• Title/Summary/Keyword: Bench-scale

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Evaluation of Cooling Water Corrosion Inhibitors by the Electrical Resistance Method (전기저항법에 의한 공업용수 부식억제제의 성능시험)

  • W. K. Min
    • Journal of the Korean Chemical Society
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    • v.7 no.4
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    • pp.251-253
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    • 1963
  • Six corrosion inhibitors for cooling water use were evaluated by means of a corrosometer in a laboratory bench scale test. A steel probe (Alloy 1020) was exposed and checked for the extent of corrosion in a recirculating water system, changing inhibitors and their concentrations at $40^{\circ}C$. A 95% inhibition was provided at the following concentrations of inhibitors. 50 ppm sodium hexametaphosphate 50 ppm commercial inhibitor A 50 ppm commercial inhibitor B 100 ppm disodium phosphate 200 ppm sodium chromate Sodium silicate was found to be use-less in this test. It was also observed that some inhibitors worked less effectively on the acid-cleaned steel probe.

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Analysis of Electrocoagulation Process using Faraday's Law (Faraday's Law에 의한 전기응집공정의 분석)

  • Kim, Hye-Sook;Yun, Young-Im;Cho, Eun-Jeong;Choi, Yun-Hee;Oh, Mi-Young;Kim, Yeong-Kwan
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.351-355
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    • 2001
  • This research was carried out to find out the possibility of using Faraday's law in analyzing the electrocoagulation system. Bench-scale reactor equipped with aluminum electrode plates was operated using synthetic wastewater which received sodium chloride for conductivity adjustment. Phosphate was added to the wastewater to induce the precipitation with Al. The amount of aluminum dissolved from the electrodes could be predicted by Faraday's law with a difference less than 5%. This difference was greater at a higher electric current, probably due to the increased solution temperature. However, effect of pH on the dissolution of the aluminum was negligible. The result of this study suggested that the operating condition of electrocoagulation system could be developed using the Faraday's law when the pollutant concentration is given.

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Effect of Foulant Characteristics on Membrane Fouling Index (오염물질의 특성이 막오염 지수에 미치는 영향)

  • Park, Chanhyuk;Kim, Hana;Hong, Seungkwan
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.6
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    • pp.775-780
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    • 2005
  • This study was performed to investigate the effect of foulant characteristics on Membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI). A linear relationship was found relating the fouling index (both SDI and MFI) on particle concentration, but fouling index values were nonlinearly (exponentially) with increasing organic concentration. When organic matter was the primary cause of fouling, the MFI was not accurately predicted due to internal fouling such as pore adsorption. The fouling index was determined mainly by particle characteristics when both particle and organic coexisted in the feed water. This observation was attributed to lessening of organic pore adsorption by particle cake layer formed on the membrane surface. Bench-scale actual fouling experiments demonstrated that permeate flux declines much faster with feed water containing particles than organic matters although fouling potential predicted by SDI values were identical, indicating that the accurate prediction of fouling potential requires the development of fouling index reflecting different foulant characteristics.

Effect of pH and Iron/Manganese Ion on TiO2 Mediated Photocatalytic Inactivation of Index Microorganisms (LNAPL을 이용한 지중 산소전달 향상: (I) Abiotic Condition)

  • Ha, Jeong-Hyub;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.3
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    • pp.307-311
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    • 2004
  • The objective of this work is to evaluate the hypothesis that a good technique for supplying oxygen to the saturated zone in the presence of light nonaqueous phase liquid (LNAPL) pool contamination at the water table is to pass air through the unsaturated zone above the pool. This hypothesis was evaluated in experimental studies performed using a bench-scale, sand-tank reactor, Steady-state abiotic experiments in the sand-tank reactor with air flowing through the reactor headspace demonstrated that oxygen supply through the water table interface into the saturated zone was enhanced when an LNAPL (dodecane) pool was present at the water table. These experimental results confirmed the hypothesis that an LNAPL pool can serve as a high concentration oxygen source to the oxygen-limited area beneath the pool and, as a result, enhance the in situ biodegradation rate.

Combined Effects of Metal Coagulants and Monochloramine on Polyamide RO Membrane Performance (금속성 응집제와 모노클로라민의 상호작용이 Polyamide계 RO막 성능에 미치는 영향)

  • Kim, Kyunghwa;Hong, Seungkwan;Park, Chanhyuk;Yoon, Seongro;Hong, Seongpyuo;Lee, Jonghwa
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.4
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    • pp.637-643
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    • 2006
  • The bench-scale chlorine exposure study was performed to investigate the effect of pretreatment by free chlorine and monochloramine ($NH_2Cl$) on the performance of RO membranes made of polyamide (PA). Feed monochloramination at 2mg/L did not cause significant productivity loss compared to free chlorine. However, metal coagulants reacted with monochloramine, the PA membrane suffered from a gradual loss of membrane integrity by chlorine oxidation, which was characterized as a decrease in salt rejection. Especially, RO membranes exposed to alum coagulants with monochloramine revealed the salt rejection lower than those exposed to iron coagulants. XPS membrane surface analysis demonstrated that the chlorine uptake on the membrane surface increased and carbon peaks were shifted significantly when exposed to alum coagulants with monochloramine.

Treatment of ground waters in a hollow-fibre liquid membrane contactor for removal of ions

  • Hossain, Md. M.
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.95-108
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    • 2013
  • Metal ions exist in seawater, groundwater and industrial wastewaters. These source waters can be recycled if their concentrations are reduced. A number of processes can be applied for this purpose. Liquid-liquid extraction is one of the promising methods. In this paper, experimental results are presented on the removal of Cr(VI) using Aliquat-336, a reactive carrier, in sunflower oil (a non-toxic solvent). The performance of this new system is compared with those of kerosene (a toxic solvent). The extent of removal of Cr(VI) from samples with high and low concentrations are presented. The process was upgraded to a bench-scale module that can selectively remove about 50-90% Cr(VI) from samples of groundwater. Thus this process can produce water within the acceptable range for recycling and for use in secondary purposes such as irrigation.

Pilot Plant Study on Biological Nutrient Removal of Wastewater

  • Ahn, Sang-Jin;Kim, Geon-Heung;Ahn, Bok-Kyoun
    • Korean Journal of Hydrosciences
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    • v.1
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    • pp.99-106
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    • 1990
  • An extensive biological nutrient removal pilot plant study of anoxic/anaerobic/ aerobic treatment process was conducted to eastblish an optimum operational mode using primary dffluent. Two operational modes, (1) Qr/Q was 3.0 and maintaining EMLSS of 3100 mg/L in which the best operational results were obtained from previous bench scale study using synthetic wastewater (2) Qr/Q was 0.5 and EMLSS of 2200 mg/L which was compatible with the main plant, were Compared and evaluated for removal of nitrogen and/or phosphorous under field conditions. The nitrogen removal increased with increasing recycle ratios, but the phosphorous removal revealed more consistent results with 83percent removal efficiency in the second mode compared with 80 percent in the first mode. Above all, the two modes equally showed good BOD and nitrogen removals by nitrification-denitrification processes. It was also observed that no scum formed in the pilot plant and the sludge exhibited excellent settling characteristic all the time. The modified biological nutrient removal train can be adopted to the main plant without any major changes of their operational modes.

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Autrophic Denitrification of Bank Filtrate Using Elemental Sulfur (황을 이용한 강변여과수의 독립영양탈질)

  • 문희선;남경필;김재영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.209-212
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    • 2000
  • As a bench-scale study, transformation of nitrate to nitrogen gas under anoxic condition was determined by using autotrophic denitrifiers containing Thiobacillus denitrificans and elemental sulfur as an electron donor. The research objective is to measure the basic kinetic parameters of autotrophic denitrification reaction on the removal efficiency of nitrate. The results showed that nitrate was almost completely transformed to nitrite in the first 4 days of column operation. After 2 days of accumulation of nitrite, its concentration slowly decreased and the compound was detected less than 0.5 mg/L in 14 days. In the experiment, sulfate concentration in the effluent was the 70~90 mg-S/L and the pH was maintained around pH 7.5. When nitrate concentration of bank filtrate in the real field is considered, this sulfate concentration seems to be acceptable. At 17 cm from the bottom of the column, the effluent showed the highest nitrite concentration, and nitrate concentration decreased rapidly to the Point of 33 cm from the bottom. The results suggest that an appropriate thickness of permeable reactive barriers is about 30 cm.

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유류오염토양 정화를 위한 생물활성 촉진방법의 평가

  • Kim Jong-Ha;Kim Tae-Seung;Yun Jeong-Gi;Kim Hyeok
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.211-214
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    • 2005
  • Bench-scale experiments conducted to evaluation of the biostimulation and bioaugmentation techniques in treatment of petroleum contaminated soil. The soil bioreactors were operated for a 52 day-period. PDB population in the stimulated treatments increased from $7{\times}10^4MPN/g$ soil in zero day to $7{\times}10^7MPN/g$ soil after 23 days. However, despite the initially higher PDB population in the augmented treatments, it was decreased PDB population with respect to time. The average biodegradation rate in the augmented treatments were greater than of the stimulated treatment in the early stage, but the average biodegradation rate in the latter stage were calculated $3{\sim}5mg/kg-day$ in the augmented treatments and 10.38mg/kg-day in the stimulated treatments. The TPH removal rate was calculated $20{\sim}30%$ in the augmented treatments and 53% in the stimulated treatments.

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Fire Simulation by Pyrolysis Method of FDS for the Small Cone Calorimeter (ISO 5660) (FDS 열분해 모델을 이용한 콘칼로리미터(ISO 5660) 화재 시뮬레이션)

  • Yang, Sung-Jin;Jang, Jung-Hun;Kang, Chan-Yong
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.206-212
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    • 2009
  • Chemical behaviors of each surface material for interior facilities affect to fire initiation and growth in general fire situation. These chemical behaviors were characterized by thermal properties (Heat release rate, Pyrolysis rate, specific heat, etc) which could be derived from experimental test. Especially, Heat release rate which indicates aspect of fire size is one of the most important property to asses fire hazard and protection needs. The cone calorimeter test (ISO 5660) has recently assumed to a dominant role in bench scale fire testing to obtain the Heat release rate of materials. This value could be calculated by the 'Oxygen Consumption Method' under various producing irradiances to each surface of materials. In this study, Process of the cone calorimeter test was simulated by Pyrolysis model of FDS (Fire Dynamics Simulator by NIST) base on the ISO 5660 international standard. Then, we could estimate the simulation method of FDS in case of single materials through the comparative study with test results.

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