• 대한화학회지
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• 제6권1호
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• pp.1-9
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• 1962

高純度의 $UO^2$ pellets나 或은 $UF_4$를 얻는 것을 目標로 하여 그 計劃의 一郡으로 純粹한 $UO_2^{++}$ 溶液을 $U^{+4}$溶液으로 電解還元하는 方法을 實驗하였다. 現在 實施되고 있는 方法으로서는 純粹한 $UO_3$粉末을 水素 或은 ADU(ammonium diuranate)를 熱分解하여 生成되는 分解된 암모니아로서 600 내지 900$^{\circ}C$ 還元하거나 혹은 복잡한 構造를 가진 Excer cell로서 濕式電解하는 方法들이 있다. 이 報告는 從來의 Excer cell을 改造하여 水銀陰極과 陽이온 交換樹脂의 膈膜 및 鉛陽極으로 구성되는 간단한 電解裝置로서 $UO_2^{++}$ 溶液을 連續的으로 電解시켰을 때 가장 適合한 電解槽의 構造, 電解液의 溫度, 電解液의 種類와 濃度 또 各 流量과 電流密度에 따르는 電流效率, 電解槽電壓等을 測定한 結果를 記錄하고 電解反應을 說明한 것이다. 實驗結果에 依하면 電解槽는 水平式으로 하여 길이와 폭의 比가 20對 1이고 電解液은 還元에 所要될 때 理論量 以上의 遊離黃酸이 共存하는 可及的 高農度의 $UO_2SO_4$ 溶液과 그에 比例하는 電流密度를 使用하여 電解함으로써 單一過程의 電解에 依하여 $UO_2^{++}$ 를 $U^{+4}$로 80 내지 95%의 電流效率로서 還元시킬 수 있다는 것을 알았다.

• Steel and Composite Structures
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• 제28권2호
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• pp.223-231
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• 2018

Nowadays, there are a great number of various structures that have been retrofitted by using different FRP Composites. Due to this, more researches need to be conducted to know more the characteristics of these structures, not only that but also a comparison among them before and after the retrofitting is needed. In this research, a model steel structure is tested using a bench-scale earthquake simulator on the shake table, using recorded micro tremor data, in order to get the dynamic behaviors. Columns of the model steel structure are then retrofitted by using GFRP composite, and then tested on the Quanser shake table by using the recorded micro tremor data. At this stage, it is needed to evaluate the dynamic behaviors of the retrofitted model steel structure. Various types of methods of OMA, such as EFDD, SSI, etc. are used to take action in the ambient responses. Having a purpose to learn more about the effects of GFRP composite, experimental model analysis of both types (retrofitted and no-retrofitted models) is conducted to evaluate their dynamic behaviors. There is a provision of ambient excitation to the shake table by using recorded micro tremor ambient vibration data on ground level. Furthermore, the Enhanced Frequency Domain Decomposition is used through output-only modal identification. At the end of this study, moderate correlation is obtained between mode shapes, periods and damping ratios. The aim of this research is to show and determine the effects of GFRP Composite implementation on structural responses of the model steel structure, in terms of changing its dynamical behaviors. The frequencies for model steel structure and the retrofitted model steel structure are shown to be 33.916% in average difference. Finally, it is shown that, in order to evaluate the period and rigidity of retrofitted structures, OMA might be used.

• 한국수자원학회논문집
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• 제36권4호
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• pp.623-631
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• 2003

본 연구에서는 유의파고별, 지오 튜브의 채움비, 지오 튜브 천단고의 변화에 따라 지오 튜브의 안정 및 소파성능에 관한 실험을 실시하였다. 축척은 1/50로 하여 조파 수로내에 모형을 설치하였다. 안정성 시험은 유의파고를 재현하여 지오 튜브의 변위를 계측하여 검토하였다. 지오 튜브의 각 부분의 변위량을 관찰하기 위하여 바닥에 메쉬를 설치하여 계측하였으며 지오 튜브 상부에 기준선을 표시하고 10cm 간격으로 초기 위치점을 설정하여 계측하였다. 소파성능은 지오 튜브의 설치전과 설치후의 각각의 채움비에 따라 천단고가 있는 경우와 없는 경우 파고전달율 해석하여 비교 분석하였다.

• 한국환경과학회지
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• 제2권2호
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• pp.145-152
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• 1993

An experimental research was conducted in order to study the treatability of leachate and a combined wastewater of municipal landfill leachate and municipal sewage. The landfill leachate was that of Nanjido landfill site, and the municipal sewage was obtained from Chungnang municipal sewage treatment plant of Seoul. Several sets of bench-scale sequencing batch reactor(SBR) were used as experimental apparatus. Specially investigated items in this experiment were the removal efficiency of substrate and the influence of the hydraulic retention time(HRT). The experiment lasted for about 8 months. The result are as follows ; 1) The characteristics of leachate were pH 7.4~8.1, BOD 280~450 mg/l, COD 1300 ~ 1350 mg/l, T-N 2021 ~2110 mg/1,7-P 2.7 ~3.2 mg/l, Cl-3540 ~4085 mg/l, and heavy metals are a very small amount. And the characteristics of sewage Ivere pH 6.9~7.3, BOD 78.4~129.3 mg/1, COD 121.2~305.0 mg/l, T-N 14.9~36.4 mg/l, T-P 1.3 ~5.9 mg/l. 2) The treatability of leachate alone was not treat well. So for the good treatment of leachate, it was necessary to deal with the pretreatment before biological treatment and a combined treatment of municipal serfage. 3) The various contents of the leachate were 5%, 10%, and 50% and the removal efficiency of COD was 86.0%, 82.8%, 60.6%, and 31.7%. The maximum content of the leachate which could be sucessfully treated by SBR in the combined treatment was 10% of that of sewage.

• 한국환경보건학회지
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• 제19권3호
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• pp.1-16
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• 1993

This paper describes an investigation to determine whether the activated sludge (AS) process could be used for the treatment of wastewater at the Union Carbide Coporation (UCC) plant in Seadrift, Texas. This plant presently utilizes a waste stabilization pond (WSP) system for treatment of the wastewater. The treatment system consists of an in-plant primary WSP and two off-plant WSPs (secondary and tertiary WSPs), run in series. The total hydraulic detention time of the WSP system is approximately 150 days. Several laboratory-based treatability studies have been conducted to evaluate the performace of the WSP system and the degradability of specific chemical compounds. From an additional study, it was determined that the WSP system was stressed and occasionally operating near the limit of its treatment capacity. The existing primary WSP plays an important role in the overall treatmemt system, because it not only functions as a pH and organic-strength equalization basin, but also serves as a "preconditioning" basin by fermenting high strength organic wastes to volatile organic acids for subsequent degradation in the escondary WSP. However, in view of pending RCRA legislatin conerning the "proposed organic toxicity characteristics limits" (40 CFR Part261: Federal Register, July, 1988), it is possible that the primary WSP will have to be abandoned in favor of alternative treatment options. Therefore the main purpose of this study was to perform activated sludge treatability evaluations for the development of an alternative to the existing primary WSP treatment ststem. In addition, another purpose was to determine the degradability of bis(2-chloroethyl)ether (Chlorex or CX) and benzene(BZ) in the activated sludge process. The presence of these two chemicals in the wastewater of the plant prompted the question of whatedether they could be degraded in an activated sludge system.

• 한국환경보건학회지
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• 제22권4호
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• pp.82-90
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• 1996

This study was performed to find the optimum mixing ratio of paper waste in composting of mixture of swine feces and newspaper. Using the experimental setting of aeration rate which was found in the experiment carried out priorly, and moisture contents reported in other literature, just the initial C:N ratios were differentiated by mixing different amount of newspaper with the same amount of swine feces. This study was carried out by operating 4 experimental cornposting reactors of bench scale for 3 weeks. The followings are the conclusions that were derived from this study. 1. During composting reaction, the C:N ratio of each cornposter was decreased. Degree of decrease was in order of run 3, run 2, run 4, and run 1 of which initial C:N ratio was 30, 25, 35, and 20 respectively. All of the final composts were found to be completed composting reaction. 2. Ash contents of each reactor increased rapidly in order of run 3, run 2, run 4, and run 1. The absolute values of quadratic effect coefficients of each second order regression function was 0.059, 0.038, 0.032, and 0.030 respectively. Ash contents evolution trend had a linear correlation with the C:N ratio trend. (r=-0.96932, p<0.05) 3. The range of highest temperatures reached during composting was 47.2-53.5$\circ$C. Those were not significantly different from one another. Thermophilic temperatures were maintained in the range of 48-108 hours. 4. Contents of heavy metal detected in the final compost were lower than those of Korean and European standards. 5. Concentration range of Nitrogen in the final compost was 1.11-2.27%, and that of phosphorus was 8.40-10.70 mg/kg. 6. The optimum C:N ratio which has been proposed without the consideration of types of bulking agents should be re-examined. Biodegradabilities of each bulking agents was thought to be important factor when determining the optimum initial C:N ratio for cornposting.

• KEPCO Journal on Electric Power and Energy
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• 제2권1호
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• pp.109-113
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• 2016

Techno-economic evaluation of Non-Capture $CO_2$ Utilization (NCCU) technology for the production of high-value-added products using greenhouse gas ($CO_2$) was performed. The general scheme of NCCU process is composed of $CO_2$ carbonation and brine electrolysis process. Through a carbonation reaction with sodium hydroxide that is generated from brine electrolysis and $CO_2$ of the flue gas, it is possible to get high-value-added products such as sodium bicarbonate, sodium hydroxide, hydrogen & chloride and also to reduce the $CO_2$ emission simultaneously. For the techno-economic study on NCCU technology, continuous operation of bench-scale facility which could treat $2kgCO_2/day$ was performed. and based on the key performance data evaluated, the economic evaluation analysis targeted on the commercial chemical plant, which could treat 6 tons $CO_2$ per day, was performed using the net present value (NPV) metrics. The results showed that the net profit obtained during the whole plant operation was about 7,890 mKRW (million Korean Won) on NPV metrics and annual $CO_2$ reduction was estimated as about $2,000tCO_2$. Also it was found that the energy consumption of brine electrolysis is one of the key factors which affect the plant operation cost (ex. electricity consumption) and the net profit of the plant. Based on these results, it could be deduced that NCCU technology of this study could be one of the cost-effective $CO_2$ utilization technology options.

• 화약ㆍ발파
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• 제32권3호
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• pp.1-9
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• 2014

벤치발파에서 발파에 의한 암석의 파쇄입도는 적재, 운반과 파쇄로 이어지는 후속공정에 직접적으로 영향을 미치고 있다. 본 연구에서는 전자뇌관을 사용하여 정확한 지연시차를 구현하였으며, 각 발파공에 대해 저항선 m당 1, 2, 3, 4, 5, 7, 10ms의 지연시차를 적용하여 실규모 시험을 통해 암석 파쇄입도를 측정하였다. 그 결과, 석회석 광산에서 저항선을 기준으로 약 6ms/m의 지연시차가 최소의 파쇄입도를 가지는 것으로 측정되었다. 또한, 파쇄입도 분포 분석을 통해 지연시차가 암석의 파쇄입도에 변화를 줄 수 있는 요소로 정의될 수 있으며, 지연시차를 통해 파쇄입도를 조절 가능하다고 사료된다.

• Environmental Engineering Research
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• 제17권4호
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• pp.185-190
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• 2012

Rejection characteristics of perchlorate ($ClO_4^-$) were examined for commercially available reverse osmosis (RO) and nanofiltration (NF) membranes. A bench-scale dead-end stirred-cell filtration system was employed to determine the toxic ion rejection and the membrane flux. Model water solutions were used to prepare $ClO_4^-$ solutions (approximately, $1,000{\mu}g/L$) in the presence of background salts (NaCl, $Na_2SO_4$, and $CaCl_2$) at various pH values (3.5, 7, and 9.5) and solution ionic strengths (0.001, 0.01, and 0.01 M NaCl) in the presence of natural organic matter (NOM). Rejection by the membranes increased with increasing solution pH owing to increasingly negative membrane charge. In addition, the rejection of the target ion by the membranes increased with increasing solution ionic strength. The rejection of $ClO_4^-$ was consistently higher for the RO membrane than for the NF membrane and $ClO_4^-$ rejection followed the order $CaCl_2$ < NaCl < $Na_2SO_4$ at conditions of constant pH and ionic strength for both the RO and NF membranes. The possible influence of NOM on $ClO_4^-$ rejection by the membranes was also explored.

• 한국가스학회지
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• 제19권6호
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• pp.22-27
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• 2015

최근 고고도 장기체공 무인기의 개발이 활발하게 진행되고 있는 가운데, 중량당 에너지 밀도가 높아서 왕복동 엔진의 연료로서 적합한 수소 연료를 적용하는 것이 경제성과 기술성 측면에서 유리한 것으로 검토되었다. 본 연구에서는 2.4리터급 왕복동 가솔린엔진을 수소엔진으로 개조하기 위하여 수소연료를 공급하기 위한 실험장치를 구축하고 수소연료 공급이 가능한 인젝터를 장착하였으며 범용 엔진제어기를 이용하여 엔진을 구동시킴으로써 시동 및 공회전 시의 연소 특성을 파악하였다. 안전하게 엔진 시동성을 확보하였고 공회전 상태를 유지할 수 있는 조건을 탐색하였다. 또한 공회전 상태에서 공연비와 점화 타이밍을 변경해보면서 연소 안정성을 비롯한 기본적인 연소 특성을 살펴봄으로써 향후 수소엔진을 활용한 무인기의 동력원을 개발하기 위한 기초를 마련하였다.