하는 공정에 대하여 실험과 전산모사를 병행하였다. Bench 규모 공정을 디자인하여 가성소다에 의한 이산화탄소 전환 공정에 대하여 실험하였고 같은 공정을 공정 모델링을 통해 전산모사 하였다. 실험결과와 전산모사 결과의 비교를 통해 모델의 신뢰성을 확인하였고, 상용급 공정에 대한 모델링을 수행하였다. 상용급 공정에 대한 열 및 물질수지를 계산하였고 반응기내 온도분포와 $CO_2$ 흡수율을 도출하였다. 본 연구를 통해 온실가스 저감뿐만 아니라 $CO_2$ 전환을 통한 경제성까지 갖춘 본 공정에 대한 기술 신뢰성을 확보할 수 있을 것이다.

반복학습을 이용한 회분식 반응기의 제어 (Control of a batch reactor using iterative learning)

  • 조문기;방성호;조진원;이광순
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1991년도 한국자동제어학술회의논문집(국내학술편); KOEX, Seoul; 22-24 Oct. 1991
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    • pp.81-86
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    • 1991
  • The iterative learning operation has been utilized in the temperature Control of a batch reactor. A generic form of feedback-assisted first-order learning control scheme was constructed and then various design and operation modes were derived through convergence and robustness analysis in the frequency domain. The proposed learning control scheme was then implemented on a bench scale batch reactor with the heat of reaction simulated by an electric heater. The results show a great improvement in the performance of control as the number of batch operations progressed.

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Control of a batch reactor by learning operation

  • Lee, Kwang-Soon;Cho, Moon-Khi;Cho, Jin-Won
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1990년도 한국자동제어학술회의논문집(국제학술편); KOEX, Seoul; 26-27 Oct. 1990
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    • pp.1277-1283
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    • 1990
  • The iterative learning control synthesized in the frequency domain has been utilized for temperature control of a batch reactor. For this purpose, a feedback-assisted generalized learning control scheme was constructed first, and the convergence and robustness analyses were conducted in the frequency domain. The feedback-assisted learning operation was then implemented in a bench scale batch reactor where reaction heat is simulated using an electric heater. As a result, progressive reduction of temperature control error could be obviously observed as batch operation is repeated.

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