• Title/Summary/Keyword: Bench-scale

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Characteristics of Agricultural Paddy Soil Contaminated by Lead after Bench-scale In-situ Washing with FeCl3 (납 오염 논토양의 원위치 세척을 위한 FeCl3의 Bench-scale 적용성 평가: 세척전후 토양 특성변화)

  • Koh, Il-Ha;Kim, Gi Suk;Chang, Yoon-Young;Yang, Jae-Kyu;Moon, Deok Hyun;Choi, Yulim;Ko, Myoung-Soo;Ji, Won Hyun
    • Journal of Soil and Groundwater Environment
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    • v.22 no.1
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    • pp.18-26
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    • 2017
  • In a previous study, we assessed the feasibility of ferric chloride ($FeCl_3$) as a washing agent in bench-scale in-situ soil washing to remove Pb from agricultural paddy soil. Herein is a subsequent study to evaluate variations in soil properties after $FeCl_3$ soil washing in terms of fractionation and bioavailability of Pb and chemical properties of the soil. After soil washing, the soil pH decreased from 4.8 to 2.6 and the exchangeable fractions of Pb in the soil increased from 12 mg/kg to 15 mg/kg. Variations in the Pb fractionation of the soil increased Pb bioavailability by almost three-fold; however,the base saturation decreased by 75%. The concentrations of total nitrogen and available phosphate were similar before and after soil washing. The available silicate concentration significantly increased after soil washing but was two times lower than that of soil washed with HCl, which is widely used as a washing agent. This indicates that $FeCl_3$ can be an acceptable washing agent that protects the soil clay structure. The results suggest that soil amendment, such as liming, is needed to recover soil pH, reduce mobility of Pb, and provide exchangeable bases of Ca, Mg, and K as essential elements for the healthy growth of rice plants in reused soil that has been washed.

Performance comparison of acidogenic fermentation and hydrogen fermentation using bench-scale leaching-bed reactors for food waste (벤치스케일 침출상 반응조를 이용한 음식폐기물 처리 시 신발효 및 수소발효의 거동특성 비교)

  • Han, Sun-Ki
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.3
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    • pp.97-105
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    • 2007
  • This study was conducted to compare the performances of acidogenic fermentation and hydrogen fermentation using bench-scale leaching-bed reactors for organic solid waste. Acidogenic fermenters were operated with dilution rates (D) of 2.0, 3.0 and $4.0d^{-1}$ after employing anaerobic sludge and hydrogen fermenters were operated with D of 2.0, 4.0 and $6.0d^{-1}$ after employing heat-treated anaerobic sludge. The highest chemical oxygen demand (COD) conversion efficiency (56.2%) was obtained in acidogenic fermentation with D of $3.0d^{-1}$. Only volatile fatty acid (VFA) was produced as a metabolite. On the other hand, hydrogen fermentation did not show higher COD conversion efficiency (49.3%) than acidogenic fermentation, but it produced hydrogen gas (5.1% of total COD) which was a clean and environmentally friendly fuel with a high energy yield. Therefore, either acidogenic fermentation or hydrogen fermentation could be applied to organic solid waste depending on the purpose of treatment, which could maximize the economics of anaerobic treatment.

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A Study on a Process for Conversion of Carbon Dioxide through Saline Water Electrolysis (염수 전기분해와 연계한 이산화탄소의 전환 공정 연구)

  • Lee, Dong Woog;Lee, Ji Hyun;Lee, Junghyun;Kwak, No-Sang;Lee, Sujin;Shim, Jae-Goo
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.86-92
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    • 2017
  • A process, which converts carbon dioxide contained in the flue gas of coal-fired power plants to sodium bicarbonate, was studied experimentally and numerically. In this process, the carbon dioxide reacts with sodium hydroxide which is produced through saline water electrolysis. A bench scale reactor system was prepared for experiments of this process and numerical process modeling was performed for the bench scale reactor system. Comparing the process modeling results with the experimental data, responsibility of the process modeling was confirmed. Using this model, commercial scale process was simulated. Mass and energy balance of this process were calculated. Temperature profile in the reactor and carbon dioxide removal rate were obtained.

Analysis of the Control Variables for Natural Gas Liquefied Process Using Mixed Refrigerant (혼합냉매를 이용한 천연가스 액화공정의 제어변수 분석)

  • Lee, Jae Yong;Kim, Mun-Hyun;Park, Chan-Cook
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.51-57
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    • 2013
  • The process of liquefied natural gas is less then $-160^{\circ}C$ to natural gas by cooling at atmospheric pressure. When control strategy was made, one of the most significant is analysis of process. It is important to understand the control variable change according to manipulated variable change. In this study, we experiment natural gas liquefied process using C3MR(Propane Pre-cooled Mixed Refrigerant) process by BSU(Bench Scale Unit). We analyzed the change of refrigerant temperature and natural gas temperature according to the change of refrigerant flow rate so as to search an influence flow rate according to adjust each manipulated variables. One of the manipulated variable affected a number of control variables, but were able to confirm a control variable with a large response.

Study of performance improvement in bench scale auxiliary bioelectrochemical anaerobic digestion for application suitability verification (보조 미생물전기화학적 혐기성소화의 적용적합성 검증을 위한 bench scale에서의 성능향상 연구)

  • Yang, Hyeon Myeong;Cheon, A In;Kim, Min Ji;Cha, Ji Hwan;Jun, Hang Bae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.397-397
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    • 2022
  • 오늘날 급격한 인구증가 및 도시화로 인해 음식물류 폐기물 발생량이 크게 증가하였으며, 음식물류 폐기물에서 발생되는 음폐수의 적절한 처리방안에 대한 관심이 증가하였다. 혐기성 소화(Anaerobic digestion; AD)는 음폐수의 바람직한 처리방법으로 알려졌지만, 긴 처리기간 및 공정 불안정 등의 문제로 개선이 필요하며, 그 중 기존 AD에 보조 반응조를 추가한 보조 미생물전기화학적 혐기성소화(Auxiliary bioelectrochemical anaerobic digestion; ABEAD)가 적절한 개선방안으로 제시되었다. 하지만 아직 20 L 이상 용량에서의 연구는 이뤄지지 않았으며, 따라서 본 연구에서는 100 L의 용량에서 ABEAD의 성능향상을 평가하고 규모증가에 따른 성능변화를 비교하였다. 반응조는 AD와 ABEAD로 구성되었다. 유효용량 100 L, 유기물부하율 4 kg/m3/d, HRT 20 days 및 중온소화(35℃) 조건으로 운전하였으며, AD는 기계적 교반, ABEAD는 기계적 교반 및 펌프를 통한 bulk 용액 순환이 이뤄졌다. ABEAD의 전극재질은 SUS304를 사용하였고, 0.4V의 전압을 공급하였다. 성능비교는 pH, 휘발성지방산(Volatile fatty acids; VFAs), 유기물제거율 및 메탄 생성량을 비교해 수행하였다. 실험결과 AD는 pH 및 VFAs가 각각 평균 7.37 및 3,880 mg/L, ABEAD는 각각 평균 7.5 및 2,870 mg/L로 VFAs의 빠른 처리를 통해 공정안전성 향상되었고, 유기물제거율 및 메탄생성량의 경우 AD는 각각 평균 65.8 % 및 85.1 L/d, ABEAD는 각각 평균 76.1 % 및 108.1 L/d로 유기물의 빠른 처리 및 메탄전환이 이루어져 비교적 큰 규모에서도 ABEAD의 성능향상이 나타남을 확인하였다. 또한 이전 소규모 연구들과 비교를 통해 규모에 따른 성능향상폭을 비교했을 때에도 큰 차이가 나지 않는 것으로 판단되며, 따라서 ABEAD는 BEAD 기술의 상용화 및 적용에 적합한 것으로 사료된다.

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Bench-scale Experiment on Catalytic Decomposition of 1,2 Dichlorobenzene by Vanadia-Titania Catalyst

  • Jeong, Ju-Young;Chin, Sung-Min;Jurng, Jong-Soo
    • Journal of Environmental Science International
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    • v.18 no.7
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    • pp.709-714
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    • 2009
  • Catalytic activities of $V_2O_5/TiO_2$ catalyst were investigated under reaction conditions such as reaction temperature, catalyst size, inlet concentration and space velocity. A 1,2-dichlorobenzene(1,2-DCB) concentrations were measured in front and after of the heated $V_2O_5/TiO_2$ catalyst bed, and conversion efficiency of 1,2-DCB was determined from it's concentration difference. The conversion of 1,2-DCB using a pellet type catalyst in the bench-scale reactor was lower than that with the powder type used in the micro flow-scale reactor. However, when the pellet size was halved, the conversion was similar to that with the powder type catalyst. The highest conversion was shown with an inlet concentration of 100 ppmv, but when the concentration was higher or lower than 100 ppmv, the conversion was found to decrease. Complete conversion was obtained when the GHSV was maintained at below 10,000 $h^{-1}$, even at the relatively low temperature of $250^{\circ}C$. Water vapor inhibited the conversion of 1,2-DCB, which was suspected to be due to the competitive adsorption between the reactant and water for active sites.